(1R,2S,4S,4aS,8S,8aS)-4-Hydroxy-8,8a-dimethyl-10-oxo-2,3,4,7,8,8a-hexahydro-1H-4a,1-(epoxymethano)naphthalen-2-yl acetate

(1R,2S,4S,4aS,8S,8aS)-4-Hydroxy-8,8a-dimethyl-10-oxo-2,3,4,7,8,8a-hexahydro-1H-4a,1-(epoxymethano)naphthalen-2-yl acetate

The title compound, C15H20O5, presents a bisnorsesquiterpene skeleton, with a trans-decaline backbone constrained by the lactone bridge. The α-hydroxy substituent and the methyl group belonging to the two decaline rings are in axial positions, whereas the other methyl group and the acyl gro...

Full description

Bibliographic Details
Main Authors:	Ouassila Selaïmia-Ferdjani, Chahra Bidjou-Haiour, Aurelien Planchat, Muriel Pipelier
Format:	Article
Language:	English
Published:	International Union of Crystallography 2013-06-01
Series:	Acta Crystallographica Section E
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S1600536813013524

Similar Items

Ethyl (4aR*,7S*,8S*,8aS*)-1-oxo-7-phenyl-3,4,4a,7,8,8a-hexahydro-1H-isochromene-8-carboxylate
by: Xiu Qing Jiang, et al.
Published: (2010-06-01)

Crystal structure of (c-4a,c-8a)-1,4,4a,5,8,8a-hexahydro- 1,4,10,10-tetramethyl-r-1 ,c-4:t-5,t-8- dimethanophthalazine, [C7H8] [C3N2(CH3)4]
by: Peters K., et al.
Published: (2000-02-01)

Diethyl 1-benzyl-2,2-dioxo-4-phenyl-3,4,6,7,8,8a-hexahydro-1H-pyrrolo[2,1-c][1,4]thiazine-1,3-dicarboxylate
by: A. Chitradevi, et al.
Published: (2011-09-01)

8,8-Diethyl-1,4,5,8-tetrahydronaphthalene-1,4,5-trione
by: Ramiro Araya-Maturana, et al.
Published: (2009-02-01)

2-{1-[2,8-Bis(trifluoromethyl)quinolin-4-yl]-3,5,6,7,8,8a-hexahydro-1H-1,3-oxazolo[3,4-a]pyridin-3-yl}phenol
by: Raoni S. B. Gon&#231;alves, et al.
Published: (2011-07-01)

(±)-(4aR,5R,8S,8aR)-8-(tert-Butyldimethylsilyloxy)-2,5,8a-trimethyl-4a,5,8,8a-tetrahydronaphthalene-1,4-dione
by: Fernanda G. Finelli, et al.
Published: (2013-03-01)

(4bS,8aS)-1-Isopropyl-4b,8,8-trimethyl-4b,5,6,7,8,8a,9,10-octahydrophenanthren-2-yl benzoate
by: Radouane Oubabi, et al.
Published: (2014-08-01)

(4R,6S,7S,8S,8aS)-6-Ethyl-7,8-dihydroxy-4-methyl-1,2,3,5,6,7,8,8a-octahydroindolizin-4-ium iodide
by: Viktor Vr&#225;bel, et al.
Published: (2011-12-01)

8-(2-Chlorophenyl)-1-(4-chlorophenyl)-4-[(E)-(2-chlorophenyl)methylidene]-6-methyl-4,5,6,7,7a,8-hexahydro-1,2,4-oxadiazolo[5,4-d]pyrido[3,4-c][1,5]benzothiazepine
by: V. Rajni Swamy, et al.
Published: (2010-05-01)

3-(4-Chlorophenyl)-1-[(2R,4aR,8aR)-4a,8-dimethyl-1,2,3,4,4a,5,6,8a-octahydronaphthalen-2-yl]prop-2-en-1-one
by: Mohamed Tebbaa, et al.
Published: (2011-06-01)

4,4&#8242;-(1,8-Naphthalene-1,8-diyl)dibenzonitrile
by: John Nicolson Low, et al.
Published: (2011-01-01)

1,4,8,11-Tetraazoniacyclotetradecane tetrakis(hydrogensulfate)
by: Houcine Naïli, et al.
Published: (2013-08-01)

(4,7,13,16,21,24-Hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane-κ8N2,O6)rubidium 4,4′-bipyridinidyl
by: Kerstin Mayer, et al.
Published: (2016-03-01)

Redetermination of 1,3,6,8-tetraazatricyclo[4.4.1.13,8]dodecane
by: Augusto Rivera, et al.
Published: (2014-03-01)

Crystal structures of sulfonamide protected bicyclic guanidines: (S)-8-{[(tert-butyldimethylsilyl)oxy]methyl}-1-[(2,2,4,6,7-pentamethyl-2,3-dihydrobenzofuran-5-yl)sulfonyl]-1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidin-1-ium trifluoromethanesulfonate and (S)-8-(iodomethyl)-1-tosyl-1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidin-1-ium iodide
by: Jamal M. H. Alaboosh, et al.
Published: (2024-03-01)

1-(4a,8-Dimethyl-1,2,3,4,4a,5,6,8a-octahydronaphthalen-2-yl)-3-phenylprop-2-en-1-one
by: Mohamed Tebbaa, et al.
Published: (2011-04-01)

(4aR*,8aS*)-2,3-Diphenyl-4a,5,6,7,8,8a-hexahydroquinoxaline
by: W. Chen, et al.
Published: (2012-07-01)

1-Dichloroacetyl-8a-methyl-1,2,3,4,6,7,8,8a-octahydropyrrolo[1,2-a]pyrimidin-6-one
by: Shuang Gao, et al.
Published: (2012-07-01)

Isomorphous diethyl 1-(4-chlorobenzyl)-4-(4-chlorophenyl)-2,2-dioxo-3,4,6,7,8,8a-hexahydro-1H-pyrrolo[2,1-c][1,4]thiazine-1,3-dicarboxylate and its 1-(4-methylbenzyl)-4-(4-methylphenyl)-substituted analogue obeying the chloro–methyl exchange rule
by: R. Sribala, et al.
Published: (2018-09-01)

8-Methyl-3-methylsulfanyl-8a,8b-dihydro-5H-1-oxa-2,4-diazaacenaphthylene
by: Akoun Abou, et al.
Published: (2021-06-01)

The crystal structure of 1,2-dimethyl-3,4-dinitrobenzene, C8H8N2O4
by: Fanfan Shen, et al.
Published: (2019-03-01)

4-(4-Chlorophenyl)-8-methyl-2-oxo-1,2,5,6,7,8-hexahydroquinoline-3-carbonitrile
by: Khadija O. Badahdah, et al.
Published: (2011-10-01)

8-(4-Chlorobenzylidene)-4-(4-chlorophenyl)-2-phenyl-5,6,7,8-tetrahydroquinoline
by: Fangfang Jian, et al.
Published: (2010-06-01)

Evaluation of the Antioxidant Activity of <i>Cis</i>/<i>Trans</i>-<i>N</i>-Phenyl-1,4,4a,5,8,8a-Hexahydro-3,1-Benzoxazin-2-Imines
by: Guadalupe Firpo, et al.
Published: (2019-06-01)

(4aR,8aR)-2,3-Diphenyl-4a,5,6,7,8,8a-hexahydroquinoxaline
by: Heng-Yun Ye, et al.
Published: (2008-02-01)

Crystal structure of 1-benzoylamino-8a-hydroperoxy-1,5,6,7,8,8a-hexahydro- 4H-cyclohepta[c]isothiazole 2,2-dioxide, C15H18N2O5S
by: Kolberg A., et al.
Published: (2001-04-01)

3,6-DIDEOXY-3,6-IMINO-1,2-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSE AS A DIVERGENT INTERMEDIATE FOR THE SYNTHESIS OF HYDROXYLATED PYRROLIDINES - SYNTHESIS OF 1,4-DIDEOXY-1,4-IMINO-L-GULITOL, 1,4-DIDEOXY-1,4-IMINO-D-LYXITOL, 2S,3S,4R-3,4-DIHYDROXYPROLINE AND (1S,2R,8S,8AR)-1,2,8-TRIHYDROXYOCTAHYDROINDOLIZINE [8-EPI-SWAINSONINE] - X-RAY CRYSTAL-STRUCTURE OF (1S,2R,8S,8AR)-1,2,8-TRIHYDROXY-5-OXO-OCTAHYDROINDOLIZINE
by: Austin, G, et al.
Published: (1987)

Crystal structure of (1,10-phenanthroline) (tetrafluorophtahlato) copper(II), [Cu(C8F4O4)(C12H8N2)2](C8H2F4O4), C40H18CuF8N4O8
by: Zhang Jun, et al.
Published: (2012-12-01)

Crystal structure of 1,4:5,8-dimethano-1,1a,4,4a,5,5a,8,8a-octahydroanthracene- 9,10-dione, C16H16O2
by: Soylu B. GüneS, et al.
Published: (1999-03-01)

8-(Pyrimidin-2-yl)-1,2,3,4,5,6,7,8-heptathiazocane
by: Vladimir A. Ogurtsov, et al.
Published: (2019-11-01)

(2RS,8aRS)-6-Oxo-1,2,3,4,6,7,8,8a-octahydronaphthalene-2-carboxylic acid
by: Hugh W. Thompson, et al.
Published: (2008-12-01)

2,6-Bis(2-chloroethyl)-8b,8c-diphenylperhydro-2,3a,4a,6,7a,8a-hexaazacyclopenta[def]fluorene-4,8-dithione
by: Yandong Wu, et al.
Published: (2009-07-01)

2,6-Bis(2-hydroxyethyl)-8b,8c-diphenylperhydro-2,3a,4a,6,7a,8a-hexaazacyclopenta[def]fluorene-4,8-dithione
by: Zihua Wang, et al.
Published: (2009-06-01)

1,4,5,8-Tetraisopropylanthracene
by: Chitoshi Kitamura, et al.
Published: (2010-09-01)

Dipropyl 4,8-dioxo-1H,5H-2,6-dioxa-3a,4a,7a,8a-tetraazacyclopenta[def]fluorene-8b,8c-dicarboxylate
by: Shuai Wang, et al.
Published: (2008-01-01)

(4aS,5R,7R,8S,8aR)-8-(1,3-Dioxolan-2-yl)-7,8-dimethyl-5-(1-methylethenyl)perhydronaphthalen-2-one
by: Maxime A. Siegler, et al.
Published: (2008-01-01)

SYNTHESIS OF THE ALPHA-MANNOSIDASE INHIBITORS SWAINSONINE [(1S, 2R, 8R, 8AR)-1,2,8-TRIHYDROXYOCTAHYDROINDOLIZINE] AND 1,4-DIDEOXY-1,4-IMINO-D-MANNITOL FROM MANNOSE
by: Bashyal, B, et al.
Published: (1987)

rac-(4aR,8aR)-2,3-Diphenyl-4a,5,6,7,8,8a-hexahydroquinoxaline
by: Fang Chen, et al.
Published: (2008-07-01)

Ethyl 5-cyano-8-nitro-2,3,4,4a,5,6-hexahydro-1H-pyrido[1,2-a]quinoline-5-carboxylate
by: Yapi Marcellin Yapo, et al.
Published: (2010-07-01)

Diethyl 2,6-(2,4-dichlorophenyl)-4,8-dioxo-2,3,6,7-tetrahydro-1H,5H-2,3a,4a,6,7a,8a-hexaazacyclopenta[def]fluorene-8b,8c-dicarboxylate
by: Jiao-yang Ding, et al.
Published: (2009-04-01)