Low-cost replication of self-organized sub-micron structures into polymer films

In this paper, the results of exploiting self-organized sub-micron polystyrene (PS) wrinkle patterns possessing random orientation, in preparation of a nickel stamp for hot embossing purposes, are presented. Self-organized patterns were prepared employing a method in which a stiff cross-linked cappi...

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Main Authors: H. Stenberg, P. Stenberg, L. Takkunen, M. Kuittinen, M. Suvanto, T. T. Pakkanen
Format: Article
Language:English
Published: Budapest University of Technology 2015-02-01
Series:eXPRESS Polymer Letters
Subjects:
Online Access:http://www.expresspolymlett.com/letolt.php?file=EPL-0005458&mi=cd
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author H. Stenberg
P. Stenberg
L. Takkunen
M. Kuittinen
M. Suvanto
T. T. Pakkanen
author_facet H. Stenberg
P. Stenberg
L. Takkunen
M. Kuittinen
M. Suvanto
T. T. Pakkanen
author_sort H. Stenberg
collection DOAJ
description In this paper, the results of exploiting self-organized sub-micron polystyrene (PS) wrinkle patterns possessing random orientation, in preparation of a nickel stamp for hot embossing purposes, are presented. Self-organized patterns were prepared employing a method in which a stiff cross-linked capping layer on the topmost part of the soft polystyrene layer was created by using reactive ion etching (RIE) device with mild conditions and argon as a process gas, and the wrinkle formation was initiated thermally. Different surface patternings were obtained using silicon and stainless steel (SST) wafers as substrates. Prepared Ni-stamps were employed in hot embossing of polycarbonate (PC) and cyclo-olefin polymer (COP) films, using a nano-imprinting process. The replication quality of the self-organized wrinkle structures in PC and COP films was monitored by comparing the shape and dimensions of the original and final surface structures. The hot embossed sub-micron scale features, originally formed on stainless steel substrate, were found to have influence on the optical properties of the PC and COP films by lowering their reflectances.
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spelling doaj.art-af9a0a55ac60414e8cd80b174e3f68402022-12-22T01:27:12ZengBudapest University of TechnologyeXPRESS Polymer Letters1788-618X2015-02-01929510410.3144/expresspolymlett.2015.11Low-cost replication of self-organized sub-micron structures into polymer filmsH. StenbergP. StenbergL. TakkunenM. KuittinenM. SuvantoT. T. PakkanenIn this paper, the results of exploiting self-organized sub-micron polystyrene (PS) wrinkle patterns possessing random orientation, in preparation of a nickel stamp for hot embossing purposes, are presented. Self-organized patterns were prepared employing a method in which a stiff cross-linked capping layer on the topmost part of the soft polystyrene layer was created by using reactive ion etching (RIE) device with mild conditions and argon as a process gas, and the wrinkle formation was initiated thermally. Different surface patternings were obtained using silicon and stainless steel (SST) wafers as substrates. Prepared Ni-stamps were employed in hot embossing of polycarbonate (PC) and cyclo-olefin polymer (COP) films, using a nano-imprinting process. The replication quality of the self-organized wrinkle structures in PC and COP films was monitored by comparing the shape and dimensions of the original and final surface structures. The hot embossed sub-micron scale features, originally formed on stainless steel substrate, were found to have influence on the optical properties of the PC and COP films by lowering their reflectances.http://www.expresspolymlett.com/letolt.php?file=EPL-0005458&mi=cdCoatingsself-organizationpolystyrenenano-imprinting
spellingShingle H. Stenberg
P. Stenberg
L. Takkunen
M. Kuittinen
M. Suvanto
T. T. Pakkanen
Low-cost replication of self-organized sub-micron structures into polymer films
eXPRESS Polymer Letters
Coatings
self-organization
polystyrene
nano-imprinting
title Low-cost replication of self-organized sub-micron structures into polymer films
title_full Low-cost replication of self-organized sub-micron structures into polymer films
title_fullStr Low-cost replication of self-organized sub-micron structures into polymer films
title_full_unstemmed Low-cost replication of self-organized sub-micron structures into polymer films
title_short Low-cost replication of self-organized sub-micron structures into polymer films
title_sort low cost replication of self organized sub micron structures into polymer films
topic Coatings
self-organization
polystyrene
nano-imprinting
url http://www.expresspolymlett.com/letolt.php?file=EPL-0005458&mi=cd
work_keys_str_mv AT hstenberg lowcostreplicationofselforganizedsubmicronstructuresintopolymerfilms
AT pstenberg lowcostreplicationofselforganizedsubmicronstructuresintopolymerfilms
AT ltakkunen lowcostreplicationofselforganizedsubmicronstructuresintopolymerfilms
AT mkuittinen lowcostreplicationofselforganizedsubmicronstructuresintopolymerfilms
AT msuvanto lowcostreplicationofselforganizedsubmicronstructuresintopolymerfilms
AT ttpakkanen lowcostreplicationofselforganizedsubmicronstructuresintopolymerfilms