Di-μ-chlorido-bis(chlorido{8-[2-(dimethylamino)ethylamino]quinoline}cadmium) ethanol monosolvate
The title solvated bimetallic complex, [Cd2Cl4(C13H17N3)2]·C2H5OH, comprises two Cd2+ metal ions linked by a pair of μ2 Cl− ions. The coordination sphere around each Cd2+ ion is completed by three N atoms of a tridentate 8-[2-(dimethylamino)ethylamino]quinoline ligand and another chloride ion to for...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2021-02-01
|
| Series: | IUCrData |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314621001504 |
| _version_ | 1819299084262965248 |
|---|---|
| author | Abdul-Razak H. Al-Sudani Myasim Qasim Abdulridha Benson M. Kariuki |
| author_facet | Abdul-Razak H. Al-Sudani Myasim Qasim Abdulridha Benson M. Kariuki |
| author_sort | Abdul-Razak H. Al-Sudani |
| collection | DOAJ |
| description | The title solvated bimetallic complex, [Cd2Cl4(C13H17N3)2]·C2H5OH, comprises two Cd2+ metal ions linked by a pair of μ2 Cl− ions. The coordination sphere around each Cd2+ ion is completed by three N atoms of a tridentate 8-[2-(dimethylamino)ethylamino]quinoline ligand and another chloride ion to form a distorted fac-CdN3Cl3 octahedron. The ethanol molecule is both an acceptor of an N—H...O and a donor of an O—H...Cl hydrogen bonds to its adjacent complex unit. In the crystal, weak aromatic π–π stacking is observed. |
| first_indexed | 2024-12-24T05:40:10Z |
| format | Article |
| id | doaj.art-aecb6a5463834a06ae2b47f575deda43 |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-24T05:40:10Z |
| publishDate | 2021-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-aecb6a5463834a06ae2b47f575deda432022-12-21T17:12:51ZengInternational Union of CrystallographyIUCrData2414-31462021-02-0162x21015010.1107/S2414314621001504hb4375Di-μ-chlorido-bis(chlorido{8-[2-(dimethylamino)ethylamino]quinoline}cadmium) ethanol monosolvateAbdul-Razak H. Al-Sudani0Myasim Qasim Abdulridha1Benson M. Kariuki2Department of Chemistry, College of Science for Women, University of Baghdad, IraqDepartment of Chemistry, College of Science for Women, University of Baghdad, IraqSchool of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10, 3AT, UKThe title solvated bimetallic complex, [Cd2Cl4(C13H17N3)2]·C2H5OH, comprises two Cd2+ metal ions linked by a pair of μ2 Cl− ions. The coordination sphere around each Cd2+ ion is completed by three N atoms of a tridentate 8-[2-(dimethylamino)ethylamino]quinoline ligand and another chloride ion to form a distorted fac-CdN3Cl3 octahedron. The ethanol molecule is both an acceptor of an N—H...O and a donor of an O—H...Cl hydrogen bonds to its adjacent complex unit. In the crystal, weak aromatic π–π stacking is observed.http://scripts.iucr.org/cgi-bin/paper?S2414314621001504crystal structurecadmiumcomplexquinoline |
| spellingShingle | Abdul-Razak H. Al-Sudani Myasim Qasim Abdulridha Benson M. Kariuki Di-μ-chlorido-bis(chlorido{8-[2-(dimethylamino)ethylamino]quinoline}cadmium) ethanol monosolvate IUCrData crystal structure cadmium complex quinoline |
| title | Di-μ-chlorido-bis(chlorido{8-[2-(dimethylamino)ethylamino]quinoline}cadmium) ethanol monosolvate |
| title_full | Di-μ-chlorido-bis(chlorido{8-[2-(dimethylamino)ethylamino]quinoline}cadmium) ethanol monosolvate |
| title_fullStr | Di-μ-chlorido-bis(chlorido{8-[2-(dimethylamino)ethylamino]quinoline}cadmium) ethanol monosolvate |
| title_full_unstemmed | Di-μ-chlorido-bis(chlorido{8-[2-(dimethylamino)ethylamino]quinoline}cadmium) ethanol monosolvate |
| title_short | Di-μ-chlorido-bis(chlorido{8-[2-(dimethylamino)ethylamino]quinoline}cadmium) ethanol monosolvate |
| title_sort | di μ chlorido bis chlorido 8 2 dimethylamino ethylamino quinoline cadmium ethanol monosolvate |
| topic | crystal structure cadmium complex quinoline |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314621001504 |
| work_keys_str_mv | AT abdulrazakhalsudani dimchloridobischlorido82dimethylaminoethylaminoquinolinecadmiumethanolmonosolvate AT myasimqasimabdulridha dimchloridobischlorido82dimethylaminoethylaminoquinolinecadmiumethanolmonosolvate AT bensonmkariuki dimchloridobischlorido82dimethylaminoethylaminoquinolinecadmiumethanolmonosolvate |