Influence of boron doping on characteristics of glucose-based hydrothermal carbons
In this study, the influence of boron doping on structural and surface properties of carbon material synthesized by a hydrothermal method was investigated, and the obtained results were compared with the previously published influence that boron has on characteristics of carbonized boron-doped hydro...
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| Format: | Article |
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Serbian Chemical Society
2022-01-01
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| Series: | Journal of the Serbian Chemical Society |
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| Online Access: | http://www.doiserbia.nb.rs/img/doi/0352-5139/2022/0352-51392200001K.pdf |
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| author | Kalijadis Ana M. Maletić Marina M. Bjelajac Anđelika Z. Babić Biljana M. Minović-Arsić Tamara Z. Vukčević Marija M. |
| author_facet | Kalijadis Ana M. Maletić Marina M. Bjelajac Anđelika Z. Babić Biljana M. Minović-Arsić Tamara Z. Vukčević Marija M. |
| author_sort | Kalijadis Ana M. |
| collection | DOAJ |
| description | In this study, the influence of boron doping on structural and surface properties of carbon material synthesized by a hydrothermal method was investigated, and the obtained results were compared with the previously published influence that boron has on characteristics of carbonized boron-doped hydrothermal carbons (CHTCB). Hydrothermal carbons doped with boron (HTCB) were obtained by the hydrothermal synthesis of glucose solutions with different nominal concentrations of boric acid. It was found that glucose based hydrothermal carbon does not have developed porosity, and the presence of boron in their structure has insignificant influence on it. On the contrary, additional carbonization increases the specific surface area of the undoped sample, while an increase in boron content drastically decreases the specific surface area. Boron doping leads to a decrease in the amount of surface oxygen groups, for both, hydrothermally synthesized and additionally carbonized materials. Raman analysis showed that the boron content does not affect a structural arrangement of the HTCB samples, and Raman structural parameters show a higher degree of disorder, compared to the CHTCB samples. Comparison of structural and surface characteristics of hydrothermal carbons and carbonized materials contributes to the study of the so far, insufficiently clarified influence that boron incorporation has on the material characteristics. |
| first_indexed | 2024-04-13T10:40:39Z |
| format | Article |
| id | doaj.art-b037e92dc49d4f998506c027ac2586d1 |
| institution | Directory Open Access Journal |
| issn | 0352-5139 1820-7421 |
| language | English |
| last_indexed | 2024-04-13T10:40:39Z |
| publishDate | 2022-01-01 |
| publisher | Serbian Chemical Society |
| record_format | Article |
| series | Journal of the Serbian Chemical Society |
| spelling | doaj.art-b037e92dc49d4f998506c027ac2586d12022-12-22T02:49:56ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51391820-74212022-01-0187674976010.2298/JSC211011001K0352-51392200001KInfluence of boron doping on characteristics of glucose-based hydrothermal carbonsKalijadis Ana M.0https://orcid.org/0000-0002-6897-4691Maletić Marina M.1https://orcid.org/0000-0002-4112-9316Bjelajac Anđelika Z.2https://orcid.org/0000-0001-5893-156XBabić Biljana M.3https://orcid.org/0000-0002-6269-7822Minović-Arsić Tamara Z.4https://orcid.org/0000-0002-2957-5372Vukčević Marija M.5https://orcid.org/0000-0003-0416-0741Department of Materials „Vinča” Institute of Nuclear Sciences, National Institute of thе Republic of Serbia, University of Belgrade, Belgrade, SerbiaInnovation Center of the Faculty of Technology and Metallurgy, Belgrade, SerbiaInnovation Center of the Faculty of Technology and Metallurgy, Belgrade, Serbia + C2N - Centre for Nanoscience and Nano-technology Universite Paris-Saclay, Palaiseau, FranceInstitute of Physics, National Institute of thе Republic of Serbia, University of Belgrade, Belgrade, SerbiaDepartment of Materials „Vinča” Institute of Nuclear Sciences, National Institute of thе Republic of Serbia, University of Belgrade, Belgrade, SerbiaFaculty of Technology and Metallurgy, University of Belgrade, Belgrade, SerbiaIn this study, the influence of boron doping on structural and surface properties of carbon material synthesized by a hydrothermal method was investigated, and the obtained results were compared with the previously published influence that boron has on characteristics of carbonized boron-doped hydrothermal carbons (CHTCB). Hydrothermal carbons doped with boron (HTCB) were obtained by the hydrothermal synthesis of glucose solutions with different nominal concentrations of boric acid. It was found that glucose based hydrothermal carbon does not have developed porosity, and the presence of boron in their structure has insignificant influence on it. On the contrary, additional carbonization increases the specific surface area of the undoped sample, while an increase in boron content drastically decreases the specific surface area. Boron doping leads to a decrease in the amount of surface oxygen groups, for both, hydrothermally synthesized and additionally carbonized materials. Raman analysis showed that the boron content does not affect a structural arrangement of the HTCB samples, and Raman structural parameters show a higher degree of disorder, compared to the CHTCB samples. Comparison of structural and surface characteristics of hydrothermal carbons and carbonized materials contributes to the study of the so far, insufficiently clarified influence that boron incorporation has on the material characteristics.http://www.doiserbia.nb.rs/img/doi/0352-5139/2022/0352-51392200001K.pdfhydrothermal synthesisboric acidraman analysisspecific surface areasurface oxygen groups |
| spellingShingle | Kalijadis Ana M. Maletić Marina M. Bjelajac Anđelika Z. Babić Biljana M. Minović-Arsić Tamara Z. Vukčević Marija M. Influence of boron doping on characteristics of glucose-based hydrothermal carbons Journal of the Serbian Chemical Society hydrothermal synthesis boric acid raman analysis specific surface area surface oxygen groups |
| title | Influence of boron doping on characteristics of glucose-based hydrothermal carbons |
| title_full | Influence of boron doping on characteristics of glucose-based hydrothermal carbons |
| title_fullStr | Influence of boron doping on characteristics of glucose-based hydrothermal carbons |
| title_full_unstemmed | Influence of boron doping on characteristics of glucose-based hydrothermal carbons |
| title_short | Influence of boron doping on characteristics of glucose-based hydrothermal carbons |
| title_sort | influence of boron doping on characteristics of glucose based hydrothermal carbons |
| topic | hydrothermal synthesis boric acid raman analysis specific surface area surface oxygen groups |
| url | http://www.doiserbia.nb.rs/img/doi/0352-5139/2022/0352-51392200001K.pdf |
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