Sol-gel Preparation of Photocatalytic Sm2Ti2O7/HZSM-5 Composite on Degradation of Reactive Brilliant Red X-3B
Sm<sub>2</sub>Ti<sub>2</sub>O<sub>7</sub> was loaded on the surface of HZSM-5 zeolite through a sol-gel route. HZSM-5 particles were coated with a thick layer of Sm<sub>2</sub>Ti<sub>2</sub>O<sub>7</sub> to form the composite. I...
Main Authors: | , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Kaunas University of Technology
2018-08-01
|
Series: | Medžiagotyra |
Subjects: | |
Online Access: | http://matsc.ktu.lt/index.php/MatSc/article/view/18853 |
_version_ | 1831839314003099648 |
---|---|
author | Wenjie ZHANG Yuxuan LIU Ling DU |
author_facet | Wenjie ZHANG Yuxuan LIU Ling DU |
author_sort | Wenjie ZHANG |
collection | DOAJ |
description | Sm<sub>2</sub>Ti<sub>2</sub>O<sub>7</sub> was loaded on the surface of HZSM-5 zeolite through a sol-gel route. HZSM-5 particles were coated with a thick layer of Sm<sub>2</sub>Ti<sub>2</sub>O<sub>7</sub> to form the composite. It was found that crystallization of pyrochlore phase Sm<sub>2</sub>Ti<sub>2</sub>O<sub>7</sub> begins at 800 °C. Continuous enlargement in Sm<sub>2</sub>Ti<sub>2</sub>O<sub>7</sub> crystallite size and cell volume are accompanied with the increase of calcination temperature. The bandgap energy of the samples calcined at temperature ranging from 600 to 1000 °C was found to be around 3.4 eV. BET specific surface area and pore volume of the materials continuously decreased with rising calcination temperature. The 70 % Sm<sub>2</sub>Ti<sub>2</sub>O<sub>7</sub>/HZSM-5 calcined at 800 °C was found to have the greatest photocatalytic activity on RBR X-3B degradation.<p>DOI: <a href="http://dx.doi.org/10.5755/j01.ms.24.3.18853">http://dx.doi.org/10.5755/j01.ms.24.3.18853</a></p> |
first_indexed | 2024-12-23T05:51:24Z |
format | Article |
id | doaj.art-b0d3b38c5ee7456ea23d9e6f958071cc |
institution | Directory Open Access Journal |
issn | 1392-1320 2029-7289 |
language | English |
last_indexed | 2024-12-23T05:51:24Z |
publishDate | 2018-08-01 |
publisher | Kaunas University of Technology |
record_format | Article |
series | Medžiagotyra |
spelling | doaj.art-b0d3b38c5ee7456ea23d9e6f958071cc2022-12-21T17:57:57ZengKaunas University of TechnologyMedžiagotyra1392-13202029-72892018-08-0124330731110.5755/j01.ms.24.3.188539141Sol-gel Preparation of Photocatalytic Sm2Ti2O7/HZSM-5 Composite on Degradation of Reactive Brilliant Red X-3BWenjie ZHANG0Yuxuan LIULing DUShenyang Ligong UniversitySm<sub>2</sub>Ti<sub>2</sub>O<sub>7</sub> was loaded on the surface of HZSM-5 zeolite through a sol-gel route. HZSM-5 particles were coated with a thick layer of Sm<sub>2</sub>Ti<sub>2</sub>O<sub>7</sub> to form the composite. It was found that crystallization of pyrochlore phase Sm<sub>2</sub>Ti<sub>2</sub>O<sub>7</sub> begins at 800 °C. Continuous enlargement in Sm<sub>2</sub>Ti<sub>2</sub>O<sub>7</sub> crystallite size and cell volume are accompanied with the increase of calcination temperature. The bandgap energy of the samples calcined at temperature ranging from 600 to 1000 °C was found to be around 3.4 eV. BET specific surface area and pore volume of the materials continuously decreased with rising calcination temperature. The 70 % Sm<sub>2</sub>Ti<sub>2</sub>O<sub>7</sub>/HZSM-5 calcined at 800 °C was found to have the greatest photocatalytic activity on RBR X-3B degradation.<p>DOI: <a href="http://dx.doi.org/10.5755/j01.ms.24.3.18853">http://dx.doi.org/10.5755/j01.ms.24.3.18853</a></p>http://matsc.ktu.lt/index.php/MatSc/article/view/18853photocatalysisSm2Ti2O7calcinationsol-gelHZSM-5 |
spellingShingle | Wenjie ZHANG Yuxuan LIU Ling DU Sol-gel Preparation of Photocatalytic Sm2Ti2O7/HZSM-5 Composite on Degradation of Reactive Brilliant Red X-3B Medžiagotyra photocatalysis Sm2Ti2O7 calcination sol-gel HZSM-5 |
title | Sol-gel Preparation of Photocatalytic Sm2Ti2O7/HZSM-5 Composite on Degradation of Reactive Brilliant Red X-3B |
title_full | Sol-gel Preparation of Photocatalytic Sm2Ti2O7/HZSM-5 Composite on Degradation of Reactive Brilliant Red X-3B |
title_fullStr | Sol-gel Preparation of Photocatalytic Sm2Ti2O7/HZSM-5 Composite on Degradation of Reactive Brilliant Red X-3B |
title_full_unstemmed | Sol-gel Preparation of Photocatalytic Sm2Ti2O7/HZSM-5 Composite on Degradation of Reactive Brilliant Red X-3B |
title_short | Sol-gel Preparation of Photocatalytic Sm2Ti2O7/HZSM-5 Composite on Degradation of Reactive Brilliant Red X-3B |
title_sort | sol gel preparation of photocatalytic sm2ti2o7 hzsm 5 composite on degradation of reactive brilliant red x 3b |
topic | photocatalysis Sm2Ti2O7 calcination sol-gel HZSM-5 |
url | http://matsc.ktu.lt/index.php/MatSc/article/view/18853 |
work_keys_str_mv | AT wenjiezhang solgelpreparationofphotocatalyticsm2ti2o7hzsm5compositeondegradationofreactivebrilliantredx3b AT yuxuanliu solgelpreparationofphotocatalyticsm2ti2o7hzsm5compositeondegradationofreactivebrilliantredx3b AT lingdu solgelpreparationofphotocatalyticsm2ti2o7hzsm5compositeondegradationofreactivebrilliantredx3b |