(1R,2S,4S,4aS,8S,8aS)-4-Hydroxy-8,8a-dimethyl-10-oxo-2,3,4,7,8,8a-hexahydro-1H-4a,1-(epoxymethano)naphthalen-2-yl acetate
The title compound, C15H20O5, presents a bisnorsesquiterpene skeleton, with a trans-decaline backbone constrained by the lactone bridge. The α-hydroxy substituent and the methyl group belonging to the two decaline rings are in axial positions, whereas the other methyl group and the acyl gro...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2013-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813013524 |
| _version_ | 1818971570674073600 |
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| author | Ouassila Selaïmia-Ferdjani Chahra Bidjou-Haiour Aurelien Planchat Muriel Pipelier |
| author_facet | Ouassila Selaïmia-Ferdjani Chahra Bidjou-Haiour Aurelien Planchat Muriel Pipelier |
| author_sort | Ouassila Selaïmia-Ferdjani |
| collection | DOAJ |
| description | The title compound, C15H20O5, presents a bisnorsesquiterpene skeleton, with a trans-decaline backbone constrained by the lactone bridge. The α-hydroxy substituent and the methyl group belonging to the two decaline rings are in axial positions, whereas the other methyl group and the acyl group occupy the sterically preferred equatorial positions. The molecular structure is stabilized by an intramolecular C—H...O hydrogen bond. In the crystal, molecules are linked into chains along [010] by O—H...O hydrogen bonds |
| first_indexed | 2024-12-20T14:54:29Z |
| format | Article |
| id | doaj.art-b07c5fa869a344f2ad0878f781d2c206 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T14:54:29Z |
| publishDate | 2013-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-b07c5fa869a344f2ad0878f781d2c2062022-12-21T19:36:54ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-06-01696o938o93910.1107/S1600536813013524(1R,2S,4S,4aS,8S,8aS)-4-Hydroxy-8,8a-dimethyl-10-oxo-2,3,4,7,8,8a-hexahydro-1H-4a,1-(epoxymethano)naphthalen-2-yl acetateOuassila Selaïmia-FerdjaniChahra Bidjou-HaiourAurelien PlanchatMuriel PipelierThe title compound, C15H20O5, presents a bisnorsesquiterpene skeleton, with a trans-decaline backbone constrained by the lactone bridge. The α-hydroxy substituent and the methyl group belonging to the two decaline rings are in axial positions, whereas the other methyl group and the acyl group occupy the sterically preferred equatorial positions. The molecular structure is stabilized by an intramolecular C—H...O hydrogen bond. In the crystal, molecules are linked into chains along [010] by O—H...O hydrogen bondshttp://scripts.iucr.org/cgi-bin/paper?S1600536813013524 |
| spellingShingle | Ouassila Selaïmia-Ferdjani Chahra Bidjou-Haiour Aurelien Planchat Muriel Pipelier (1R,2S,4S,4aS,8S,8aS)-4-Hydroxy-8,8a-dimethyl-10-oxo-2,3,4,7,8,8a-hexahydro-1H-4a,1-(epoxymethano)naphthalen-2-yl acetate Acta Crystallographica Section E |
| title | (1R,2S,4S,4aS,8S,8aS)-4-Hydroxy-8,8a-dimethyl-10-oxo-2,3,4,7,8,8a-hexahydro-1H-4a,1-(epoxymethano)naphthalen-2-yl acetate |
| title_full | (1R,2S,4S,4aS,8S,8aS)-4-Hydroxy-8,8a-dimethyl-10-oxo-2,3,4,7,8,8a-hexahydro-1H-4a,1-(epoxymethano)naphthalen-2-yl acetate |
| title_fullStr | (1R,2S,4S,4aS,8S,8aS)-4-Hydroxy-8,8a-dimethyl-10-oxo-2,3,4,7,8,8a-hexahydro-1H-4a,1-(epoxymethano)naphthalen-2-yl acetate |
| title_full_unstemmed | (1R,2S,4S,4aS,8S,8aS)-4-Hydroxy-8,8a-dimethyl-10-oxo-2,3,4,7,8,8a-hexahydro-1H-4a,1-(epoxymethano)naphthalen-2-yl acetate |
| title_short | (1R,2S,4S,4aS,8S,8aS)-4-Hydroxy-8,8a-dimethyl-10-oxo-2,3,4,7,8,8a-hexahydro-1H-4a,1-(epoxymethano)naphthalen-2-yl acetate |
| title_sort | 1r 2s 4s 4as 8s 8as 4 hydroxy 8 8a dimethyl 10 oxo 2 3 4 7 8 8a hexahydro 1h 4a 1 epoxymethano naphthalen 2 yl acetate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813013524 |
| work_keys_str_mv | AT ouassilasela239miaferdjani 1r2s4s4as8s8as4hydroxy88adimethyl10oxo234788ahexahydro1h4a1epoxymethanonaphthalen2ylacetate AT chahrabidjouhaiour 1r2s4s4as8s8as4hydroxy88adimethyl10oxo234788ahexahydro1h4a1epoxymethanonaphthalen2ylacetate AT aurelienplanchat 1r2s4s4as8s8as4hydroxy88adimethyl10oxo234788ahexahydro1h4a1epoxymethanonaphthalen2ylacetate AT murielpipelier 1r2s4s4as8s8as4hydroxy88adimethyl10oxo234788ahexahydro1h4a1epoxymethanonaphthalen2ylacetate |