Synthesis of observed air–sea CO<sub>2</sub> exchange fluxes in the river-dominated East China Sea and improved estimates of annual and seasonal net mean fluxes

Limited observations exist for a reliable assessment of annual CO<sub>2</sub> uptake that takes into consideration the strong seasonal variation in the river-dominated East China Sea (ECS). Here we explore seasonally representative CO<sub>2</sub> uptakes by the whole East Chi...

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Bibliographic Details
Main Authors: C.-M. Tseng, P.-Y. Shen, K.-K. Liu
Format: Article
Language:English
Published: Copernicus Publications 2014-07-01
Series:Biogeosciences
Online Access:http://www.biogeosciences.net/11/3855/2014/bg-11-3855-2014.pdf
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Summary:Limited observations exist for a reliable assessment of annual CO<sub>2</sub> uptake that takes into consideration the strong seasonal variation in the river-dominated East China Sea (ECS). Here we explore seasonally representative CO<sub>2</sub> uptakes by the whole East China Sea derived from observations over a 14-year period. We firstly identified the biological sequestration of CO<sub>2</sub> taking place in the highly productive, nutrient-enriched Changjiang River plume, dictated by the Changjiang River discharge in warm seasons. We have therefore established an empirical algorithm as a function of sea surface temperature (SST) and Changjiang River discharge (CRD) for predicting sea surface <i>p</i>CO<sub>2</sub>. Syntheses based on both observations and models show that the annually averaged CO<sub>2</sub> uptake from atmosphere during the period 1998–2011 was constrained to about 1.8 ± 0.5 mol C m<sup>−2</sup> yr<sup>−1</sup>. This assessment of annual CO<sub>2</sub> uptake is more reliable and representative, compared to previous estimates, in terms of temporal and spatial coverage. Additionally, the CO<sub>2</sub> time series, exhibiting distinct seasonal pattern, gives mean fluxes of −3.7 ± 0.5, −1.1 ± 1.3, −0.3 ± 0.8 and −2.5 ± 0.7 mol C m<sup>−2</sup> yr<sup>−1</sup> in spring, summer, fall and winter, respectively, and also reveals apparent interannual variations. The flux seasonality shows a strong sink in spring and a weak source in late summer–mid-fall. The weak sink status during warm periods in summer–fall is fairly sensitive to changes of <i>p</i>CO<sub>2</sub> and may easily shift from a sink to a source altered by environmental changes under climate change and anthropogenic forcing.
ISSN:1726-4170
1726-4189