Methyl 1-{4-[(S)-2-(methoxycarbonyl)pyrrolidin-1-yl]-3,6-dioxocyclohexa-1,4-dien-1-yl}pyrrolidine-2-carboxylate
The complete molecule of the title diproline ester quinone, C18H22N2O6, is generated by a crystallographic twofold axis, which passes through the centre of the benzene ring. Both –CO2Me groups are orientated to the same side of the benzene ring, with the carbonyl groups pointing roughl...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810027947 |
| _version_ | 1818896550822150144 |
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| author | Simon J. Garden Janet M. S. Skakle Edward R. T. Tiekink James L. Wardell |
| author_facet | Simon J. Garden Janet M. S. Skakle Edward R. T. Tiekink James L. Wardell |
| author_sort | Simon J. Garden |
| collection | DOAJ |
| description | The complete molecule of the title diproline ester quinone, C18H22N2O6, is generated by a crystallographic twofold axis, which passes through the centre of the benzene ring. Both –CO2Me groups are orientated to the same side of the benzene ring, with the carbonyl groups pointing roughly towards each other. The conformation of the proline residue is an envelope. In the crystal, a three-dimensional network is sustained by C—H...O interactions involving both the quinone and carbonyl O atoms. |
| first_indexed | 2024-12-19T19:02:04Z |
| format | Article |
| id | doaj.art-b005e5f8be8a4c8d8b729b0fcecb53cb |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T19:02:04Z |
| publishDate | 2010-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-b005e5f8be8a4c8d8b729b0fcecb53cb2022-12-21T20:09:32ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-08-01668o2071o207110.1107/S1600536810027947Methyl 1-{4-[(S)-2-(methoxycarbonyl)pyrrolidin-1-yl]-3,6-dioxocyclohexa-1,4-dien-1-yl}pyrrolidine-2-carboxylateSimon J. GardenJanet M. S. SkakleEdward R. T. TiekinkJames L. WardellThe complete molecule of the title diproline ester quinone, C18H22N2O6, is generated by a crystallographic twofold axis, which passes through the centre of the benzene ring. Both –CO2Me groups are orientated to the same side of the benzene ring, with the carbonyl groups pointing roughly towards each other. The conformation of the proline residue is an envelope. In the crystal, a three-dimensional network is sustained by C—H...O interactions involving both the quinone and carbonyl O atoms.http://scripts.iucr.org/cgi-bin/paper?S1600536810027947 |
| spellingShingle | Simon J. Garden Janet M. S. Skakle Edward R. T. Tiekink James L. Wardell Methyl 1-{4-[(S)-2-(methoxycarbonyl)pyrrolidin-1-yl]-3,6-dioxocyclohexa-1,4-dien-1-yl}pyrrolidine-2-carboxylate Acta Crystallographica Section E |
| title | Methyl 1-{4-[(S)-2-(methoxycarbonyl)pyrrolidin-1-yl]-3,6-dioxocyclohexa-1,4-dien-1-yl}pyrrolidine-2-carboxylate |
| title_full | Methyl 1-{4-[(S)-2-(methoxycarbonyl)pyrrolidin-1-yl]-3,6-dioxocyclohexa-1,4-dien-1-yl}pyrrolidine-2-carboxylate |
| title_fullStr | Methyl 1-{4-[(S)-2-(methoxycarbonyl)pyrrolidin-1-yl]-3,6-dioxocyclohexa-1,4-dien-1-yl}pyrrolidine-2-carboxylate |
| title_full_unstemmed | Methyl 1-{4-[(S)-2-(methoxycarbonyl)pyrrolidin-1-yl]-3,6-dioxocyclohexa-1,4-dien-1-yl}pyrrolidine-2-carboxylate |
| title_short | Methyl 1-{4-[(S)-2-(methoxycarbonyl)pyrrolidin-1-yl]-3,6-dioxocyclohexa-1,4-dien-1-yl}pyrrolidine-2-carboxylate |
| title_sort | methyl 1 4 s 2 methoxycarbonyl pyrrolidin 1 yl 3 6 dioxocyclohexa 1 4 dien 1 yl pyrrolidine 2 carboxylate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810027947 |
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