Geometry, Extent, and Chemistry of Fermentative Hot Spots in Municipal Waste Souk Sebt Landfill, Ouled Nemma, Beni Mellal, Morocco

The presence of fermentative hotspots in municipal waste dumps has been reported for several decades, but no study has focused on their size and shape. The uncontrolled landfill of Soub Sekt, covering an area of about 8 hectares in the Tadla plain in Morocco, is the source of a permanent pollution p...

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Main Authors: Yousra El Mouine, Amal El Hamdi, Abderrahim Bousouis, Youssouf El Jarjini, Meryem Touzani, Vincent Valles, Laurent Barbiero, Moad Morarech
Format: Article
Language:English
Published: MDPI AG 2024-03-01
Series:Water
Subjects:
Online Access:https://www.mdpi.com/2073-4441/16/6/795
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author Yousra El Mouine
Amal El Hamdi
Abderrahim Bousouis
Youssouf El Jarjini
Meryem Touzani
Vincent Valles
Laurent Barbiero
Moad Morarech
author_facet Yousra El Mouine
Amal El Hamdi
Abderrahim Bousouis
Youssouf El Jarjini
Meryem Touzani
Vincent Valles
Laurent Barbiero
Moad Morarech
author_sort Yousra El Mouine
collection DOAJ
description The presence of fermentative hotspots in municipal waste dumps has been reported for several decades, but no study has focused on their size and shape. The uncontrolled landfill of Soub Sekt, covering an area of about 8 hectares in the Tadla plain in Morocco, is the source of a permanent pollution plume in the groundwater, detected by self-potential (SP) measurements. The study aims to detect and characterize these hotspots as well as the leachates that form within them. These hotspots are typically circular and smaller than 3 m in size, and they are concentrated within recent waste deposits. Intense electron transfer activities, particularly during redox reactions leading to metal solubilization, result in very low SP values (down to −60 mV), facilitating their detection. Several successive field campaigns suggest that they are active for 2–3 weeks. Due to the low permeability of the soils, highly mineralized leachates (average Electrical Conductivity 45 mS cm<sup>−1</sup>) rich in organic ions accumulate on the soil surface at the base of the waste windrows. There, they evolve by concentration due to evaporation and oxidation due to slow diffusion of atmospheric O<sub>2</sub>. Despite the small size of the hotspots generating the leachates, the accumulation of leachates in ponds and the low soil permeability limits the percolation rate, resulting in moderate but permanent groundwater pollution.
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spelling doaj.art-b0770fd88cf1428d8fca8ff9ea26b72d2024-03-27T14:08:09ZengMDPI AGWater2073-44412024-03-0116679510.3390/w16060795Geometry, Extent, and Chemistry of Fermentative Hot Spots in Municipal Waste Souk Sebt Landfill, Ouled Nemma, Beni Mellal, MoroccoYousra El Mouine0Amal El Hamdi1Abderrahim Bousouis2Youssouf El Jarjini3Meryem Touzani4Vincent Valles5Laurent Barbiero6Moad Morarech7Laboratory Mediterranean Environment and Agro-Hydrosystem Modelling (UMR 1114 EMMAH), Hydrogeology Department, Avignon University, 84000 Avignon, FranceLaboratory Mediterranean Environment and Agro-Hydrosystem Modelling (UMR 1114 EMMAH), Hydrogeology Department, Avignon University, 84000 Avignon, FranceLaboratoire de Géosciences, Faculté des Sciences, Université Ibn Tofaïl, BP 133, Kénitra 14000, MoroccoLaboratory in Applied and Marine Geosciences, Geotechnics and Georisk (LR3G), Faculty of Science Tetouan, Abdelmalek Essaâdi University, Tetouan 93002, MoroccoNational Institute of Agronomic Research, Rabat 10060, MoroccoLaboratory Mediterranean Environment and Agro-Hydrosystem Modelling (UMR 1114 EMMAH), Hydrogeology Department, Avignon University, 84000 Avignon, FranceInstitut de Recherche pour le Développement, Géoscience Environnement Toulouse, CNRS, University of Toulouse, Observatoire Midi-Pyrénées, UMR 5563, 14 Avenue Edouard Belin, 31400 Toulouse, FranceLaboratory in Applied and Marine Geosciences, Geotechnics and Georisk (LR3G), Faculty of Science Tetouan, Abdelmalek Essaâdi University, Tetouan 93002, MoroccoThe presence of fermentative hotspots in municipal waste dumps has been reported for several decades, but no study has focused on their size and shape. The uncontrolled landfill of Soub Sekt, covering an area of about 8 hectares in the Tadla plain in Morocco, is the source of a permanent pollution plume in the groundwater, detected by self-potential (SP) measurements. The study aims to detect and characterize these hotspots as well as the leachates that form within them. These hotspots are typically circular and smaller than 3 m in size, and they are concentrated within recent waste deposits. Intense electron transfer activities, particularly during redox reactions leading to metal solubilization, result in very low SP values (down to −60 mV), facilitating their detection. Several successive field campaigns suggest that they are active for 2–3 weeks. Due to the low permeability of the soils, highly mineralized leachates (average Electrical Conductivity 45 mS cm<sup>−1</sup>) rich in organic ions accumulate on the soil surface at the base of the waste windrows. There, they evolve by concentration due to evaporation and oxidation due to slow diffusion of atmospheric O<sub>2</sub>. Despite the small size of the hotspots generating the leachates, the accumulation of leachates in ponds and the low soil permeability limits the percolation rate, resulting in moderate but permanent groundwater pollution.https://www.mdpi.com/2073-4441/16/6/795self-potentialredox potentialleachate plumelandfillTadlaMorocco
spellingShingle Yousra El Mouine
Amal El Hamdi
Abderrahim Bousouis
Youssouf El Jarjini
Meryem Touzani
Vincent Valles
Laurent Barbiero
Moad Morarech
Geometry, Extent, and Chemistry of Fermentative Hot Spots in Municipal Waste Souk Sebt Landfill, Ouled Nemma, Beni Mellal, Morocco
Water
self-potential
redox potential
leachate plume
landfill
Tadla
Morocco
title Geometry, Extent, and Chemistry of Fermentative Hot Spots in Municipal Waste Souk Sebt Landfill, Ouled Nemma, Beni Mellal, Morocco
title_full Geometry, Extent, and Chemistry of Fermentative Hot Spots in Municipal Waste Souk Sebt Landfill, Ouled Nemma, Beni Mellal, Morocco
title_fullStr Geometry, Extent, and Chemistry of Fermentative Hot Spots in Municipal Waste Souk Sebt Landfill, Ouled Nemma, Beni Mellal, Morocco
title_full_unstemmed Geometry, Extent, and Chemistry of Fermentative Hot Spots in Municipal Waste Souk Sebt Landfill, Ouled Nemma, Beni Mellal, Morocco
title_short Geometry, Extent, and Chemistry of Fermentative Hot Spots in Municipal Waste Souk Sebt Landfill, Ouled Nemma, Beni Mellal, Morocco
title_sort geometry extent and chemistry of fermentative hot spots in municipal waste souk sebt landfill ouled nemma beni mellal morocco
topic self-potential
redox potential
leachate plume
landfill
Tadla
Morocco
url https://www.mdpi.com/2073-4441/16/6/795
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