Lanthanide-Based Metal–Organic Frameworks with Single-Molecule Magnet Properties
Lanthanide metal–organic frameworks (Ln-MOFs) showing single-molecule magnet (SMM) properties are an ever-growing family of materials where the magnetic properties can be tuned by various interrelated parameters, such as the coordinated solvent, temperature, organic linkers, lanthanide ions and thei...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2023-07-01
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| Series: | Magnetochemistry |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2312-7481/9/7/190 |
| _version_ | 1797588510691033088 |
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| author | Fabio Manna Mariangela Oggianu Narcis Avarvari Maria Laura Mercuri |
| author_facet | Fabio Manna Mariangela Oggianu Narcis Avarvari Maria Laura Mercuri |
| author_sort | Fabio Manna |
| collection | DOAJ |
| description | Lanthanide metal–organic frameworks (Ln-MOFs) showing single-molecule magnet (SMM) properties are an ever-growing family of materials where the magnetic properties can be tuned by various interrelated parameters, such as the coordinated solvent, temperature, organic linkers, lanthanide ions and their coordination environment. An overview of the general synthetic methodologies to access MOFs/Ln-MOFs and the peculiarities and parameters to control and/or fine-tune their SMM behavior is herein presented. Additionally, diverse challenging strategies for inducing SMM/SIM behavior in an Ln-MOF are discussed, involving redox activity and chirality. Furthermore, intriguing physical phenomena such as the CISS effect and CPL are also highlighted. |
| first_indexed | 2024-03-11T00:54:07Z |
| format | Article |
| id | doaj.art-aee47877febb4105b8e1a389a143e22e |
| institution | Directory Open Access Journal |
| issn | 2312-7481 |
| language | English |
| last_indexed | 2024-03-11T00:54:07Z |
| publishDate | 2023-07-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Magnetochemistry |
| spelling | doaj.art-aee47877febb4105b8e1a389a143e22e2023-11-18T20:13:48ZengMDPI AGMagnetochemistry2312-74812023-07-019719010.3390/magnetochemistry9070190Lanthanide-Based Metal–Organic Frameworks with Single-Molecule Magnet PropertiesFabio Manna0Mariangela Oggianu1Narcis Avarvari2Maria Laura Mercuri3Department of Chemical and Geological Sciences, University of Cagliari, Highway 554, Crossroads for Sestu, I-09042 Monserrato, ItalyDepartment of Chemical and Geological Sciences, University of Cagliari, Highway 554, Crossroads for Sestu, I-09042 Monserrato, ItalyCNRS, MOLTECH-Anjou, SFR MATRIX University of Angers, F-49000 Angers, FranceDepartment of Chemical and Geological Sciences, University of Cagliari, Highway 554, Crossroads for Sestu, I-09042 Monserrato, ItalyLanthanide metal–organic frameworks (Ln-MOFs) showing single-molecule magnet (SMM) properties are an ever-growing family of materials where the magnetic properties can be tuned by various interrelated parameters, such as the coordinated solvent, temperature, organic linkers, lanthanide ions and their coordination environment. An overview of the general synthetic methodologies to access MOFs/Ln-MOFs and the peculiarities and parameters to control and/or fine-tune their SMM behavior is herein presented. Additionally, diverse challenging strategies for inducing SMM/SIM behavior in an Ln-MOF are discussed, involving redox activity and chirality. Furthermore, intriguing physical phenomena such as the CISS effect and CPL are also highlighted.https://www.mdpi.com/2312-7481/9/7/190lanthanide metal–organic frameworkssingle-molecule magnetssingle-ion magnets |
| spellingShingle | Fabio Manna Mariangela Oggianu Narcis Avarvari Maria Laura Mercuri Lanthanide-Based Metal–Organic Frameworks with Single-Molecule Magnet Properties Magnetochemistry lanthanide metal–organic frameworks single-molecule magnets single-ion magnets |
| title | Lanthanide-Based Metal–Organic Frameworks with Single-Molecule Magnet Properties |
| title_full | Lanthanide-Based Metal–Organic Frameworks with Single-Molecule Magnet Properties |
| title_fullStr | Lanthanide-Based Metal–Organic Frameworks with Single-Molecule Magnet Properties |
| title_full_unstemmed | Lanthanide-Based Metal–Organic Frameworks with Single-Molecule Magnet Properties |
| title_short | Lanthanide-Based Metal–Organic Frameworks with Single-Molecule Magnet Properties |
| title_sort | lanthanide based metal organic frameworks with single molecule magnet properties |
| topic | lanthanide metal–organic frameworks single-molecule magnets single-ion magnets |
| url | https://www.mdpi.com/2312-7481/9/7/190 |
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