5-(1,3-Dithiolo[4,5-d][1,3]dithiol-2-ylidene)-1,3-dithiolo[4,5-c][1,2,5]thiadiazole: an unsymmetrical tetrathiafulvalene with fused 1,2,5-thiadiazole and 1,3-dithiole rings
The title unsymmetrical tetrathiafulvalene (TTF), C7H2N2S7, contains fused 1,2,5-thiadiazole and 1,3-dithiole rings and is a component molecule for conducting organic solids. The TTF molecule is disordered crystallographically over two orientations related by an inversion center, where each site is...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-05-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809014184 |
| _version_ | 1818323422281728000 |
|---|---|
| author | Yoshiro Yamashita Masaaki Tomura |
| author_facet | Yoshiro Yamashita Masaaki Tomura |
| author_sort | Yoshiro Yamashita |
| collection | DOAJ |
| description | The title unsymmetrical tetrathiafulvalene (TTF), C7H2N2S7, contains fused 1,2,5-thiadiazole and 1,3-dithiole rings and is a component molecule for conducting organic solids. The TTF molecule is disordered crystallographically over two orientations related by an inversion center, where each site is half-occupied. The molecule is almost planar with an r.m.s. deviation of 0.096 Å. In the crystal structure, molecules are linked by short intermolecular S...S interactions [3.47 (2), 3.507 (8) and 3.517 (13) Å]. |
| first_indexed | 2024-12-13T11:12:26Z |
| format | Article |
| id | doaj.art-b010a187414a48a481690489b1adede0 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T11:12:26Z |
| publishDate | 2009-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-b010a187414a48a481690489b1adede02022-12-21T23:48:42ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-05-01655o1082o108210.1107/S16005368090141845-(1,3-Dithiolo[4,5-d][1,3]dithiol-2-ylidene)-1,3-dithiolo[4,5-c][1,2,5]thiadiazole: an unsymmetrical tetrathiafulvalene with fused 1,2,5-thiadiazole and 1,3-dithiole ringsYoshiro YamashitaMasaaki TomuraThe title unsymmetrical tetrathiafulvalene (TTF), C7H2N2S7, contains fused 1,2,5-thiadiazole and 1,3-dithiole rings and is a component molecule for conducting organic solids. The TTF molecule is disordered crystallographically over two orientations related by an inversion center, where each site is half-occupied. The molecule is almost planar with an r.m.s. deviation of 0.096 Å. In the crystal structure, molecules are linked by short intermolecular S...S interactions [3.47 (2), 3.507 (8) and 3.517 (13) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536809014184 |
| spellingShingle | Yoshiro Yamashita Masaaki Tomura 5-(1,3-Dithiolo[4,5-d][1,3]dithiol-2-ylidene)-1,3-dithiolo[4,5-c][1,2,5]thiadiazole: an unsymmetrical tetrathiafulvalene with fused 1,2,5-thiadiazole and 1,3-dithiole rings Acta Crystallographica Section E |
| title | 5-(1,3-Dithiolo[4,5-d][1,3]dithiol-2-ylidene)-1,3-dithiolo[4,5-c][1,2,5]thiadiazole: an unsymmetrical tetrathiafulvalene with fused 1,2,5-thiadiazole and 1,3-dithiole rings |
| title_full | 5-(1,3-Dithiolo[4,5-d][1,3]dithiol-2-ylidene)-1,3-dithiolo[4,5-c][1,2,5]thiadiazole: an unsymmetrical tetrathiafulvalene with fused 1,2,5-thiadiazole and 1,3-dithiole rings |
| title_fullStr | 5-(1,3-Dithiolo[4,5-d][1,3]dithiol-2-ylidene)-1,3-dithiolo[4,5-c][1,2,5]thiadiazole: an unsymmetrical tetrathiafulvalene with fused 1,2,5-thiadiazole and 1,3-dithiole rings |
| title_full_unstemmed | 5-(1,3-Dithiolo[4,5-d][1,3]dithiol-2-ylidene)-1,3-dithiolo[4,5-c][1,2,5]thiadiazole: an unsymmetrical tetrathiafulvalene with fused 1,2,5-thiadiazole and 1,3-dithiole rings |
| title_short | 5-(1,3-Dithiolo[4,5-d][1,3]dithiol-2-ylidene)-1,3-dithiolo[4,5-c][1,2,5]thiadiazole: an unsymmetrical tetrathiafulvalene with fused 1,2,5-thiadiazole and 1,3-dithiole rings |
| title_sort | 5 1 3 dithiolo 4 5 d 1 3 dithiol 2 ylidene 1 3 dithiolo 4 5 c 1 2 5 thiadiazole an unsymmetrical tetrathiafulvalene with fused 1 2 5 thiadiazole and 1 3 dithiole rings |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809014184 |
| work_keys_str_mv | AT yoshiroyamashita 513dithiolo45d13dithiol2ylidene13dithiolo45c125thiadiazoleanunsymmetricaltetrathiafulvalenewithfused125thiadiazoleand13dithiolerings AT masaakitomura 513dithiolo45d13dithiol2ylidene13dithiolo45c125thiadiazoleanunsymmetricaltetrathiafulvalenewithfused125thiadiazoleand13dithiolerings |