Modeling of Laboratory Steam Methane Reforming and CO<sub>2</sub> Methanation Reactors

To support the interpretation of the experimental results obtained from two laboratory-scale reactors, one working in the steam methane reforming (SMR) mode, and the other in the CO<sub>2</sub> hydrogenation (MCO2) mode, a steady-state pseudo-homogeneous 1D non-isothermal packed-bed reac...

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Main Authors: Paola Costamagna, Federico Pugliese, Tullio Cavattoni, Guido Busca, Gabriella Garbarino
Format: Article
Language:English
Published: MDPI AG 2020-05-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/13/10/2624
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author Paola Costamagna
Federico Pugliese
Tullio Cavattoni
Guido Busca
Gabriella Garbarino
author_facet Paola Costamagna
Federico Pugliese
Tullio Cavattoni
Guido Busca
Gabriella Garbarino
author_sort Paola Costamagna
collection DOAJ
description To support the interpretation of the experimental results obtained from two laboratory-scale reactors, one working in the steam methane reforming (SMR) mode, and the other in the CO<sub>2</sub> hydrogenation (MCO2) mode, a steady-state pseudo-homogeneous 1D non-isothermal packed-bed reactor model is developed, embedding the classical Xu and Froment local kinetics. The laboratory reactors are operated with three different catalysts, two commercial and one homemade. The simulation model makes it possible to identify and account for thermal effects occurring inside the catalytic zone of the reactor and along the exit line. The model is intended to guide the development of small size SMR and MCO2 reactors in the context of Power-to-X (P2X) studies.
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spelling doaj.art-ae86d20983f54a64a030fd33fcdd17582023-11-20T01:20:37ZengMDPI AGEnergies1996-10732020-05-011310262410.3390/en13102624Modeling of Laboratory Steam Methane Reforming and CO<sub>2</sub> Methanation ReactorsPaola Costamagna0Federico Pugliese1Tullio Cavattoni2Guido Busca3Gabriella Garbarino4Department of Chemistry and Industrial Chemistry, University of Genova, via Dodecaneso 31, I-16146 Genova, ItalyDepartment of Civil, Chemical and Environmental Engineering, Chemical Engineering Pole, University of Genova, via Opera Pia 15, I-16145 Genova, ItalyINSTM, UdR Genova, via Dodecaneso 31, I-16146 Genova, ItalyDepartment of Civil, Chemical and Environmental Engineering, Chemical Engineering Pole, University of Genova, via Opera Pia 15, I-16145 Genova, ItalyDepartment of Civil, Chemical and Environmental Engineering, Chemical Engineering Pole, University of Genova, via Opera Pia 15, I-16145 Genova, ItalyTo support the interpretation of the experimental results obtained from two laboratory-scale reactors, one working in the steam methane reforming (SMR) mode, and the other in the CO<sub>2</sub> hydrogenation (MCO2) mode, a steady-state pseudo-homogeneous 1D non-isothermal packed-bed reactor model is developed, embedding the classical Xu and Froment local kinetics. The laboratory reactors are operated with three different catalysts, two commercial and one homemade. The simulation model makes it possible to identify and account for thermal effects occurring inside the catalytic zone of the reactor and along the exit line. The model is intended to guide the development of small size SMR and MCO2 reactors in the context of Power-to-X (P2X) studies.https://www.mdpi.com/1996-1073/13/10/2624chemical reactor modelingCO<sub>2</sub> methanationhydrogenNi-based catalystsPower-to-Xsteam methane reforming
spellingShingle Paola Costamagna
Federico Pugliese
Tullio Cavattoni
Guido Busca
Gabriella Garbarino
Modeling of Laboratory Steam Methane Reforming and CO<sub>2</sub> Methanation Reactors
Energies
chemical reactor modeling
CO<sub>2</sub> methanation
hydrogen
Ni-based catalysts
Power-to-X
steam methane reforming
title Modeling of Laboratory Steam Methane Reforming and CO<sub>2</sub> Methanation Reactors
title_full Modeling of Laboratory Steam Methane Reforming and CO<sub>2</sub> Methanation Reactors
title_fullStr Modeling of Laboratory Steam Methane Reforming and CO<sub>2</sub> Methanation Reactors
title_full_unstemmed Modeling of Laboratory Steam Methane Reforming and CO<sub>2</sub> Methanation Reactors
title_short Modeling of Laboratory Steam Methane Reforming and CO<sub>2</sub> Methanation Reactors
title_sort modeling of laboratory steam methane reforming and co sub 2 sub methanation reactors
topic chemical reactor modeling
CO<sub>2</sub> methanation
hydrogen
Ni-based catalysts
Power-to-X
steam methane reforming
url https://www.mdpi.com/1996-1073/13/10/2624
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AT tulliocavattoni modelingoflaboratorysteammethanereformingandcosub2submethanationreactors
AT guidobusca modelingoflaboratorysteammethanereformingandcosub2submethanationreactors
AT gabriellagarbarino modelingoflaboratorysteammethanereformingandcosub2submethanationreactors