Synthesis and Characterization of PMMA with 4 - Carbazole Chromophore Substitution
A new carbazole- containing polymer has been synthesized for further photophysical studies. Efficient synthesis of the substituted methyl methacrylate has been accomplished via microwave assisted synthesis of 1 - chloro - 4-carboxy -5,6, 7, 8- tetrahydrocarbazole followed by further steps, such as r...
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| Format: | Article |
| Language: | English |
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Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR
2005-06-01
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| Series: | Iranian Journal of Chemistry & Chemical Engineering |
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| Online Access: | http://www.ijcce.ac.ir/article_8119_72f68af008689ba09ce286b81c71f6eb.pdf |
| _version_ | 1818276020119142400 |
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| author | Mansoor Keyanpour Rad |
| author_facet | Mansoor Keyanpour Rad |
| author_sort | Mansoor Keyanpour Rad |
| collection | DOAJ |
| description | A new carbazole- containing polymer has been synthesized for further photophysical studies. Efficient synthesis of the substituted methyl methacrylate has been accomplished via microwave assisted synthesis of 1 - chloro - 4-carboxy -5,6, 7, 8- tetrahydrocarbazole followed by further steps, such as reduction of the 4-substituted methyl carboxylate, dechlorination of the ring and at last, the reaction of the 4 - hydroxymethyl - 9 - ethyl carbazole with methacryloyl chloride. The resulting monomer was then polymerized free-radically to form the polymer, having a distribution Mw/Mn of 2.6. |
| first_indexed | 2024-12-12T22:39:00Z |
| format | Article |
| id | doaj.art-aeded0370e614b14a57ac670bf505d99 |
| institution | Directory Open Access Journal |
| issn | 1021-9986 1021-9986 |
| language | English |
| last_indexed | 2024-12-12T22:39:00Z |
| publishDate | 2005-06-01 |
| publisher | Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR |
| record_format | Article |
| series | Iranian Journal of Chemistry & Chemical Engineering |
| spelling | doaj.art-aeded0370e614b14a57ac670bf505d992022-12-22T00:09:23ZengIranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECRIranian Journal of Chemistry & Chemical Engineering1021-99861021-99862005-06-0124211158119Synthesis and Characterization of PMMA with 4 - Carbazole Chromophore SubstitutionMansoor Keyanpour Rad0Materials and Energy Research Center, P. O. Box 14155-4777, Tehran, I. R. IRANA new carbazole- containing polymer has been synthesized for further photophysical studies. Efficient synthesis of the substituted methyl methacrylate has been accomplished via microwave assisted synthesis of 1 - chloro - 4-carboxy -5,6, 7, 8- tetrahydrocarbazole followed by further steps, such as reduction of the 4-substituted methyl carboxylate, dechlorination of the ring and at last, the reaction of the 4 - hydroxymethyl - 9 - ethyl carbazole with methacryloyl chloride. The resulting monomer was then polymerized free-radically to form the polymer, having a distribution Mw/Mn of 2.6.http://www.ijcce.ac.ir/article_8119_72f68af008689ba09ce286b81c71f6eb.pdfmicrowave promoted synthesiscarbazole-containing polymethylmethacrylatecarbazole chromophores4- substituted carbazolesfree radical polymerization |
| spellingShingle | Mansoor Keyanpour Rad Synthesis and Characterization of PMMA with 4 - Carbazole Chromophore Substitution Iranian Journal of Chemistry & Chemical Engineering microwave promoted synthesis carbazole-containing polymethylmethacrylate carbazole chromophores 4- substituted carbazoles free radical polymerization |
| title | Synthesis and Characterization of PMMA with 4 - Carbazole Chromophore Substitution |
| title_full | Synthesis and Characterization of PMMA with 4 - Carbazole Chromophore Substitution |
| title_fullStr | Synthesis and Characterization of PMMA with 4 - Carbazole Chromophore Substitution |
| title_full_unstemmed | Synthesis and Characterization of PMMA with 4 - Carbazole Chromophore Substitution |
| title_short | Synthesis and Characterization of PMMA with 4 - Carbazole Chromophore Substitution |
| title_sort | synthesis and characterization of pmma with 4 carbazole chromophore substitution |
| topic | microwave promoted synthesis carbazole-containing polymethylmethacrylate carbazole chromophores 4- substituted carbazoles free radical polymerization |
| url | http://www.ijcce.ac.ir/article_8119_72f68af008689ba09ce286b81c71f6eb.pdf |
| work_keys_str_mv | AT mansoorkeyanpourrad synthesisandcharacterizationofpmmawith4carbazolechromophoresubstitution |