Poly[diaqua(μ3-8-oxidoquinoline-5-sulfonato-κ4N,O8:O5:O8)nickel(II)]
In title compound, [Ni(C9H5NO4S)(H2O)2]n, the NiII atom is coordinated by one N atom and two bridging O atoms from two 8-oxidoquinoline-5-sulfonate ligands, one sulfonate O atom from a third ligand, and two water molecules in a distorted octahedral geometry. The two NiII atoms are linked to each oth...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809026105 |
| _version_ | 1818282756808900608 |
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| author | Guangshan Zhu Jianing Xu Ying Wang Li Wang |
| author_facet | Guangshan Zhu Jianing Xu Ying Wang Li Wang |
| author_sort | Guangshan Zhu |
| collection | DOAJ |
| description | In title compound, [Ni(C9H5NO4S)(H2O)2]n, the NiII atom is coordinated by one N atom and two bridging O atoms from two 8-oxidoquinoline-5-sulfonate ligands, one sulfonate O atom from a third ligand, and two water molecules in a distorted octahedral geometry. The two NiII atoms are linked to each other through the bridging O atoms, forming a dimer. Adjacent dimers are connected through the coordination of the sulfonate O atom into a two-dimensional coordination network parallel to (010). Hydrogen bonds between the coordinated water molecules and the uncoordinated O atoms of the sulfonate groups result in the construction of a three-dimensional supramolecular structure. |
| first_indexed | 2024-12-13T00:26:05Z |
| format | Article |
| id | doaj.art-af2c5546384340ef93a4b41ee2288696 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T00:26:05Z |
| publishDate | 2009-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-af2c5546384340ef93a4b41ee22886962022-12-22T00:05:26ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-08-01658m902m90210.1107/S1600536809026105Poly[diaqua(μ3-8-oxidoquinoline-5-sulfonato-κ4N,O8:O5:O8)nickel(II)]Guangshan ZhuJianing XuYing WangLi WangIn title compound, [Ni(C9H5NO4S)(H2O)2]n, the NiII atom is coordinated by one N atom and two bridging O atoms from two 8-oxidoquinoline-5-sulfonate ligands, one sulfonate O atom from a third ligand, and two water molecules in a distorted octahedral geometry. The two NiII atoms are linked to each other through the bridging O atoms, forming a dimer. Adjacent dimers are connected through the coordination of the sulfonate O atom into a two-dimensional coordination network parallel to (010). Hydrogen bonds between the coordinated water molecules and the uncoordinated O atoms of the sulfonate groups result in the construction of a three-dimensional supramolecular structure.http://scripts.iucr.org/cgi-bin/paper?S1600536809026105 |
| spellingShingle | Guangshan Zhu Jianing Xu Ying Wang Li Wang Poly[diaqua(μ3-8-oxidoquinoline-5-sulfonato-κ4N,O8:O5:O8)nickel(II)] Acta Crystallographica Section E |
| title | Poly[diaqua(μ3-8-oxidoquinoline-5-sulfonato-κ4N,O8:O5:O8)nickel(II)] |
| title_full | Poly[diaqua(μ3-8-oxidoquinoline-5-sulfonato-κ4N,O8:O5:O8)nickel(II)] |
| title_fullStr | Poly[diaqua(μ3-8-oxidoquinoline-5-sulfonato-κ4N,O8:O5:O8)nickel(II)] |
| title_full_unstemmed | Poly[diaqua(μ3-8-oxidoquinoline-5-sulfonato-κ4N,O8:O5:O8)nickel(II)] |
| title_short | Poly[diaqua(μ3-8-oxidoquinoline-5-sulfonato-κ4N,O8:O5:O8)nickel(II)] |
| title_sort | poly diaqua amp 956 3 8 oxidoquinoline 5 sulfonato amp 954 4n o8 o5 o8 nickel ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809026105 |
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