Improvement of Congo Red Photodegradation Performance Through Zn/Al-TiO2 and Zn/Al-ZnO Preparation

Layered double hydroxide (LDH) is an anionic clay material known to be effective as a catalyst for the photodegradation of dye organic pollutants. Zn/Al LDH was synthesized by coprecipitation then impregnated with metal oxides and calcined at 300oC to form Zn/Al-TiO2 and Zn/Al-ZnO as photodegradatio...

Full description

Bibliographic Details
Main Authors: Nova Yuliasari, Amri, Risfidian Mohadi, Elfita Elfita, Aldes Lesbani
Format: Article
Language:English
Published: Magister Program of Material Sciences, Graduate School of Universitas Sriwijaya 2022-10-01
Series:Science and Technology Indonesia
Subjects:
Online Access:https://sciencetechindonesia.com/index.php/jsti/article/view/562/267
_version_ 1797227115464097792
author Nova Yuliasari
Amri
Risfidian Mohadi
Elfita Elfita
Aldes Lesbani
author_facet Nova Yuliasari
Amri
Risfidian Mohadi
Elfita Elfita
Aldes Lesbani
author_sort Nova Yuliasari
collection DOAJ
description Layered double hydroxide (LDH) is an anionic clay material known to be effective as a catalyst for the photodegradation of dye organic pollutants. Zn/Al LDH was synthesized by coprecipitation then impregnated with metal oxides and calcined at 300oC to form Zn/Al-TiO2 and Zn/Al-ZnO as photodegradation catalysts of congo red (CR). The characterization of the catalysts after preparation using SEM and UV-DRS while the catalyst that have been used in 5 regeneration cycles was characterized by XRD and FTIR. Photodegradation of CR was carried out by optimizing pH, catalyst weight, and time radiation. Zn/Al LDH which was modified into Zn/Al-TiO2 and ZnAl-ZnO had a better degradation percentage, rate constant, and stability than Zn/Al LDH pristine structure. Zn/Al LDH, Zn/Al TiO2 and Zn/Al-ZnO catalyzed CR photodegradation for 120 minutes with percent degradation 68.39%, 81.24% and 71.09%, respectively.
first_indexed 2024-04-24T14:35:40Z
format Article
id doaj.art-ae8bc2bf3d3241f5a033776539adb79e
institution Directory Open Access Journal
issn 2580-4405
2580-4391
language English
last_indexed 2024-04-24T14:35:40Z
publishDate 2022-10-01
publisher Magister Program of Material Sciences, Graduate School of Universitas Sriwijaya
record_format Article
series Science and Technology Indonesia
spelling doaj.art-ae8bc2bf3d3241f5a033776539adb79e2024-04-03T01:11:39ZengMagister Program of Material Sciences, Graduate School of Universitas SriwijayaScience and Technology Indonesia2580-44052580-43912022-10-017444945410.26554/sti.2022.7.4.449-454Improvement of Congo Red Photodegradation Performance Through Zn/Al-TiO2 and Zn/Al-ZnO PreparationNova Yuliasari 0Amri 1Risfidian Mohadi 2Elfita Elfita 3Aldes Lesbani 4Graduate School of Mathematics and Natural Sciences, Faculty of Mathematics and natural Sciences, Universitas Sriwijaya, Palembang, 30662, IndonesiaMagister Program Graduate School of Mathematics and Natural Sciences, Universitas Sriwijaya, Palembang, 30139, IndonesiaResearch Center of Inorganic Materials and Coordination Complexes, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Palembang, 30662, IndonesiaGraduate School of Mathematics and Natural Sciences, Faculty of Mathematics and natural Sciences, Universitas Sriwijaya, Palembang, 30662, IndonesiaResearch Center of Inorganic Materials and Coordination Complexes, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Palembang, 30662, IndonesiaLayered double hydroxide (LDH) is an anionic clay material known to be effective as a catalyst for the photodegradation of dye organic pollutants. Zn/Al LDH was synthesized by coprecipitation then impregnated with metal oxides and calcined at 300oC to form Zn/Al-TiO2 and Zn/Al-ZnO as photodegradation catalysts of congo red (CR). The characterization of the catalysts after preparation using SEM and UV-DRS while the catalyst that have been used in 5 regeneration cycles was characterized by XRD and FTIR. Photodegradation of CR was carried out by optimizing pH, catalyst weight, and time radiation. Zn/Al LDH which was modified into Zn/Al-TiO2 and ZnAl-ZnO had a better degradation percentage, rate constant, and stability than Zn/Al LDH pristine structure. Zn/Al LDH, Zn/Al TiO2 and Zn/Al-ZnO catalyzed CR photodegradation for 120 minutes with percent degradation 68.39%, 81.24% and 71.09%, respectively.https://sciencetechindonesia.com/index.php/jsti/article/view/562/267zn/al ldhcongo redznotio2photodegradation
spellingShingle Nova Yuliasari
Amri
Risfidian Mohadi
Elfita Elfita
Aldes Lesbani
Improvement of Congo Red Photodegradation Performance Through Zn/Al-TiO2 and Zn/Al-ZnO Preparation
Science and Technology Indonesia
zn/al ldh
congo red
zno
tio2
photodegradation
title Improvement of Congo Red Photodegradation Performance Through Zn/Al-TiO2 and Zn/Al-ZnO Preparation
title_full Improvement of Congo Red Photodegradation Performance Through Zn/Al-TiO2 and Zn/Al-ZnO Preparation
title_fullStr Improvement of Congo Red Photodegradation Performance Through Zn/Al-TiO2 and Zn/Al-ZnO Preparation
title_full_unstemmed Improvement of Congo Red Photodegradation Performance Through Zn/Al-TiO2 and Zn/Al-ZnO Preparation
title_short Improvement of Congo Red Photodegradation Performance Through Zn/Al-TiO2 and Zn/Al-ZnO Preparation
title_sort improvement of congo red photodegradation performance through zn al tio2 and zn al zno preparation
topic zn/al ldh
congo red
zno
tio2
photodegradation
url https://sciencetechindonesia.com/index.php/jsti/article/view/562/267
work_keys_str_mv AT novayuliasari improvementofcongoredphotodegradationperformancethroughznaltio2andznalznopreparation
AT amri improvementofcongoredphotodegradationperformancethroughznaltio2andznalznopreparation
AT risfidianmohadi improvementofcongoredphotodegradationperformancethroughznaltio2andznalznopreparation
AT elfitaelfita improvementofcongoredphotodegradationperformancethroughznaltio2andznalznopreparation
AT aldeslesbani improvementofcongoredphotodegradationperformancethroughznaltio2andznalznopreparation