Combining Ti4(embonate)6 cages and [Pb4(OH)4]4+ clusters for enhanced third-order nonlinear optical property
Herein, we present a novel cage-cluster-based framework composed of Ti4L6 (L = embonate) tetrahedra and [Pb4(µ3-OH)4]4+ cubane-like clusters that also exhibits high stability in water, air, and other common solvents. According to the topology study, it exhibits a chiral srs-type network. Integrating...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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Tsinghua University Press
2022-09-01
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| Series: | Polyoxometalates |
| Subjects: | |
| Online Access: | https://www.sciopen.com/article/10.26599/POM.2022.9140002 |
| _version_ | 1797865971504906240 |
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| author | Rui-Yan Chen Yan-Ping He Jian Zhang |
| author_facet | Rui-Yan Chen Yan-Ping He Jian Zhang |
| author_sort | Rui-Yan Chen |
| collection | DOAJ |
| description | Herein, we present a novel cage-cluster-based framework composed of Ti4L6 (L = embonate) tetrahedra and [Pb4(µ3-OH)4]4+ cubane-like clusters that also exhibits high stability in water, air, and other common solvents. According to the topology study, it exhibits a chiral srs-type network. Integrating titanium cages and lead-oxo clusters into a rigid cage-cluster-based framework significantly enhances its third-order nonlinear optical (NLO) property. |
| first_indexed | 2024-04-09T23:17:51Z |
| format | Article |
| id | doaj.art-b0d4de7eac0740c1abe5e1a4fe35015f |
| institution | Directory Open Access Journal |
| issn | 2957-9821 2957-9503 |
| language | English |
| last_indexed | 2024-04-09T23:17:51Z |
| publishDate | 2022-09-01 |
| publisher | Tsinghua University Press |
| record_format | Article |
| series | Polyoxometalates |
| spelling | doaj.art-b0d4de7eac0740c1abe5e1a4fe35015f2023-03-22T05:54:37ZengTsinghua University PressPolyoxometalates2957-98212957-95032022-09-01119140002914000210.26599/POM.2022.9140002Combining Ti4(embonate)6 cages and [Pb4(OH)4]4+ clusters for enhanced third-order nonlinear optical propertyRui-Yan Chen0Yan-Ping He1https://orcid.org/0000-0002-8873-4265Jian Zhang2https://orcid.org/0000-0003-3373-9621State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, ChinaState Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, ChinaState Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, ChinaHerein, we present a novel cage-cluster-based framework composed of Ti4L6 (L = embonate) tetrahedra and [Pb4(µ3-OH)4]4+ cubane-like clusters that also exhibits high stability in water, air, and other common solvents. According to the topology study, it exhibits a chiral srs-type network. Integrating titanium cages and lead-oxo clusters into a rigid cage-cluster-based framework significantly enhances its third-order nonlinear optical (NLO) property.https://www.sciopen.com/article/10.26599/POM.2022.9140002cage-cluster-based frameworktitanium cagemultistage assemblynonlinear optics |
| spellingShingle | Rui-Yan Chen Yan-Ping He Jian Zhang Combining Ti4(embonate)6 cages and [Pb4(OH)4]4+ clusters for enhanced third-order nonlinear optical property Polyoxometalates cage-cluster-based framework titanium cage multistage assembly nonlinear optics |
| title | Combining Ti4(embonate)6 cages and [Pb4(OH)4]4+ clusters for enhanced third-order nonlinear optical property |
| title_full | Combining Ti4(embonate)6 cages and [Pb4(OH)4]4+ clusters for enhanced third-order nonlinear optical property |
| title_fullStr | Combining Ti4(embonate)6 cages and [Pb4(OH)4]4+ clusters for enhanced third-order nonlinear optical property |
| title_full_unstemmed | Combining Ti4(embonate)6 cages and [Pb4(OH)4]4+ clusters for enhanced third-order nonlinear optical property |
| title_short | Combining Ti4(embonate)6 cages and [Pb4(OH)4]4+ clusters for enhanced third-order nonlinear optical property |
| title_sort | combining ti4 embonate 6 cages and pb4 oh 4 4 clusters for enhanced third order nonlinear optical property |
| topic | cage-cluster-based framework titanium cage multistage assembly nonlinear optics |
| url | https://www.sciopen.com/article/10.26599/POM.2022.9140002 |
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