Synthesis and Characterization of PMMA with 4 - Carbazole Chromophore Substitution
A new carbazole- containing polymer has been synthesized for further photophysical studies. Efficient synthesis of the substituted methyl methacrylate has been accomplished via microwave assisted synthesis of 1 - chloro - 4-carboxy -5,6, 7, 8- tetrahydrocarbazole followed by further steps, such as r...
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| Format: | Article |
| Language: | English |
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Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR
2005-06-01
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| Series: | Iranian Journal of Chemistry & Chemical Engineering |
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| Online Access: | http://www.ijcce.ac.ir/article_8119_72f68af008689ba09ce286b81c71f6eb.pdf |
| Summary: | A new carbazole- containing polymer has been synthesized for further photophysical studies. Efficient synthesis of the substituted methyl methacrylate has been accomplished via microwave assisted synthesis of 1 - chloro - 4-carboxy -5,6, 7, 8- tetrahydrocarbazole followed by further steps, such as reduction of the 4-substituted methyl carboxylate, dechlorination of the ring and at last, the reaction of the 4 - hydroxymethyl - 9 - ethyl carbazole with methacryloyl chloride. The resulting monomer was then polymerized free-radically to form the polymer, having a distribution Mw/Mn of 2.6. |
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| ISSN: | 1021-9986 1021-9986 |