Potassium (3-Methyl-2-oxido-1,2,5-oxadiazol-4-yl)dinitromethanide

Furoxan derivatives enriched with explosophoric functionalities are promising compounds in the preparation of novel energetic materials. Herein, a previously unknown potassium (3-methyl-2-oxido-1,2,5-oxadiazol-4-yl)dinitromethanide (also referred to as potassium 4-dinitromethyl-3-methylfuroxanate) w...

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Bibliographic Details
Main Authors: Egor S. Zhilin, Dmitry B. Meerov, Leonid L. Fershtat
Format: Article
Language:English
Published: MDPI AG 2021-11-01
Series:Molbank
Subjects:
Online Access:https://www.mdpi.com/1422-8599/2021/4/M1301
Description
Summary:Furoxan derivatives enriched with explosophoric functionalities are promising compounds in the preparation of novel energetic materials. Herein, a previously unknown potassium (3-methyl-2-oxido-1,2,5-oxadiazol-4-yl)dinitromethanide (also referred to as potassium 4-dinitromethyl-3-methylfuroxanate) was synthesized via tandem nitration-reduction reactions of an available (furoxanyl)chloroxime. The structure of the synthesized compound was established by elemental analysis, IR, <sup>1</sup>H, <sup>13</sup>C and <sup>14</sup>N NMR spectroscopy. Thermal stability and mechanical sensitivity of the prepared compound toward impact and friction were experimentally determined.
ISSN:1422-8599