The Catalytic Effect from Alkaline Elements on the Tar-Rich Coal Pyrolysis
Tar-rich coal has been widely concerned because of its high tar yield. Two kinds of tar-rich coals were studied by Thermogravimetric-Mass spectrometer-Fourier transform infrared (TG-MS-FTIR) to obtain the pyrolysis characteristics. TG-MS-FTIR was used to study the mass loss, gaseous compounds evolut...
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MDPI AG
2022-03-01
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| Series: | Catalysts |
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| Online Access: | https://www.mdpi.com/2073-4344/12/4/376 |
| _version_ | 1797436497177083904 |
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| author | Zhonghua Du Wu Li |
| author_facet | Zhonghua Du Wu Li |
| author_sort | Zhonghua Du |
| collection | DOAJ |
| description | Tar-rich coal has been widely concerned because of its high tar yield. Two kinds of tar-rich coals were studied by Thermogravimetric-Mass spectrometer-Fourier transform infrared (TG-MS-FTIR) to obtain the pyrolysis characteristics. TG-MS-FTIR was used to study the mass loss, gaseous compounds evolution, and functional group information of tar-rich coal during pyrolysis. Mass loss is mainly caused by water release and macromolecular decomposition. The results showed that there were two stages of mass loss in the pyrolysis process. In addition, the gas release signal detected by mass spectrometry is consistent with the functional group information detected by FTIR. The main gaseous products include H<sub>2</sub>, H<sub>2</sub>O, CO, CO<sub>2</sub>, and CH<sub>4</sub>. In addition, the effect of ash content on the pyrolysis of oil-rich coal and the catalytic effect of internal minerals on coal pyrolysis are also discussed, and the thermal pyrolysis characteristics of coke-rich oil coal are put forward. The results provide a new idea for the study of pyrolysis characteristics of tar-rich coal. |
| first_indexed | 2024-03-09T11:02:27Z |
| format | Article |
| id | doaj.art-b083b0fc7e6a401fa00b9b6440ca9bcb |
| institution | Directory Open Access Journal |
| issn | 2073-4344 |
| language | English |
| last_indexed | 2024-03-09T11:02:27Z |
| publishDate | 2022-03-01 |
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| spelling | doaj.art-b083b0fc7e6a401fa00b9b6440ca9bcb2023-12-01T01:10:24ZengMDPI AGCatalysts2073-43442022-03-0112437610.3390/catal12040376The Catalytic Effect from Alkaline Elements on the Tar-Rich Coal PyrolysisZhonghua Du0Wu Li1Key Laboratory of Coalbed Methane Resource & Reservoir Formation Process, Ministry of Education, China University of Mining and Technology, Xuzhou 221008, ChinaKey Laboratory of Coalbed Methane Resource & Reservoir Formation Process, Ministry of Education, China University of Mining and Technology, Xuzhou 221008, ChinaTar-rich coal has been widely concerned because of its high tar yield. Two kinds of tar-rich coals were studied by Thermogravimetric-Mass spectrometer-Fourier transform infrared (TG-MS-FTIR) to obtain the pyrolysis characteristics. TG-MS-FTIR was used to study the mass loss, gaseous compounds evolution, and functional group information of tar-rich coal during pyrolysis. Mass loss is mainly caused by water release and macromolecular decomposition. The results showed that there were two stages of mass loss in the pyrolysis process. In addition, the gas release signal detected by mass spectrometry is consistent with the functional group information detected by FTIR. The main gaseous products include H<sub>2</sub>, H<sub>2</sub>O, CO, CO<sub>2</sub>, and CH<sub>4</sub>. In addition, the effect of ash content on the pyrolysis of oil-rich coal and the catalytic effect of internal minerals on coal pyrolysis are also discussed, and the thermal pyrolysis characteristics of coke-rich oil coal are put forward. The results provide a new idea for the study of pyrolysis characteristics of tar-rich coal.https://www.mdpi.com/2073-4344/12/4/376tar-rich coalpyrolysisTG-MS-FTIRcatalysis |
| spellingShingle | Zhonghua Du Wu Li The Catalytic Effect from Alkaline Elements on the Tar-Rich Coal Pyrolysis Catalysts tar-rich coal pyrolysis TG-MS-FTIR catalysis |
| title | The Catalytic Effect from Alkaline Elements on the Tar-Rich Coal Pyrolysis |
| title_full | The Catalytic Effect from Alkaline Elements on the Tar-Rich Coal Pyrolysis |
| title_fullStr | The Catalytic Effect from Alkaline Elements on the Tar-Rich Coal Pyrolysis |
| title_full_unstemmed | The Catalytic Effect from Alkaline Elements on the Tar-Rich Coal Pyrolysis |
| title_short | The Catalytic Effect from Alkaline Elements on the Tar-Rich Coal Pyrolysis |
| title_sort | catalytic effect from alkaline elements on the tar rich coal pyrolysis |
| topic | tar-rich coal pyrolysis TG-MS-FTIR catalysis |
| url | https://www.mdpi.com/2073-4344/12/4/376 |
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