Electrochemically Deposited Calcium Phosphate Coatings Using a Potentiostat of In-house Design and Implementation
Abstract The effect of growth conditions and post treatments on the properties of calcium phosphate films electrodeposited by a potentiostat of the authors’ design and construction is presented. The electrolyte used was formed with 0.025 M (NH4)H2PO4 and 0.042 M Ca(NO3)2.4H2O, and its pH was kept at...
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| Format: | Article |
| Language: | English |
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Associação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol)
2021-09-01
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| Series: | Materials Research |
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| Online Access: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392021000500226&tlng=en |
| _version_ | 1818719705629720576 |
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| author | F. N. Jiménez-García L.R. Giraldo-Torres E. Restrepo-Parra |
| author_facet | F. N. Jiménez-García L.R. Giraldo-Torres E. Restrepo-Parra |
| author_sort | F. N. Jiménez-García |
| collection | DOAJ |
| description | Abstract The effect of growth conditions and post treatments on the properties of calcium phosphate films electrodeposited by a potentiostat of the authors’ design and construction is presented. The electrolyte used was formed with 0.025 M (NH4)H2PO4 and 0.042 M Ca(NO3)2.4H2O, and its pH was kept at 5. A voltametric analysis was performed to determine the necessary potential values to obtain the films. Additionally, the temperature of the electrolyte was varied to determine its influence on the properties of the deposited films. The films were characterized by Fourier transform infrared spectroscopy, X-ray diffraction and scanning electron microscopy. The films deposited at -1.4 V and -1.7 V present the brushite phase. The thermal post-treatment favored the formation of octagonal calcium phosphate in amorphous phase, while the basic treatment provided the OH- groups necessary for the formation of hydroxyapatite. The low cost potentiostat implemented presents excellent characteristics for obtaining films with similar characteristics to those obtained with a conventional potentiostat. |
| first_indexed | 2024-12-17T20:11:11Z |
| format | Article |
| id | doaj.art-af21aea90c2147e5b807d8e440a1571a |
| institution | Directory Open Access Journal |
| issn | 1516-1439 |
| language | English |
| last_indexed | 2024-12-17T20:11:11Z |
| publishDate | 2021-09-01 |
| publisher | Associação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol) |
| record_format | Article |
| series | Materials Research |
| spelling | doaj.art-af21aea90c2147e5b807d8e440a1571a2022-12-21T21:34:14ZengAssociação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol)Materials Research1516-14392021-09-0124510.1590/1980-5373-mr-2021-0098Electrochemically Deposited Calcium Phosphate Coatings Using a Potentiostat of In-house Design and ImplementationF. N. Jiménez-Garcíahttps://orcid.org/0000-0003-1546-8426L.R. Giraldo-Torreshttps://orcid.org/0000-0002-8366-6478E. Restrepo-ParraAbstract The effect of growth conditions and post treatments on the properties of calcium phosphate films electrodeposited by a potentiostat of the authors’ design and construction is presented. The electrolyte used was formed with 0.025 M (NH4)H2PO4 and 0.042 M Ca(NO3)2.4H2O, and its pH was kept at 5. A voltametric analysis was performed to determine the necessary potential values to obtain the films. Additionally, the temperature of the electrolyte was varied to determine its influence on the properties of the deposited films. The films were characterized by Fourier transform infrared spectroscopy, X-ray diffraction and scanning electron microscopy. The films deposited at -1.4 V and -1.7 V present the brushite phase. The thermal post-treatment favored the formation of octagonal calcium phosphate in amorphous phase, while the basic treatment provided the OH- groups necessary for the formation of hydroxyapatite. The low cost potentiostat implemented presents excellent characteristics for obtaining films with similar characteristics to those obtained with a conventional potentiostat.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392021000500226&tlng=enCalcium phosphateelectrodepositionpotentiostatbasic treatmentthermal treatment |
| spellingShingle | F. N. Jiménez-García L.R. Giraldo-Torres E. Restrepo-Parra Electrochemically Deposited Calcium Phosphate Coatings Using a Potentiostat of In-house Design and Implementation Materials Research Calcium phosphate electrodeposition potentiostat basic treatment thermal treatment |
| title | Electrochemically Deposited Calcium Phosphate Coatings Using a Potentiostat of In-house Design and Implementation |
| title_full | Electrochemically Deposited Calcium Phosphate Coatings Using a Potentiostat of In-house Design and Implementation |
| title_fullStr | Electrochemically Deposited Calcium Phosphate Coatings Using a Potentiostat of In-house Design and Implementation |
| title_full_unstemmed | Electrochemically Deposited Calcium Phosphate Coatings Using a Potentiostat of In-house Design and Implementation |
| title_short | Electrochemically Deposited Calcium Phosphate Coatings Using a Potentiostat of In-house Design and Implementation |
| title_sort | electrochemically deposited calcium phosphate coatings using a potentiostat of in house design and implementation |
| topic | Calcium phosphate electrodeposition potentiostat basic treatment thermal treatment |
| url | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392021000500226&tlng=en |
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