Contact angle and adhesion of CaO-SiO2- and CaO-Al2O3-based mold slags on solid steel of various compositions

To evaluate the lubrication capacity and flaking behavior of mold slag during continuous casting, the contact angle and spreading of CaO-SiO2 and CaO-Al2O3-based mold slags on solid substrates of three steel grades were investigated systematically by the sessile drop technique. The optical basicity...

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Main Authors: Huazhi Yuan, Zengkun Dan, Qiangqiang Wang, Shengping He
Format: Article
Language:English
Published: Elsevier 2020-07-01
Series:Journal of Materials Research and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2238785420313090
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author Huazhi Yuan
Zengkun Dan
Qiangqiang Wang
Shengping He
author_facet Huazhi Yuan
Zengkun Dan
Qiangqiang Wang
Shengping He
author_sort Huazhi Yuan
collection DOAJ
description To evaluate the lubrication capacity and flaking behavior of mold slag during continuous casting, the contact angle and spreading of CaO-SiO2 and CaO-Al2O3-based mold slags on solid substrates of three steel grades were investigated systematically by the sessile drop technique. The optical basicity and viscosity were combined to clarify the relationship between melt structure and contact angle, and the Mills’ model was used to determine the work of adhesion of mold slags on steel substrates. The primary results indicated that an increasing content of Al and Mn in steel was favorable for decreasing the contact angles. The wettability of the mold slags was related to the network structure, where a more complex network structure, correlated with a larger contact angle on the solid steel surface. The separation of the low-reactive or non-reactive mold slags from the solidified shell was more difficult than that of the CaO-SiO2-based mold slags. Considering the contact angles and works of adhesion, the developed low-reactive or non-reactive mold slags could present both satisfactory lubricating capacity and flaking behavior from the strand surface.
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spelling doaj.art-af439897f4424884bc36d37ce896f1912022-12-22T01:48:54ZengElsevierJournal of Materials Research and Technology2238-78542020-07-019478287837Contact angle and adhesion of CaO-SiO2- and CaO-Al2O3-based mold slags on solid steel of various compositionsHuazhi Yuan0Zengkun Dan1Qiangqiang Wang2Shengping He3College of Materials Science and Engineering, and Chongqing Key Laboratory of Vanadium–Titanium Metallurgy and Advanced Materials, Chongqing University, Chongqing 400044, ChinaCollege of Materials Science and Engineering, and Chongqing Key Laboratory of Vanadium–Titanium Metallurgy and Advanced Materials, Chongqing University, Chongqing 400044, ChinaCorresponding author.; College of Materials Science and Engineering, and Chongqing Key Laboratory of Vanadium–Titanium Metallurgy and Advanced Materials, Chongqing University, Chongqing 400044, ChinaCollege of Materials Science and Engineering, and Chongqing Key Laboratory of Vanadium–Titanium Metallurgy and Advanced Materials, Chongqing University, Chongqing 400044, ChinaTo evaluate the lubrication capacity and flaking behavior of mold slag during continuous casting, the contact angle and spreading of CaO-SiO2 and CaO-Al2O3-based mold slags on solid substrates of three steel grades were investigated systematically by the sessile drop technique. The optical basicity and viscosity were combined to clarify the relationship between melt structure and contact angle, and the Mills’ model was used to determine the work of adhesion of mold slags on steel substrates. The primary results indicated that an increasing content of Al and Mn in steel was favorable for decreasing the contact angles. The wettability of the mold slags was related to the network structure, where a more complex network structure, correlated with a larger contact angle on the solid steel surface. The separation of the low-reactive or non-reactive mold slags from the solidified shell was more difficult than that of the CaO-SiO2-based mold slags. Considering the contact angles and works of adhesion, the developed low-reactive or non-reactive mold slags could present both satisfactory lubricating capacity and flaking behavior from the strand surface.http://www.sciencedirect.com/science/article/pii/S2238785420313090Contact angleMold slagSolid steelWork of adhesion
spellingShingle Huazhi Yuan
Zengkun Dan
Qiangqiang Wang
Shengping He
Contact angle and adhesion of CaO-SiO2- and CaO-Al2O3-based mold slags on solid steel of various compositions
Journal of Materials Research and Technology
Contact angle
Mold slag
Solid steel
Work of adhesion
title Contact angle and adhesion of CaO-SiO2- and CaO-Al2O3-based mold slags on solid steel of various compositions
title_full Contact angle and adhesion of CaO-SiO2- and CaO-Al2O3-based mold slags on solid steel of various compositions
title_fullStr Contact angle and adhesion of CaO-SiO2- and CaO-Al2O3-based mold slags on solid steel of various compositions
title_full_unstemmed Contact angle and adhesion of CaO-SiO2- and CaO-Al2O3-based mold slags on solid steel of various compositions
title_short Contact angle and adhesion of CaO-SiO2- and CaO-Al2O3-based mold slags on solid steel of various compositions
title_sort contact angle and adhesion of cao sio2 and cao al2o3 based mold slags on solid steel of various compositions
topic Contact angle
Mold slag
Solid steel
Work of adhesion
url http://www.sciencedirect.com/science/article/pii/S2238785420313090
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