Bimetallic catalysts as electrocatalytic cathode materials for the oxygen reduction reaction in microbial fuel cell: A review

Microbial fuel cell (MFC) is one synchronous power generation device for wastewater treatment that takes into account environmental and energy issues, exhibiting promising potential. Sluggish oxygen reduction reaction (ORR) kinetics on the cathode remains by far the most critical bottleneck hinderin...

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Main Authors: Ke Zhao, Yuanxiang Shu, Fengxiang Li, Guosong Peng
Format: Article
Language:English
Published: KeAi Communications Co., Ltd. 2023-08-01
Series:Green Energy & Environment
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2468025722001510
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author Ke Zhao
Yuanxiang Shu
Fengxiang Li
Guosong Peng
author_facet Ke Zhao
Yuanxiang Shu
Fengxiang Li
Guosong Peng
author_sort Ke Zhao
collection DOAJ
description Microbial fuel cell (MFC) is one synchronous power generation device for wastewater treatment that takes into account environmental and energy issues, exhibiting promising potential. Sluggish oxygen reduction reaction (ORR) kinetics on the cathode remains by far the most critical bottleneck hindering the practical application of MFC. An ideal cathode catalyst should possess excellent ORR activity, stability, and cost-effectiveness, experiments have demonstrated that bimetallic catalysts are one of the most promising ORR catalysts currently. Based on this, this review mainly analyzes the reaction mechanism (ORR mechanisms, synergistic effects), advantages (combined with characterization technologies), and typical synthesis methods of bimetallic catalysts, focusing on the application effects of early Pt-M (M = Fe, Co, and Ni) alloys to bifunctional catalysts in MFC, pointing out that the main existing challenges remain economic analysis, long-term durability and large-scale application, and looking forward to this. At last, the research trend of bimetallic catalysts suitable for MFC is evaluated, and it is considered that the development and research of metal-organic framework (MOF)-based bimetallic catalysts are still worth focusing on in the future, intending to provide a reference for MFC to achieve energy-efficient wastewater treatment.
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spelling doaj.art-afe202fcd833484ab4b517d8e47897ea2023-07-07T04:27:41ZengKeAi Communications Co., Ltd.Green Energy & Environment2468-02572023-08-018410431070Bimetallic catalysts as electrocatalytic cathode materials for the oxygen reduction reaction in microbial fuel cell: A reviewKe Zhao0Yuanxiang Shu1Fengxiang Li2Guosong Peng3College of Municipal and Environmental Engineering, Ministry of Education Key Laboratory of Songliao Aquatic Environment, Jilin Jianzhu University, Jilin, 130118, ChinaCollege of Municipal and Environmental Engineering, Ministry of Education Key Laboratory of Songliao Aquatic Environment, Jilin Jianzhu University, Jilin, 130118, China; College of Environmental Science and Engineering, Ministry of Education Key Laboratory of Pollution Processes and Environmental Criteria, Remediation and Pollution Control for Urban Ecological Environmental, Nankai University, Tianjin, 300350, ChinaCollege of Environmental Science and Engineering, Ministry of Education Key Laboratory of Pollution Processes and Environmental Criteria, Remediation and Pollution Control for Urban Ecological Environmental, Nankai University, Tianjin, 300350, China; Corresponding author. College of Environmental Science and Engineering, Nankai University, 38 Tongyan Road, Tianjin 300350, China.College of Municipal and Environmental Engineering, Ministry of Education Key Laboratory of Songliao Aquatic Environment, Jilin Jianzhu University, Jilin, 130118, ChinaMicrobial fuel cell (MFC) is one synchronous power generation device for wastewater treatment that takes into account environmental and energy issues, exhibiting promising potential. Sluggish oxygen reduction reaction (ORR) kinetics on the cathode remains by far the most critical bottleneck hindering the practical application of MFC. An ideal cathode catalyst should possess excellent ORR activity, stability, and cost-effectiveness, experiments have demonstrated that bimetallic catalysts are one of the most promising ORR catalysts currently. Based on this, this review mainly analyzes the reaction mechanism (ORR mechanisms, synergistic effects), advantages (combined with characterization technologies), and typical synthesis methods of bimetallic catalysts, focusing on the application effects of early Pt-M (M = Fe, Co, and Ni) alloys to bifunctional catalysts in MFC, pointing out that the main existing challenges remain economic analysis, long-term durability and large-scale application, and looking forward to this. At last, the research trend of bimetallic catalysts suitable for MFC is evaluated, and it is considered that the development and research of metal-organic framework (MOF)-based bimetallic catalysts are still worth focusing on in the future, intending to provide a reference for MFC to achieve energy-efficient wastewater treatment.http://www.sciencedirect.com/science/article/pii/S2468025722001510Bimetallic catalystsOxygen reduction reactionMicrobial fuel cellWastewater treatmentPower generation
spellingShingle Ke Zhao
Yuanxiang Shu
Fengxiang Li
Guosong Peng
Bimetallic catalysts as electrocatalytic cathode materials for the oxygen reduction reaction in microbial fuel cell: A review
Green Energy & Environment
Bimetallic catalysts
Oxygen reduction reaction
Microbial fuel cell
Wastewater treatment
Power generation
title Bimetallic catalysts as electrocatalytic cathode materials for the oxygen reduction reaction in microbial fuel cell: A review
title_full Bimetallic catalysts as electrocatalytic cathode materials for the oxygen reduction reaction in microbial fuel cell: A review
title_fullStr Bimetallic catalysts as electrocatalytic cathode materials for the oxygen reduction reaction in microbial fuel cell: A review
title_full_unstemmed Bimetallic catalysts as electrocatalytic cathode materials for the oxygen reduction reaction in microbial fuel cell: A review
title_short Bimetallic catalysts as electrocatalytic cathode materials for the oxygen reduction reaction in microbial fuel cell: A review
title_sort bimetallic catalysts as electrocatalytic cathode materials for the oxygen reduction reaction in microbial fuel cell a review
topic Bimetallic catalysts
Oxygen reduction reaction
Microbial fuel cell
Wastewater treatment
Power generation
url http://www.sciencedirect.com/science/article/pii/S2468025722001510
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AT fengxiangli bimetalliccatalystsaselectrocatalyticcathodematerialsfortheoxygenreductionreactioninmicrobialfuelcellareview
AT guosongpeng bimetalliccatalystsaselectrocatalyticcathodematerialsfortheoxygenreductionreactioninmicrobialfuelcellareview