catena-Poly[[(2-{[2-(dimethylammonio)ethyl]iminomethyl}pyridine-κ2N,N′)bis(thiocyanato-κN)manganese(II)]-μ-thiocyanato-κ2N:S]
In the title one-dimensional coordination polymer, [Mn(NCS)3(C10H16N3)]n, the MnII atom is coordinated by an N,N′-bidentate Schiff base and four thiocyanate ligands in a distorted octahedral N5S geometry. Bridging thiocyanate ligands interconnect adjacent [Mn(NCS)2(C10H16N3)] units, gi...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812032874 |
| _version_ | 1819289286994821120 |
|---|---|
| author | Jun Wang Wubiao Zhu Jichang Li |
| author_facet | Jun Wang Wubiao Zhu Jichang Li |
| author_sort | Jun Wang |
| collection | DOAJ |
| description | In the title one-dimensional coordination polymer, [Mn(NCS)3(C10H16N3)]n, the MnII atom is coordinated by an N,N′-bidentate Schiff base and four thiocyanate ligands in a distorted octahedral N5S geometry. Bridging thiocyanate ligands interconnect adjacent [Mn(NCS)2(C10H16N3)] units, giving rise to helical chains extending along the b axis. The chains are further linked through N—H...S hydrogen bonds, leading to a three-dimensional supramolecular network. |
| first_indexed | 2024-12-24T03:04:27Z |
| format | Article |
| id | doaj.art-afa39e336f55461fac47d126558534e0 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T03:04:27Z |
| publishDate | 2012-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-afa39e336f55461fac47d126558534e02022-12-21T17:18:04ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-08-01688m1131m113110.1107/S1600536812032874catena-Poly[[(2-{[2-(dimethylammonio)ethyl]iminomethyl}pyridine-κ2N,N′)bis(thiocyanato-κN)manganese(II)]-μ-thiocyanato-κ2N:S]Jun WangWubiao ZhuJichang LiIn the title one-dimensional coordination polymer, [Mn(NCS)3(C10H16N3)]n, the MnII atom is coordinated by an N,N′-bidentate Schiff base and four thiocyanate ligands in a distorted octahedral N5S geometry. Bridging thiocyanate ligands interconnect adjacent [Mn(NCS)2(C10H16N3)] units, giving rise to helical chains extending along the b axis. The chains are further linked through N—H...S hydrogen bonds, leading to a three-dimensional supramolecular network.http://scripts.iucr.org/cgi-bin/paper?S1600536812032874 |
| spellingShingle | Jun Wang Wubiao Zhu Jichang Li catena-Poly[[(2-{[2-(dimethylammonio)ethyl]iminomethyl}pyridine-κ2N,N′)bis(thiocyanato-κN)manganese(II)]-μ-thiocyanato-κ2N:S] Acta Crystallographica Section E |
| title | catena-Poly[[(2-{[2-(dimethylammonio)ethyl]iminomethyl}pyridine-κ2N,N′)bis(thiocyanato-κN)manganese(II)]-μ-thiocyanato-κ2N:S] |
| title_full | catena-Poly[[(2-{[2-(dimethylammonio)ethyl]iminomethyl}pyridine-κ2N,N′)bis(thiocyanato-κN)manganese(II)]-μ-thiocyanato-κ2N:S] |
| title_fullStr | catena-Poly[[(2-{[2-(dimethylammonio)ethyl]iminomethyl}pyridine-κ2N,N′)bis(thiocyanato-κN)manganese(II)]-μ-thiocyanato-κ2N:S] |
| title_full_unstemmed | catena-Poly[[(2-{[2-(dimethylammonio)ethyl]iminomethyl}pyridine-κ2N,N′)bis(thiocyanato-κN)manganese(II)]-μ-thiocyanato-κ2N:S] |
| title_short | catena-Poly[[(2-{[2-(dimethylammonio)ethyl]iminomethyl}pyridine-κ2N,N′)bis(thiocyanato-κN)manganese(II)]-μ-thiocyanato-κ2N:S] |
| title_sort | catena poly 2 2 dimethylammonio ethyl iminomethyl pyridine amp 954 2n n amp 8242 bis thiocyanato amp 954 n manganese ii amp 956 thiocyanato amp 954 2n s |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812032874 |
| work_keys_str_mv | AT junwang catenapoly22dimethylammonioethyliminomethylpyridineamp9542nnamp8242bisthiocyanatoamp954nmanganeseiiamp956thiocyanatoamp9542ns AT wubiaozhu catenapoly22dimethylammonioethyliminomethylpyridineamp9542nnamp8242bisthiocyanatoamp954nmanganeseiiamp956thiocyanatoamp9542ns AT jichangli catenapoly22dimethylammonioethyliminomethylpyridineamp9542nnamp8242bisthiocyanatoamp954nmanganeseiiamp956thiocyanatoamp9542ns |