Synthesis of N-perfluoroalkyl-3,4-disubstituted pyrroles by rhodium-catalyzed transannulation of N-fluoroalkyl-1,2,3-triazoles with terminal alkynes

Synthesis of N-perfluoroalkyl-3,4-disubstituted pyrroles by rhodium-catalyzed transannulation of N-fluoroalkyl-1,2,3-triazoles with terminal alkynes

The rhodium-catalyzed transannulation of N-perfluoroalkyl-1,2,3-triazoles with aromatic and aliphatic terminal alkynes under microwave heating conditions afforded N-perfluoroalkyl-3,4-disubstituted pyrroles (major products) and N-fluoroalkyl-2,4-disubstituted pyrroles (minor products). The observed...

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Bibliographic Details
Main Authors: Olga Bakhanovich, Viktor Khutorianskyi, Vladimir Motornov, Petr Beier
Format: Article
Language:English
Published: Beilstein-Institut 2021-02-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
pyrrole
transannulation
rhodium carbene
triazole
Online Access:https://doi.org/10.3762/bjoc.17.44

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