(Dimethyl sulfoxide-κO)[2-({(ethylsulfanyl)[2-(2-oxidobenzylidene-κO)hydrazinylidene-κN2]methyl}iminomethyl)phenolato-κO]dioxidouranium(VI)
The UVI atom in the title complex, [U(C17H15N3O2S)O2(C2H6OS)], exists within a distorted pentagonal–pyramidal geometry where the oxide atoms occupy axial positions [O—U—O = 177.84 (14)°] and the pentagonal plane is defined by the N...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-03-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812003789 |
| _version_ | 1819289016161271808 |
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| author | Seik Weng Ng Reza Takjoo Edward R. T. Tiekink |
| author_facet | Seik Weng Ng Reza Takjoo Edward R. T. Tiekink |
| author_sort | Seik Weng Ng |
| collection | DOAJ |
| description | The UVI atom in the title complex, [U(C17H15N3O2S)O2(C2H6OS)], exists within a distorted pentagonal–pyramidal geometry where the oxide atoms occupy axial positions [O—U—O = 177.84 (14)°] and the pentagonal plane is defined by the N2O2 atoms of the tetradentate Schiff base ligand and the O atom of the dimethyl sulfoxide molecule. In the crystal, centrosymmetric aggregates are formed via pairs of C—H...O interactions. The azomethine C=N atoms and ethylthiolyl group are disordered over two orientations in a 0.828 (3):0.172 (3) ratio. |
| first_indexed | 2024-12-24T03:00:08Z |
| format | Article |
| id | doaj.art-af82bd1044bf4c3da3afb0ec351f83d0 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T03:00:08Z |
| publishDate | 2012-03-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-af82bd1044bf4c3da3afb0ec351f83d02022-12-21T17:18:15ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-03-01683m244m24510.1107/S1600536812003789(Dimethyl sulfoxide-κO)[2-({(ethylsulfanyl)[2-(2-oxidobenzylidene-κO)hydrazinylidene-κN2]methyl}iminomethyl)phenolato-κO]dioxidouranium(VI)Seik Weng NgReza TakjooEdward R. T. TiekinkThe UVI atom in the title complex, [U(C17H15N3O2S)O2(C2H6OS)], exists within a distorted pentagonal–pyramidal geometry where the oxide atoms occupy axial positions [O—U—O = 177.84 (14)°] and the pentagonal plane is defined by the N2O2 atoms of the tetradentate Schiff base ligand and the O atom of the dimethyl sulfoxide molecule. In the crystal, centrosymmetric aggregates are formed via pairs of C—H...O interactions. The azomethine C=N atoms and ethylthiolyl group are disordered over two orientations in a 0.828 (3):0.172 (3) ratio.http://scripts.iucr.org/cgi-bin/paper?S1600536812003789 |
| spellingShingle | Seik Weng Ng Reza Takjoo Edward R. T. Tiekink (Dimethyl sulfoxide-κO)[2-({(ethylsulfanyl)[2-(2-oxidobenzylidene-κO)hydrazinylidene-κN2]methyl}iminomethyl)phenolato-κO]dioxidouranium(VI) Acta Crystallographica Section E |
| title | (Dimethyl sulfoxide-κO)[2-({(ethylsulfanyl)[2-(2-oxidobenzylidene-κO)hydrazinylidene-κN2]methyl}iminomethyl)phenolato-κO]dioxidouranium(VI) |
| title_full | (Dimethyl sulfoxide-κO)[2-({(ethylsulfanyl)[2-(2-oxidobenzylidene-κO)hydrazinylidene-κN2]methyl}iminomethyl)phenolato-κO]dioxidouranium(VI) |
| title_fullStr | (Dimethyl sulfoxide-κO)[2-({(ethylsulfanyl)[2-(2-oxidobenzylidene-κO)hydrazinylidene-κN2]methyl}iminomethyl)phenolato-κO]dioxidouranium(VI) |
| title_full_unstemmed | (Dimethyl sulfoxide-κO)[2-({(ethylsulfanyl)[2-(2-oxidobenzylidene-κO)hydrazinylidene-κN2]methyl}iminomethyl)phenolato-κO]dioxidouranium(VI) |
| title_short | (Dimethyl sulfoxide-κO)[2-({(ethylsulfanyl)[2-(2-oxidobenzylidene-κO)hydrazinylidene-κN2]methyl}iminomethyl)phenolato-κO]dioxidouranium(VI) |
| title_sort | dimethyl sulfoxide amp 954 o 2 ethylsulfanyl 2 2 oxidobenzylidene amp 954 o hydrazinylidene amp 954 n2 methyl iminomethyl phenolato amp 954 o dioxidouranium vi |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812003789 |
| work_keys_str_mv | AT seikwengng dimethylsulfoxideamp954o2ethylsulfanyl22oxidobenzylideneamp954ohydrazinylideneamp954n2methyliminomethylphenolatoamp954odioxidouraniumvi AT rezatakjoo dimethylsulfoxideamp954o2ethylsulfanyl22oxidobenzylideneamp954ohydrazinylideneamp954n2methyliminomethylphenolatoamp954odioxidouraniumvi AT edwardrttiekink dimethylsulfoxideamp954o2ethylsulfanyl22oxidobenzylideneamp954ohydrazinylideneamp954n2methyliminomethylphenolatoamp954odioxidouraniumvi |