Potassium (3-Methyl-2-oxido-1,2,5-oxadiazol-4-yl)dinitromethanide
Furoxan derivatives enriched with explosophoric functionalities are promising compounds in the preparation of novel energetic materials. Herein, a previously unknown potassium (3-methyl-2-oxido-1,2,5-oxadiazol-4-yl)dinitromethanide (also referred to as potassium 4-dinitromethyl-3-methylfuroxanate) w...
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| Format: | Article |
| Language: | English |
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MDPI AG
2021-11-01
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| Series: | Molbank |
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| Online Access: | https://www.mdpi.com/1422-8599/2021/4/M1301 |
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| author | Egor S. Zhilin Dmitry B. Meerov Leonid L. Fershtat |
| author_facet | Egor S. Zhilin Dmitry B. Meerov Leonid L. Fershtat |
| author_sort | Egor S. Zhilin |
| collection | DOAJ |
| description | Furoxan derivatives enriched with explosophoric functionalities are promising compounds in the preparation of novel energetic materials. Herein, a previously unknown potassium (3-methyl-2-oxido-1,2,5-oxadiazol-4-yl)dinitromethanide (also referred to as potassium 4-dinitromethyl-3-methylfuroxanate) was synthesized via tandem nitration-reduction reactions of an available (furoxanyl)chloroxime. The structure of the synthesized compound was established by elemental analysis, IR, <sup>1</sup>H, <sup>13</sup>C and <sup>14</sup>N NMR spectroscopy. Thermal stability and mechanical sensitivity of the prepared compound toward impact and friction were experimentally determined. |
| first_indexed | 2024-03-10T03:30:34Z |
| format | Article |
| id | doaj.art-af322e2df9a2420b8b3298aa0f40130a |
| institution | Directory Open Access Journal |
| issn | 1422-8599 |
| language | English |
| last_indexed | 2024-03-10T03:30:34Z |
| publishDate | 2021-11-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molbank |
| spelling | doaj.art-af322e2df9a2420b8b3298aa0f40130a2023-11-23T09:43:36ZengMDPI AGMolbank1422-85992021-11-0120214M130110.3390/M1301Potassium (3-Methyl-2-oxido-1,2,5-oxadiazol-4-yl)dinitromethanideEgor S. Zhilin0Dmitry B. Meerov1Leonid L. Fershtat2N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Avenue, 119991 Moscow, RussiaSemenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, 4 Kosygina Street, 119991 Moscow, RussiaN.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Avenue, 119991 Moscow, RussiaFuroxan derivatives enriched with explosophoric functionalities are promising compounds in the preparation of novel energetic materials. Herein, a previously unknown potassium (3-methyl-2-oxido-1,2,5-oxadiazol-4-yl)dinitromethanide (also referred to as potassium 4-dinitromethyl-3-methylfuroxanate) was synthesized via tandem nitration-reduction reactions of an available (furoxanyl)chloroxime. The structure of the synthesized compound was established by elemental analysis, IR, <sup>1</sup>H, <sup>13</sup>C and <sup>14</sup>N NMR spectroscopy. Thermal stability and mechanical sensitivity of the prepared compound toward impact and friction were experimentally determined.https://www.mdpi.com/1422-8599/2021/4/M1301nitrogen heterocyclesoxadiazolesenergetic materialsfuroxansnitrationthermal stability |
| spellingShingle | Egor S. Zhilin Dmitry B. Meerov Leonid L. Fershtat Potassium (3-Methyl-2-oxido-1,2,5-oxadiazol-4-yl)dinitromethanide Molbank nitrogen heterocycles oxadiazoles energetic materials furoxans nitration thermal stability |
| title | Potassium (3-Methyl-2-oxido-1,2,5-oxadiazol-4-yl)dinitromethanide |
| title_full | Potassium (3-Methyl-2-oxido-1,2,5-oxadiazol-4-yl)dinitromethanide |
| title_fullStr | Potassium (3-Methyl-2-oxido-1,2,5-oxadiazol-4-yl)dinitromethanide |
| title_full_unstemmed | Potassium (3-Methyl-2-oxido-1,2,5-oxadiazol-4-yl)dinitromethanide |
| title_short | Potassium (3-Methyl-2-oxido-1,2,5-oxadiazol-4-yl)dinitromethanide |
| title_sort | potassium 3 methyl 2 oxido 1 2 5 oxadiazol 4 yl dinitromethanide |
| topic | nitrogen heterocycles oxadiazoles energetic materials furoxans nitration thermal stability |
| url | https://www.mdpi.com/1422-8599/2021/4/M1301 |
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