Preparation of Functionalized Zr-Based MOFs and MOFs/GO for Efficient Removal of 1,3-Butadiene from Cigarette Smoke
Removal of 1,3-butadiene from cigarette smoke plays an important role in human health and environmental protection. Herein, a series of UiO-66 X% containing different ratios of the -NH<sub>2</sub> group was synthesized via the solvothermal method by using terephthalic acid (H<sub>2...
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MDPI AG
2023-01-01
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| Online Access: | https://www.mdpi.com/1996-1944/16/2/684 |
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| author | Yunxin Yang Cong Wang Hua Zhang Jiancai Qian Song Yang Huiyun Liao Xuehui Sun Yipeng Wang Peijian Sun Yunzhen Jia Junwei Guo Huaiyuan Zhu Cong Nie |
| author_facet | Yunxin Yang Cong Wang Hua Zhang Jiancai Qian Song Yang Huiyun Liao Xuehui Sun Yipeng Wang Peijian Sun Yunzhen Jia Junwei Guo Huaiyuan Zhu Cong Nie |
| author_sort | Yunxin Yang |
| collection | DOAJ |
| description | Removal of 1,3-butadiene from cigarette smoke plays an important role in human health and environmental protection. Herein, a series of UiO-66 X% containing different ratios of the -NH<sub>2</sub> group was synthesized via the solvothermal method by using terephthalic acid (H<sub>2</sub>BDC) and 2-aminoterephthalic acid (NH<sub>2</sub>-BDC) as ligands. Using GO as support, a series of UiO-66-NH<sub>2</sub>/GO Y% were prepared by controlling the ratio of UiO-66-NH<sub>2</sub> and GO. The effects of -NH<sub>2</sub> and GO contents on the structure and composition of MOFs were investigated. Finally, the different -NH<sub>2</sub> contents of UiO-66 X% and the different GO contents of UiO-66-NH<sub>2</sub>/GO Y% were applied in 1,3-butadiene removal from cigarette smoke. The results showed that UiO-66 X% with the higher contents of -NH<sub>2</sub> showed a higher rate of 1,3-butadiene removal, and UiO-66-NH<sub>2</sub>/GO Y% with the GO contents of 5% showed the highest removal rate of about 33.85%, which was 25.54% higher than that of activated carbon. In addition, the saturation capacity of the adsorbent materials for 1,3-butadiene was as high as 210.01–239.54 mg/g, showing great potential in reducing harmful components in cigarette smoke and environmental protection. |
| first_indexed | 2024-03-09T11:49:43Z |
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| id | doaj.art-b0d7495e5b5540c0a25e2804bf9122fb |
| institution | Directory Open Access Journal |
| issn | 1996-1944 |
| language | English |
| last_indexed | 2024-03-09T11:49:43Z |
| publishDate | 2023-01-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Materials |
| spelling | doaj.art-b0d7495e5b5540c0a25e2804bf9122fb2023-11-30T23:16:45ZengMDPI AGMaterials1996-19442023-01-0116268410.3390/ma16020684Preparation of Functionalized Zr-Based MOFs and MOFs/GO for Efficient Removal of 1,3-Butadiene from Cigarette SmokeYunxin Yang0Cong Wang1Hua Zhang2Jiancai Qian3Song Yang4Huiyun Liao5Xuehui Sun6Yipeng Wang7Peijian Sun8Yunzhen Jia9Junwei Guo10Huaiyuan Zhu11Cong Nie12Zhengzhou Tobacco Research Institute of CNTC, Zhengzhou 450001, ChinaZhengzhou Tobacco Research Institute of CNTC, Zhengzhou 450001, ChinaZhengzhou Tobacco Research Institute of CNTC, Zhengzhou 450001, ChinaZhengzhou Tobacco Research Institute of CNTC, Zhengzhou 450001, ChinaZhengzhou Tobacco Research Institute of CNTC, Zhengzhou 450001, ChinaZhengzhou Tobacco Research Institute of CNTC, Zhengzhou 450001, ChinaZhengzhou Tobacco Research Institute of CNTC, Zhengzhou 450001, ChinaZhengzhou Tobacco Research Institute of CNTC, Zhengzhou 450001, ChinaZhengzhou Tobacco Research Institute of CNTC, Zhengzhou 450001, ChinaZhengzhou Tobacco Research Institute of CNTC, Zhengzhou 450001, ChinaZhengzhou Tobacco Research Institute of CNTC, Zhengzhou 450001, ChinaZhengzhou Tobacco Research Institute of CNTC, Zhengzhou 450001, ChinaZhengzhou Tobacco Research Institute of CNTC, Zhengzhou 450001, ChinaRemoval of 1,3-butadiene from cigarette smoke plays an important role in human health and environmental protection. Herein, a series of UiO-66 X% containing different ratios of the -NH<sub>2</sub> group was synthesized via the solvothermal method by using terephthalic acid (H<sub>2</sub>BDC) and 2-aminoterephthalic acid (NH<sub>2</sub>-BDC) as ligands. Using GO as support, a series of UiO-66-NH<sub>2</sub>/GO Y% were prepared by controlling the ratio of UiO-66-NH<sub>2</sub> and GO. The effects of -NH<sub>2</sub> and GO contents on the structure and composition of MOFs were investigated. Finally, the different -NH<sub>2</sub> contents of UiO-66 X% and the different GO contents of UiO-66-NH<sub>2</sub>/GO Y% were applied in 1,3-butadiene removal from cigarette smoke. The results showed that UiO-66 X% with the higher contents of -NH<sub>2</sub> showed a higher rate of 1,3-butadiene removal, and UiO-66-NH<sub>2</sub>/GO Y% with the GO contents of 5% showed the highest removal rate of about 33.85%, which was 25.54% higher than that of activated carbon. In addition, the saturation capacity of the adsorbent materials for 1,3-butadiene was as high as 210.01–239.54 mg/g, showing great potential in reducing harmful components in cigarette smoke and environmental protection.https://www.mdpi.com/1996-1944/16/2/684UiO-66UiO-66-NH<sub>2</sub>/GO1,3-butadiene removalcigarette smoke |
| spellingShingle | Yunxin Yang Cong Wang Hua Zhang Jiancai Qian Song Yang Huiyun Liao Xuehui Sun Yipeng Wang Peijian Sun Yunzhen Jia Junwei Guo Huaiyuan Zhu Cong Nie Preparation of Functionalized Zr-Based MOFs and MOFs/GO for Efficient Removal of 1,3-Butadiene from Cigarette Smoke Materials UiO-66 UiO-66-NH<sub>2</sub>/GO 1,3-butadiene removal cigarette smoke |
| title | Preparation of Functionalized Zr-Based MOFs and MOFs/GO for Efficient Removal of 1,3-Butadiene from Cigarette Smoke |
| title_full | Preparation of Functionalized Zr-Based MOFs and MOFs/GO for Efficient Removal of 1,3-Butadiene from Cigarette Smoke |
| title_fullStr | Preparation of Functionalized Zr-Based MOFs and MOFs/GO for Efficient Removal of 1,3-Butadiene from Cigarette Smoke |
| title_full_unstemmed | Preparation of Functionalized Zr-Based MOFs and MOFs/GO for Efficient Removal of 1,3-Butadiene from Cigarette Smoke |
| title_short | Preparation of Functionalized Zr-Based MOFs and MOFs/GO for Efficient Removal of 1,3-Butadiene from Cigarette Smoke |
| title_sort | preparation of functionalized zr based mofs and mofs go for efficient removal of 1 3 butadiene from cigarette smoke |
| topic | UiO-66 UiO-66-NH<sub>2</sub>/GO 1,3-butadiene removal cigarette smoke |
| url | https://www.mdpi.com/1996-1944/16/2/684 |
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