Photocatalytic Treatment of Stained Wastewater Coming from Handicraft Factories. A Case Study at the Pilot Plant Level

UV/H<sub>2</sub>O<sub>2</sub> process and TiO<sub>2</sub>-based photocatalysis were studied in the present work. The effectiveness of these methods was tested in the treatment of effluents taken from handicraft factories. Microorganisms, dyes, and different organi...

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Main Authors: Julie Joseane Murcia Mesa, Jhon Sebastián Hernández Niño, Wilson González, Hugo Rojas, María Carmen Hidalgo, José Antonio Navío
Format: Article
Language:English
Published: MDPI AG 2021-09-01
Series:Water
Subjects:
Online Access:https://www.mdpi.com/2073-4441/13/19/2705
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author Julie Joseane Murcia Mesa
Jhon Sebastián Hernández Niño
Wilson González
Hugo Rojas
María Carmen Hidalgo
José Antonio Navío
author_facet Julie Joseane Murcia Mesa
Jhon Sebastián Hernández Niño
Wilson González
Hugo Rojas
María Carmen Hidalgo
José Antonio Navío
author_sort Julie Joseane Murcia Mesa
collection DOAJ
description UV/H<sub>2</sub>O<sub>2</sub> process and TiO<sub>2</sub>-based photocatalysis were studied in the present work. The effectiveness of these methods was tested in the treatment of effluents taken from handicraft factories. Microorganisms, dyes, and different organic pollutants were detected in the industrial effluents. The experimental procedure for the wastewater treatment was carried out in a patented sunlight reactor on a pilot plant scale. From this study, UV/H<sub>2</sub>O<sub>2</sub> was found to be the best treatment for dye elimination. The optimal peroxide dosage for the degradation of dyes and the elimination of bacteria was 0.07 M. In this case, 70.80% of discoloration was achieved after 7 h of sunlight exposure, under an average sunlight intensity of 3.42 W/m<sup>2</sup>. The photocatalytic treatment based on TiO<sub>2</sub> achieved the highest elimination of coliform bacteria and the lowest TOC value; however, the presence of this material in the reactor had a detrimental effect on the overall elimination of dyes. A combination of both UV/H<sub>2</sub>O<sub>2</sub> and TiO<sub>2</sub> treatments significantly improves the dyes discoloration, the elimination of bacteria, and the organic compounds degradation. Some of the results of this study were presented at the 4th Congreso Colombiano de Procesos Avanzados de Oxidación, 4CCPAOx.
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spelling doaj.art-af4185d2cb58435dbe108aff29576b822023-11-22T17:01:23ZengMDPI AGWater2073-44412021-09-011319270510.3390/w13192705Photocatalytic Treatment of Stained Wastewater Coming from Handicraft Factories. A Case Study at the Pilot Plant LevelJulie Joseane Murcia Mesa0Jhon Sebastián Hernández Niño1Wilson González2Hugo Rojas3María Carmen Hidalgo4José Antonio Navío5Grupo de Catálisis, Facultad de Ciencias, Universidad Pedagógica y Tecnológica de Colombia, Avenida Central del Norte, Tunja 150003, Boyacá, ColombiaGrupo de Catálisis, Facultad de Ciencias, Universidad Pedagógica y Tecnológica de Colombia, Avenida Central del Norte, Tunja 150003, Boyacá, ColombiaGrupo de Catálisis, Facultad de Ciencias, Universidad Pedagógica y Tecnológica de Colombia, Avenida Central del Norte, Tunja 150003, Boyacá, ColombiaGrupo de Catálisis, Facultad de Ciencias, Universidad Pedagógica y Tecnológica de Colombia, Avenida Central del Norte, Tunja 150003, Boyacá, ColombiaInstituto de Ciencia de Materiales de Sevilla (ICMS), Consejo Superior de Investigaciones Científicas CSIC—Universidad de Sevilla, Calle Américo Vespucio 49, 41092 Seville, SpainInstituto de Ciencia de Materiales de Sevilla (ICMS), Consejo Superior de Investigaciones Científicas CSIC—Universidad de Sevilla, Calle Américo Vespucio 49, 41092 Seville, SpainUV/H<sub>2</sub>O<sub>2</sub> process and TiO<sub>2</sub>-based photocatalysis were studied in the present work. The effectiveness of these methods was tested in the treatment of effluents taken from handicraft factories. Microorganisms, dyes, and different organic pollutants were detected in the industrial effluents. The experimental procedure for the wastewater treatment was carried out in a patented sunlight reactor on a pilot plant scale. From this study, UV/H<sub>2</sub>O<sub>2</sub> was found to be the best treatment for dye elimination. The optimal peroxide dosage for the degradation of dyes and the elimination of bacteria was 0.07 M. In this case, 70.80% of discoloration was achieved after 7 h of sunlight exposure, under an average sunlight intensity of 3.42 W/m<sup>2</sup>. The photocatalytic treatment based on TiO<sub>2</sub> achieved the highest elimination of coliform bacteria and the lowest TOC value; however, the presence of this material in the reactor had a detrimental effect on the overall elimination of dyes. A combination of both UV/H<sub>2</sub>O<sub>2</sub> and TiO<sub>2</sub> treatments significantly improves the dyes discoloration, the elimination of bacteria, and the organic compounds degradation. Some of the results of this study were presented at the 4th Congreso Colombiano de Procesos Avanzados de Oxidación, 4CCPAOx.https://www.mdpi.com/2073-4441/13/19/2705handicraft factorieseffluentsUV/H<sub>2</sub>O<sub>2</sub>TiO<sub>2</sub>pilot plant
spellingShingle Julie Joseane Murcia Mesa
Jhon Sebastián Hernández Niño
Wilson González
Hugo Rojas
María Carmen Hidalgo
José Antonio Navío
Photocatalytic Treatment of Stained Wastewater Coming from Handicraft Factories. A Case Study at the Pilot Plant Level
Water
handicraft factories
effluents
UV/H<sub>2</sub>O<sub>2</sub>
TiO<sub>2</sub>
pilot plant
title Photocatalytic Treatment of Stained Wastewater Coming from Handicraft Factories. A Case Study at the Pilot Plant Level
title_full Photocatalytic Treatment of Stained Wastewater Coming from Handicraft Factories. A Case Study at the Pilot Plant Level
title_fullStr Photocatalytic Treatment of Stained Wastewater Coming from Handicraft Factories. A Case Study at the Pilot Plant Level
title_full_unstemmed Photocatalytic Treatment of Stained Wastewater Coming from Handicraft Factories. A Case Study at the Pilot Plant Level
title_short Photocatalytic Treatment of Stained Wastewater Coming from Handicraft Factories. A Case Study at the Pilot Plant Level
title_sort photocatalytic treatment of stained wastewater coming from handicraft factories a case study at the pilot plant level
topic handicraft factories
effluents
UV/H<sub>2</sub>O<sub>2</sub>
TiO<sub>2</sub>
pilot plant
url https://www.mdpi.com/2073-4441/13/19/2705
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