In Situ Forming MnFe2O4/D201 Magnetic Composite Adsorbents for High Selectivity Adsorption and Deep Treatment of As(V) from Wastewater

A new magnetic adsorbent, namely, MnFe2O4/D201, with deep-treatment ability and high selectivity adsorption for As(V) was prepared. According to isotherm adsorption and kinetics, As(V) adsorption is primarily used for chemical bonding throughout the single-layer adsorbing process. The maximum As(V)...

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Main Authors: Shaopeng Zhang, Jie Ding, Dayong Tian, Feifei Liu, Qiaoling Li, Minghua Lu
Format: Article
Language:English
Published: SAGE Publications 2023-01-01
Series:Adsorption Science & Technology
Online Access:http://dx.doi.org/10.1155/2023/9084244
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author Shaopeng Zhang
Jie Ding
Dayong Tian
Feifei Liu
Qiaoling Li
Minghua Lu
author_facet Shaopeng Zhang
Jie Ding
Dayong Tian
Feifei Liu
Qiaoling Li
Minghua Lu
author_sort Shaopeng Zhang
collection DOAJ
description A new magnetic adsorbent, namely, MnFe2O4/D201, with deep-treatment ability and high selectivity adsorption for As(V) was prepared. According to isotherm adsorption and kinetics, As(V) adsorption is primarily used for chemical bonding throughout the single-layer adsorbing process. The maximum As(V) adsorption capacity of MnFe2O4/D201 can reach 35.8 mg/g at pH 3. MnFe2O4/D201 also exhibits higher selectivity adsorption against Cl-, NO3-, SO42-, and PO43-. According to the thermodynamic results, the adsorption process was spontaneous and endothermic. The adsorption capacity is maintained at 81% of the initial after ten adsorption-desorption cycles. As(V) concentrations ranging from 1 mg/L to 10 μg/L can be treated in fixed-bed column experiments. The effectual cure volume of As(V) reaches 1332 BV (26.64 L). The removal mechanism primarily comprises electrostatic attraction and complexation.
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spelling doaj.art-af8e9819b5f34bbf89c896dc02f3b60f2024-04-02T21:03:50ZengSAGE PublicationsAdsorption Science & Technology2048-40382023-01-01202310.1155/2023/9084244In Situ Forming MnFe2O4/D201 Magnetic Composite Adsorbents for High Selectivity Adsorption and Deep Treatment of As(V) from WastewaterShaopeng Zhang0Jie Ding1Dayong Tian2Feifei Liu3Qiaoling Li4Minghua Lu5College of Chemical and Environmental EngineeringCollege of Chemical and Environmental EngineeringCollege of Chemical and Environmental EngineeringCollege of Chemical and Environmental EngineeringCollege of Chemical and Environmental EngineeringCollege of Chemistry and Chemical EngineeringA new magnetic adsorbent, namely, MnFe2O4/D201, with deep-treatment ability and high selectivity adsorption for As(V) was prepared. According to isotherm adsorption and kinetics, As(V) adsorption is primarily used for chemical bonding throughout the single-layer adsorbing process. The maximum As(V) adsorption capacity of MnFe2O4/D201 can reach 35.8 mg/g at pH 3. MnFe2O4/D201 also exhibits higher selectivity adsorption against Cl-, NO3-, SO42-, and PO43-. According to the thermodynamic results, the adsorption process was spontaneous and endothermic. The adsorption capacity is maintained at 81% of the initial after ten adsorption-desorption cycles. As(V) concentrations ranging from 1 mg/L to 10 μg/L can be treated in fixed-bed column experiments. The effectual cure volume of As(V) reaches 1332 BV (26.64 L). The removal mechanism primarily comprises electrostatic attraction and complexation.http://dx.doi.org/10.1155/2023/9084244
spellingShingle Shaopeng Zhang
Jie Ding
Dayong Tian
Feifei Liu
Qiaoling Li
Minghua Lu
In Situ Forming MnFe2O4/D201 Magnetic Composite Adsorbents for High Selectivity Adsorption and Deep Treatment of As(V) from Wastewater
Adsorption Science & Technology
title In Situ Forming MnFe2O4/D201 Magnetic Composite Adsorbents for High Selectivity Adsorption and Deep Treatment of As(V) from Wastewater
title_full In Situ Forming MnFe2O4/D201 Magnetic Composite Adsorbents for High Selectivity Adsorption and Deep Treatment of As(V) from Wastewater
title_fullStr In Situ Forming MnFe2O4/D201 Magnetic Composite Adsorbents for High Selectivity Adsorption and Deep Treatment of As(V) from Wastewater
title_full_unstemmed In Situ Forming MnFe2O4/D201 Magnetic Composite Adsorbents for High Selectivity Adsorption and Deep Treatment of As(V) from Wastewater
title_short In Situ Forming MnFe2O4/D201 Magnetic Composite Adsorbents for High Selectivity Adsorption and Deep Treatment of As(V) from Wastewater
title_sort in situ forming mnfe2o4 d201 magnetic composite adsorbents for high selectivity adsorption and deep treatment of as v from wastewater
url http://dx.doi.org/10.1155/2023/9084244
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