Tris(2,2′-bipyridine-κ2N,N′)cobalt(III) bis[bis(pyridine-2,6-dicarboxylato-κ3O2,N,O6)cobaltate(III)] perchlorate dimethylformamide hemisolvate 1.3-hydrate
In the title compound, [Co(C10H8N2)3][Co(C7H3NO4)2]2(ClO4)·0.5C3H7NO·1.3H2O, the CoIII atom in the complex cation is pseudooctahedrally coordinated by six N atoms of three chelating bipyridine ligands. The CoIII atom in the complex anion is coordinated by two pyridine N ato...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812037208 |
| _version_ | 1819290518532653056 |
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| author | Irina A. Golenya Alexander N. Boyko Natalia V. Kotova Matti Haukka Turganbay S. Iskenderov |
| author_facet | Irina A. Golenya Alexander N. Boyko Natalia V. Kotova Matti Haukka Turganbay S. Iskenderov |
| author_sort | Irina A. Golenya |
| collection | DOAJ |
| description | In the title compound, [Co(C10H8N2)3][Co(C7H3NO4)2]2(ClO4)·0.5C3H7NO·1.3H2O, the CoIII atom in the complex cation is pseudooctahedrally coordinated by six N atoms of three chelating bipyridine ligands. The CoIII atom in the complex anion is coordinated by two pyridine N atoms and four carboxylate O atoms of two doubly deprotonated pyridine-2,6-dicarboxylate ligands in a distorted octahedral geometry. One dimethylformamide solvent molecule and two water molecules are half-occupied and one water molecule is 0.3-occupied. O—H...O hydrogen bonds link the water molecules, the perchlorate anions and the complex anions. π–π interactions between the pyridine rings of the complex anions are also observed [centroid–centroid distance = 3.804 (3) Å]. |
| first_indexed | 2024-12-24T03:24:01Z |
| format | Article |
| id | doaj.art-aed651884f344facb85019e93435fe10 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T03:24:01Z |
| publishDate | 2012-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-aed651884f344facb85019e93435fe102022-12-21T17:17:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-10-016810m1237m123810.1107/S1600536812037208Tris(2,2′-bipyridine-κ2N,N′)cobalt(III) bis[bis(pyridine-2,6-dicarboxylato-κ3O2,N,O6)cobaltate(III)] perchlorate dimethylformamide hemisolvate 1.3-hydrateIrina A. GolenyaAlexander N. BoykoNatalia V. KotovaMatti HaukkaTurganbay S. IskenderovIn the title compound, [Co(C10H8N2)3][Co(C7H3NO4)2]2(ClO4)·0.5C3H7NO·1.3H2O, the CoIII atom in the complex cation is pseudooctahedrally coordinated by six N atoms of three chelating bipyridine ligands. The CoIII atom in the complex anion is coordinated by two pyridine N atoms and four carboxylate O atoms of two doubly deprotonated pyridine-2,6-dicarboxylate ligands in a distorted octahedral geometry. One dimethylformamide solvent molecule and two water molecules are half-occupied and one water molecule is 0.3-occupied. O—H...O hydrogen bonds link the water molecules, the perchlorate anions and the complex anions. π–π interactions between the pyridine rings of the complex anions are also observed [centroid–centroid distance = 3.804 (3) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536812037208 |
| spellingShingle | Irina A. Golenya Alexander N. Boyko Natalia V. Kotova Matti Haukka Turganbay S. Iskenderov Tris(2,2′-bipyridine-κ2N,N′)cobalt(III) bis[bis(pyridine-2,6-dicarboxylato-κ3O2,N,O6)cobaltate(III)] perchlorate dimethylformamide hemisolvate 1.3-hydrate Acta Crystallographica Section E |
| title | Tris(2,2′-bipyridine-κ2N,N′)cobalt(III) bis[bis(pyridine-2,6-dicarboxylato-κ3O2,N,O6)cobaltate(III)] perchlorate dimethylformamide hemisolvate 1.3-hydrate |
| title_full | Tris(2,2′-bipyridine-κ2N,N′)cobalt(III) bis[bis(pyridine-2,6-dicarboxylato-κ3O2,N,O6)cobaltate(III)] perchlorate dimethylformamide hemisolvate 1.3-hydrate |
| title_fullStr | Tris(2,2′-bipyridine-κ2N,N′)cobalt(III) bis[bis(pyridine-2,6-dicarboxylato-κ3O2,N,O6)cobaltate(III)] perchlorate dimethylformamide hemisolvate 1.3-hydrate |
| title_full_unstemmed | Tris(2,2′-bipyridine-κ2N,N′)cobalt(III) bis[bis(pyridine-2,6-dicarboxylato-κ3O2,N,O6)cobaltate(III)] perchlorate dimethylformamide hemisolvate 1.3-hydrate |
| title_short | Tris(2,2′-bipyridine-κ2N,N′)cobalt(III) bis[bis(pyridine-2,6-dicarboxylato-κ3O2,N,O6)cobaltate(III)] perchlorate dimethylformamide hemisolvate 1.3-hydrate |
| title_sort | tris 2 2 amp 8242 bipyridine amp 954 2n n amp 8242 cobalt iii bis bis pyridine 2 6 dicarboxylato amp 954 3o2 n o6 cobaltate iii perchlorate dimethylformamide hemisolvate 1 3 hydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812037208 |
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