catena-Poly[[(3-methylpyridine)copper(I)]-μ-cyanido-copper(I)-μ-cyanido]
In the title complex, [Cu2(CN)2(C6H7N)]n, there are two copper atoms with different coordination environments. One Cu atom (Cu1) is linked to the two cyanide ligands, one N atom from a pyridine ring while the other (Cu2) is coordinated by the two cyanide ligands in a slightly distorted tetrahedral g...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811028509 |
| _version_ | 1798025790002036736 |
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| author | Jin-Biao Cai Ting-Ting Chen Ze-Ying Xie Hong Deng |
| author_facet | Jin-Biao Cai Ting-Ting Chen Ze-Ying Xie Hong Deng |
| author_sort | Jin-Biao Cai |
| collection | DOAJ |
| description | In the title complex, [Cu2(CN)2(C6H7N)]n, there are two copper atoms with different coordination environments. One Cu atom (Cu1) is linked to the two cyanide ligands, one N atom from a pyridine ring while the other (Cu2) is coordinated by the two cyanide ligands in a slightly distorted tetrahedral geometry and linked to Cu1, forming a triangular coordination environment. The Cu atoms are bridged by bidentate cyanide ligands, forming an infinite Cu–CN chain. One cyanide ligand is equally disordered over two sets of sites, exchanging C and N atoms coordinated to both metal atoms. However, one cyanide group is not disordered and it coordinates to Cu1 via the N atom whereas its C-atom counterpart coordinates Cu2. The 3-methylpyridine (3MP) ligand coordinates through the N atom to Cu1 as a terminal ligand, which originates from decyanation of 3-pyridylacetonitrile under hydrothermal conditions. Adjacent Cu–CN chains are interconnected through Cu...Cu interactions [2.8364 (10) Å], forming a three-dimensional framework. |
| first_indexed | 2024-04-11T18:24:26Z |
| format | Article |
| id | doaj.art-af1f1aa8aef54c99bcda3c6973880020 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T18:24:26Z |
| publishDate | 2011-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-af1f1aa8aef54c99bcda3c69738800202022-12-22T04:09:40ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-08-01678m1136m113710.1107/S1600536811028509catena-Poly[[(3-methylpyridine)copper(I)]-μ-cyanido-copper(I)-μ-cyanido]Jin-Biao CaiTing-Ting ChenZe-Ying XieHong DengIn the title complex, [Cu2(CN)2(C6H7N)]n, there are two copper atoms with different coordination environments. One Cu atom (Cu1) is linked to the two cyanide ligands, one N atom from a pyridine ring while the other (Cu2) is coordinated by the two cyanide ligands in a slightly distorted tetrahedral geometry and linked to Cu1, forming a triangular coordination environment. The Cu atoms are bridged by bidentate cyanide ligands, forming an infinite Cu–CN chain. One cyanide ligand is equally disordered over two sets of sites, exchanging C and N atoms coordinated to both metal atoms. However, one cyanide group is not disordered and it coordinates to Cu1 via the N atom whereas its C-atom counterpart coordinates Cu2. The 3-methylpyridine (3MP) ligand coordinates through the N atom to Cu1 as a terminal ligand, which originates from decyanation of 3-pyridylacetonitrile under hydrothermal conditions. Adjacent Cu–CN chains are interconnected through Cu...Cu interactions [2.8364 (10) Å], forming a three-dimensional framework.http://scripts.iucr.org/cgi-bin/paper?S1600536811028509 |
| spellingShingle | Jin-Biao Cai Ting-Ting Chen Ze-Ying Xie Hong Deng catena-Poly[[(3-methylpyridine)copper(I)]-μ-cyanido-copper(I)-μ-cyanido] Acta Crystallographica Section E |
| title | catena-Poly[[(3-methylpyridine)copper(I)]-μ-cyanido-copper(I)-μ-cyanido] |
| title_full | catena-Poly[[(3-methylpyridine)copper(I)]-μ-cyanido-copper(I)-μ-cyanido] |
| title_fullStr | catena-Poly[[(3-methylpyridine)copper(I)]-μ-cyanido-copper(I)-μ-cyanido] |
| title_full_unstemmed | catena-Poly[[(3-methylpyridine)copper(I)]-μ-cyanido-copper(I)-μ-cyanido] |
| title_short | catena-Poly[[(3-methylpyridine)copper(I)]-μ-cyanido-copper(I)-μ-cyanido] |
| title_sort | catena poly 3 methylpyridine copper i amp 956 cyanido copper i amp 956 cyanido |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811028509 |
| work_keys_str_mv | AT jinbiaocai catenapoly3methylpyridinecopperiamp956cyanidocopperiamp956cyanido AT tingtingchen catenapoly3methylpyridinecopperiamp956cyanidocopperiamp956cyanido AT zeyingxie catenapoly3methylpyridinecopperiamp956cyanidocopperiamp956cyanido AT hongdeng catenapoly3methylpyridinecopperiamp956cyanidocopperiamp956cyanido |