rac-2,2′-(Thiane-2,6-diyl)bis[1-(4-bromophenyl)ethanone]
In the title compound, C21H20Br2O2S, prepared by the reaction of 1,9-bis(4-bromophenyl)nona-2,7-diene-1,9-dione with sodium sulfide nonahydrate in acetonitrile, the six-membered thiopyran ring has a chair conformation while the H atoms ortho to the S atom adopt a cis configuration. The dihedral angl...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-05-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811011792 |
| _version_ | 1798018409371271168 |
|---|---|
| author | Li-Qiang Liu Jing-Kui Yang |
| author_facet | Li-Qiang Liu Jing-Kui Yang |
| author_sort | Li-Qiang Liu |
| collection | DOAJ |
| description | In the title compound, C21H20Br2O2S, prepared by the reaction of 1,9-bis(4-bromophenyl)nona-2,7-diene-1,9-dione with sodium sulfide nonahydrate in acetonitrile, the six-membered thiopyran ring has a chair conformation while the H atoms ortho to the S atom adopt a cis configuration. The dihedral angle between the two benzene rings is 2.59 (8)°. |
| first_indexed | 2024-04-11T16:23:40Z |
| format | Article |
| id | doaj.art-aee38795796f40df9a58fb8842b8ee36 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T16:23:40Z |
| publishDate | 2011-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-aee38795796f40df9a58fb8842b8ee362022-12-22T04:14:15ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-05-01675o1047o104710.1107/S1600536811011792rac-2,2′-(Thiane-2,6-diyl)bis[1-(4-bromophenyl)ethanone]Li-Qiang LiuJing-Kui YangIn the title compound, C21H20Br2O2S, prepared by the reaction of 1,9-bis(4-bromophenyl)nona-2,7-diene-1,9-dione with sodium sulfide nonahydrate in acetonitrile, the six-membered thiopyran ring has a chair conformation while the H atoms ortho to the S atom adopt a cis configuration. The dihedral angle between the two benzene rings is 2.59 (8)°.http://scripts.iucr.org/cgi-bin/paper?S1600536811011792 |
| spellingShingle | Li-Qiang Liu Jing-Kui Yang rac-2,2′-(Thiane-2,6-diyl)bis[1-(4-bromophenyl)ethanone] Acta Crystallographica Section E |
| title | rac-2,2′-(Thiane-2,6-diyl)bis[1-(4-bromophenyl)ethanone] |
| title_full | rac-2,2′-(Thiane-2,6-diyl)bis[1-(4-bromophenyl)ethanone] |
| title_fullStr | rac-2,2′-(Thiane-2,6-diyl)bis[1-(4-bromophenyl)ethanone] |
| title_full_unstemmed | rac-2,2′-(Thiane-2,6-diyl)bis[1-(4-bromophenyl)ethanone] |
| title_short | rac-2,2′-(Thiane-2,6-diyl)bis[1-(4-bromophenyl)ethanone] |
| title_sort | rac 2 2 amp 8242 thiane 2 6 diyl bis 1 4 bromophenyl ethanone |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811011792 |
| work_keys_str_mv | AT liqiangliu rac22amp8242thiane26diylbis14bromophenylethanone AT jingkuiyang rac22amp8242thiane26diylbis14bromophenylethanone |