Bimetallic catalysts as electrocatalytic cathode materials for the oxygen reduction reaction in microbial fuel cell: A review
Microbial fuel cell (MFC) is one synchronous power generation device for wastewater treatment that takes into account environmental and energy issues, exhibiting promising potential. Sluggish oxygen reduction reaction (ORR) kinetics on the cathode remains by far the most critical bottleneck hinderin...
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KeAi Communications Co., Ltd.
2023-08-01
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Online Access: | http://www.sciencedirect.com/science/article/pii/S2468025722001510 |
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author | Ke Zhao Yuanxiang Shu Fengxiang Li Guosong Peng |
author_facet | Ke Zhao Yuanxiang Shu Fengxiang Li Guosong Peng |
author_sort | Ke Zhao |
collection | DOAJ |
description | Microbial fuel cell (MFC) is one synchronous power generation device for wastewater treatment that takes into account environmental and energy issues, exhibiting promising potential. Sluggish oxygen reduction reaction (ORR) kinetics on the cathode remains by far the most critical bottleneck hindering the practical application of MFC. An ideal cathode catalyst should possess excellent ORR activity, stability, and cost-effectiveness, experiments have demonstrated that bimetallic catalysts are one of the most promising ORR catalysts currently. Based on this, this review mainly analyzes the reaction mechanism (ORR mechanisms, synergistic effects), advantages (combined with characterization technologies), and typical synthesis methods of bimetallic catalysts, focusing on the application effects of early Pt-M (M = Fe, Co, and Ni) alloys to bifunctional catalysts in MFC, pointing out that the main existing challenges remain economic analysis, long-term durability and large-scale application, and looking forward to this. At last, the research trend of bimetallic catalysts suitable for MFC is evaluated, and it is considered that the development and research of metal-organic framework (MOF)-based bimetallic catalysts are still worth focusing on in the future, intending to provide a reference for MFC to achieve energy-efficient wastewater treatment. |
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issn | 2468-0257 |
language | English |
last_indexed | 2024-03-13T00:55:26Z |
publishDate | 2023-08-01 |
publisher | KeAi Communications Co., Ltd. |
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series | Green Energy & Environment |
spelling | doaj.art-afe202fcd833484ab4b517d8e47897ea2023-07-07T04:27:41ZengKeAi Communications Co., Ltd.Green Energy & Environment2468-02572023-08-018410431070Bimetallic catalysts as electrocatalytic cathode materials for the oxygen reduction reaction in microbial fuel cell: A reviewKe Zhao0Yuanxiang Shu1Fengxiang Li2Guosong Peng3College of Municipal and Environmental Engineering, Ministry of Education Key Laboratory of Songliao Aquatic Environment, Jilin Jianzhu University, Jilin, 130118, ChinaCollege of Municipal and Environmental Engineering, Ministry of Education Key Laboratory of Songliao Aquatic Environment, Jilin Jianzhu University, Jilin, 130118, China; College of Environmental Science and Engineering, Ministry of Education Key Laboratory of Pollution Processes and Environmental Criteria, Remediation and Pollution Control for Urban Ecological Environmental, Nankai University, Tianjin, 300350, ChinaCollege of Environmental Science and Engineering, Ministry of Education Key Laboratory of Pollution Processes and Environmental Criteria, Remediation and Pollution Control for Urban Ecological Environmental, Nankai University, Tianjin, 300350, China; Corresponding author. College of Environmental Science and Engineering, Nankai University, 38 Tongyan Road, Tianjin 300350, China.College of Municipal and Environmental Engineering, Ministry of Education Key Laboratory of Songliao Aquatic Environment, Jilin Jianzhu University, Jilin, 130118, ChinaMicrobial fuel cell (MFC) is one synchronous power generation device for wastewater treatment that takes into account environmental and energy issues, exhibiting promising potential. Sluggish oxygen reduction reaction (ORR) kinetics on the cathode remains by far the most critical bottleneck hindering the practical application of MFC. An ideal cathode catalyst should possess excellent ORR activity, stability, and cost-effectiveness, experiments have demonstrated that bimetallic catalysts are one of the most promising ORR catalysts currently. Based on this, this review mainly analyzes the reaction mechanism (ORR mechanisms, synergistic effects), advantages (combined with characterization technologies), and typical synthesis methods of bimetallic catalysts, focusing on the application effects of early Pt-M (M = Fe, Co, and Ni) alloys to bifunctional catalysts in MFC, pointing out that the main existing challenges remain economic analysis, long-term durability and large-scale application, and looking forward to this. At last, the research trend of bimetallic catalysts suitable for MFC is evaluated, and it is considered that the development and research of metal-organic framework (MOF)-based bimetallic catalysts are still worth focusing on in the future, intending to provide a reference for MFC to achieve energy-efficient wastewater treatment.http://www.sciencedirect.com/science/article/pii/S2468025722001510Bimetallic catalystsOxygen reduction reactionMicrobial fuel cellWastewater treatmentPower generation |
spellingShingle | Ke Zhao Yuanxiang Shu Fengxiang Li Guosong Peng Bimetallic catalysts as electrocatalytic cathode materials for the oxygen reduction reaction in microbial fuel cell: A review Green Energy & Environment Bimetallic catalysts Oxygen reduction reaction Microbial fuel cell Wastewater treatment Power generation |
title | Bimetallic catalysts as electrocatalytic cathode materials for the oxygen reduction reaction in microbial fuel cell: A review |
title_full | Bimetallic catalysts as electrocatalytic cathode materials for the oxygen reduction reaction in microbial fuel cell: A review |
title_fullStr | Bimetallic catalysts as electrocatalytic cathode materials for the oxygen reduction reaction in microbial fuel cell: A review |
title_full_unstemmed | Bimetallic catalysts as electrocatalytic cathode materials for the oxygen reduction reaction in microbial fuel cell: A review |
title_short | Bimetallic catalysts as electrocatalytic cathode materials for the oxygen reduction reaction in microbial fuel cell: A review |
title_sort | bimetallic catalysts as electrocatalytic cathode materials for the oxygen reduction reaction in microbial fuel cell a review |
topic | Bimetallic catalysts Oxygen reduction reaction Microbial fuel cell Wastewater treatment Power generation |
url | http://www.sciencedirect.com/science/article/pii/S2468025722001510 |
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