Thermodynamic Properties and Equation of State for Tungsten
A high-temperature equation of state for tungsten was constructed in this study using experimental data on its thermodynamic properties, thermal expansion, compressibility, and bulk compression modulus. The totality of experimental data were optimized by the temperature-dependent Tait equation over...
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| Format: | Article |
| Language: | English |
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MDPI AG
2023-10-01
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| Series: | Crystals |
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| Online Access: | https://www.mdpi.com/2073-4352/13/10/1470 |
| _version_ | 1827721321961750528 |
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| author | Nikolay V. Kozyrev Vladimir V. Gordeev |
| author_facet | Nikolay V. Kozyrev Vladimir V. Gordeev |
| author_sort | Nikolay V. Kozyrev |
| collection | DOAJ |
| description | A high-temperature equation of state for tungsten was constructed in this study using experimental data on its thermodynamic properties, thermal expansion, compressibility, and bulk compression modulus. The totality of experimental data were optimized by the temperature-dependent Tait equation over a pressure range from 0 up to 1000 kbar and over a temperature range from 20 K to the melting point. An extended Einstein model was used to describe the temperature dependence of thermodynamic and thermophysical parameters. A linear temperature dependence was embraced for the derivative of the isothermal bulk modulus. The resultant equation of state provides a good fit to the whole set of experimental data within measurement uncertainties associated with individual quantities. |
| first_indexed | 2024-03-10T21:19:57Z |
| format | Article |
| id | doaj.art-afcf4a00ce084d469de11cc5f8ec69bb |
| institution | Directory Open Access Journal |
| issn | 2073-4352 |
| language | English |
| last_indexed | 2024-03-10T21:19:57Z |
| publishDate | 2023-10-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Crystals |
| spelling | doaj.art-afcf4a00ce084d469de11cc5f8ec69bb2023-11-19T16:09:41ZengMDPI AGCrystals2073-43522023-10-011310147010.3390/cryst13101470Thermodynamic Properties and Equation of State for TungstenNikolay V. Kozyrev0Vladimir V. Gordeev1Laboratory for Physicochemical Fundamentals of Energetic Condensed Systems, Institute for Problems of Chemical and Energetic Technologies, Siberian Branch of the Russian Academy of Sciences (IPCET SB RAS), Biysk 659322, RussiaLaboratory for Physicochemical Fundamentals of Energetic Condensed Systems, Institute for Problems of Chemical and Energetic Technologies, Siberian Branch of the Russian Academy of Sciences (IPCET SB RAS), Biysk 659322, RussiaA high-temperature equation of state for tungsten was constructed in this study using experimental data on its thermodynamic properties, thermal expansion, compressibility, and bulk compression modulus. The totality of experimental data were optimized by the temperature-dependent Tait equation over a pressure range from 0 up to 1000 kbar and over a temperature range from 20 K to the melting point. An extended Einstein model was used to describe the temperature dependence of thermodynamic and thermophysical parameters. A linear temperature dependence was embraced for the derivative of the isothermal bulk modulus. The resultant equation of state provides a good fit to the whole set of experimental data within measurement uncertainties associated with individual quantities.https://www.mdpi.com/2073-4352/13/10/1470Tait equation of statetungstenbehavior modeling |
| spellingShingle | Nikolay V. Kozyrev Vladimir V. Gordeev Thermodynamic Properties and Equation of State for Tungsten Crystals Tait equation of state tungsten behavior modeling |
| title | Thermodynamic Properties and Equation of State for Tungsten |
| title_full | Thermodynamic Properties and Equation of State for Tungsten |
| title_fullStr | Thermodynamic Properties and Equation of State for Tungsten |
| title_full_unstemmed | Thermodynamic Properties and Equation of State for Tungsten |
| title_short | Thermodynamic Properties and Equation of State for Tungsten |
| title_sort | thermodynamic properties and equation of state for tungsten |
| topic | Tait equation of state tungsten behavior modeling |
| url | https://www.mdpi.com/2073-4352/13/10/1470 |
| work_keys_str_mv | AT nikolayvkozyrev thermodynamicpropertiesandequationofstatefortungsten AT vladimirvgordeev thermodynamicpropertiesandequationofstatefortungsten |