{μ-6,6′-Dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethanylylidene)]diphenolato}trinitratocopper(II)samarium(III)
In the monomeric dinuclear title complex, [CuSm(C20H22N2O4)(NO3)3], the four-coordinate CuII ion has a square-planar geometry involving two O atoms and two N atoms of the deprotonated Schiff base ligand. The SmIII ion is ten-coordinate, chelated by four O donor atoms of the Schiff base and two O ato...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811031138 |
| _version_ | 1818320929304870912 |
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| author | Jing-Chun Xing Bing Zhang Wen-Zhi Li Xiao-Guang Cui |
| author_facet | Jing-Chun Xing Bing Zhang Wen-Zhi Li Xiao-Guang Cui |
| author_sort | Jing-Chun Xing |
| collection | DOAJ |
| description | In the monomeric dinuclear title complex, [CuSm(C20H22N2O4)(NO3)3], the four-coordinate CuII ion has a square-planar geometry involving two O atoms and two N atoms of the deprotonated Schiff base ligand. The SmIII ion is ten-coordinate, chelated by four O donor atoms of the Schiff base and two O atoms each from three bidentate nitrate groups, one of which is disordered over two sites in a 0.55 (7):0.45 (7) ratio. |
| first_indexed | 2024-12-13T10:32:49Z |
| format | Article |
| id | doaj.art-af81e28c8b36477db518b5b9e419a134 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T10:32:49Z |
| publishDate | 2011-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-af81e28c8b36477db518b5b9e419a1342022-12-21T23:50:49ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-09-01679m1212m121210.1107/S1600536811031138{μ-6,6′-Dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethanylylidene)]diphenolato}trinitratocopper(II)samarium(III)Jing-Chun XingBing ZhangWen-Zhi LiXiao-Guang CuiIn the monomeric dinuclear title complex, [CuSm(C20H22N2O4)(NO3)3], the four-coordinate CuII ion has a square-planar geometry involving two O atoms and two N atoms of the deprotonated Schiff base ligand. The SmIII ion is ten-coordinate, chelated by four O donor atoms of the Schiff base and two O atoms each from three bidentate nitrate groups, one of which is disordered over two sites in a 0.55 (7):0.45 (7) ratio.http://scripts.iucr.org/cgi-bin/paper?S1600536811031138 |
| spellingShingle | Jing-Chun Xing Bing Zhang Wen-Zhi Li Xiao-Guang Cui {μ-6,6′-Dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethanylylidene)]diphenolato}trinitratocopper(II)samarium(III) Acta Crystallographica Section E |
| title | {μ-6,6′-Dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethanylylidene)]diphenolato}trinitratocopper(II)samarium(III) |
| title_full | {μ-6,6′-Dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethanylylidene)]diphenolato}trinitratocopper(II)samarium(III) |
| title_fullStr | {μ-6,6′-Dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethanylylidene)]diphenolato}trinitratocopper(II)samarium(III) |
| title_full_unstemmed | {μ-6,6′-Dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethanylylidene)]diphenolato}trinitratocopper(II)samarium(III) |
| title_short | {μ-6,6′-Dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethanylylidene)]diphenolato}trinitratocopper(II)samarium(III) |
| title_sort | amp 956 6 6 amp 8242 dimethoxy 2 2 amp 8242 butane 1 4 diylbis nitrilomethanylylidene diphenolato trinitratocopper ii samarium iii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811031138 |
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