Study on the proportion of paste filling materials based on fluorogypsum

A new type of paste filling material was created using fluorogypsum, a byproduct of hydrofluoric acid, as the raw material to address the issue of the filling material’s high cost. The effects of five factors, including gangue, fly ash, fluorogypsum, lime content, and mass concentration on the physi...

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Main Authors: Wang Chun, Li Xin-ru, Cheng Lu-ping, Xiong Zu-qiang, Zhan Shuai-fei
Format: Article
Language:English
Published: Public Library of Science (PLoS) 2023-01-01
Series:PLoS ONE
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10249845/?tool=EBI
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author Wang Chun
Li Xin-ru
Cheng Lu-ping
Xiong Zu-qiang
Zhan Shuai-fei
author_facet Wang Chun
Li Xin-ru
Cheng Lu-ping
Xiong Zu-qiang
Zhan Shuai-fei
author_sort Wang Chun
collection DOAJ
description A new type of paste filling material was created using fluorogypsum, a byproduct of hydrofluoric acid, as the raw material to address the issue of the filling material’s high cost. The effects of five factors, including gangue, fly ash, fluorogypsum, lime content, and mass concentration on the physical and mechanical properties of filling material were also examined. In addition to analyzing slump and extension changes, the filler’s mineral composition and microstructure were examined using SEM and XRD examinations. The results show that the best ratio of the developed filling material was 1000g coal gangue, 300g fly ash, 300g fluorogypsum, and 50g lime and mass concentration is 78%, and its compressive strength can reach 4–5MPa at 28 days. Raw materials such as gangue and fly ash will have a certain influence on the mechanical properties of the filling material. The hydration products of the developed filling material prepared by XRD and SEM were ettringite, calcium sulfate dihydrate, and calcium silicate hydrate gel. The new fluorogypsum-based paste filling material can be used to consolidate loose rock strata and fill goaf. It solves the problem of disposal of industrial waste fluoropgypsum and also solves the problem of coal mine gangue stacking, which has a far-reaching influence on ecological environment management.
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spelling doaj.art-aeccaaffbdf54222854625bd00802d6e2023-06-11T05:31:28ZengPublic Library of Science (PLoS)PLoS ONE1932-62032023-01-01186Study on the proportion of paste filling materials based on fluorogypsumWang ChunLi Xin-ruCheng Lu-pingXiong Zu-qiangZhan Shuai-feiA new type of paste filling material was created using fluorogypsum, a byproduct of hydrofluoric acid, as the raw material to address the issue of the filling material’s high cost. The effects of five factors, including gangue, fly ash, fluorogypsum, lime content, and mass concentration on the physical and mechanical properties of filling material were also examined. In addition to analyzing slump and extension changes, the filler’s mineral composition and microstructure were examined using SEM and XRD examinations. The results show that the best ratio of the developed filling material was 1000g coal gangue, 300g fly ash, 300g fluorogypsum, and 50g lime and mass concentration is 78%, and its compressive strength can reach 4–5MPa at 28 days. Raw materials such as gangue and fly ash will have a certain influence on the mechanical properties of the filling material. The hydration products of the developed filling material prepared by XRD and SEM were ettringite, calcium sulfate dihydrate, and calcium silicate hydrate gel. The new fluorogypsum-based paste filling material can be used to consolidate loose rock strata and fill goaf. It solves the problem of disposal of industrial waste fluoropgypsum and also solves the problem of coal mine gangue stacking, which has a far-reaching influence on ecological environment management.https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10249845/?tool=EBI
spellingShingle Wang Chun
Li Xin-ru
Cheng Lu-ping
Xiong Zu-qiang
Zhan Shuai-fei
Study on the proportion of paste filling materials based on fluorogypsum
PLoS ONE
title Study on the proportion of paste filling materials based on fluorogypsum
title_full Study on the proportion of paste filling materials based on fluorogypsum
title_fullStr Study on the proportion of paste filling materials based on fluorogypsum
title_full_unstemmed Study on the proportion of paste filling materials based on fluorogypsum
title_short Study on the proportion of paste filling materials based on fluorogypsum
title_sort study on the proportion of paste filling materials based on fluorogypsum
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10249845/?tool=EBI
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AT xiongzuqiang studyontheproportionofpastefillingmaterialsbasedonfluorogypsum
AT zhanshuaifei studyontheproportionofpastefillingmaterialsbasedonfluorogypsum