Synthesis of Borane Complexes: From Small Borane Molecules to Polyhedral Boranes

Borane is a class of boron compounds, including active small borane molecules and relative stable polyhedral borane compounds, and has widely applied in energy storage, material science, and pharmaceutical medicine, especially as promising boron carriers for boron neutron capture therapy(BNCT), and...

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Main Authors: JING Yi, WANG Ying-ying, WANG Kai, XI Bi-ying, CHEN Xue-nian
Format: Article
Language:zho
Published: Editorial Office of Journal of Nuclear and Radiochemistry 2023-12-01
Series:He huaxue yu fangshe huaxue
Subjects:
Online Access:http://www.jnrc.org.cn/CN/10.7538/hhx.2023.45.06.0499
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author JING Yi
WANG Ying-ying
WANG Kai
XI Bi-ying
CHEN Xue-nian
author_facet JING Yi
WANG Ying-ying
WANG Kai
XI Bi-ying
CHEN Xue-nian
author_sort JING Yi
collection DOAJ
description Borane is a class of boron compounds, including active small borane molecules and relative stable polyhedral borane compounds, and has widely applied in energy storage, material science, and pharmaceutical medicine, especially as promising boron carriers for boron neutron capture therapy(BNCT), and many other fields. The synthesis of new borane molecules and optimization of the synthetic methods of boranes have been a significant part of boron chemistry over the last one hundred years. Herein, we have systematically summarized the syntheses of small borane molecules, polyhedral boranes, and carboranes; we also provided the molecular structures and 11B NMR spectra of borane compounds. Anticipatedly, this review will provide the basic knowledge for readers interested in borane chemistry and facilitate the readers for improving the synthetic methods of boranes and exploring the application of borane compounds.
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spelling doaj.art-b0dbc06ac55d4bf194ecf4cd3a92849d2024-04-06T05:48:45ZzhoEditorial Office of Journal of Nuclear and RadiochemistryHe huaxue yu fangshe huaxue0253-99502023-12-0145649952310.7538/hhx.2023.45.06.0499Synthesis of Borane Complexes: From Small Borane Molecules to Polyhedral BoranesJING Yi0WANG Ying-ying1WANG Kai2XI Bi-ying3CHEN Xue-nian4Green Catalysis Center, College of Chemistry, Zhengzhou UniversityGreen Catalysis Center, College of Chemistry, Zhengzhou UniversityGreen Catalysis Center, College of Chemistry, Zhengzhou UniversityGreen Catalysis Center, College of Chemistry, Zhengzhou UniversityGreen Catalysis Center, College of Chemistry, Zhengzhou UniversityBorane is a class of boron compounds, including active small borane molecules and relative stable polyhedral borane compounds, and has widely applied in energy storage, material science, and pharmaceutical medicine, especially as promising boron carriers for boron neutron capture therapy(BNCT), and many other fields. The synthesis of new borane molecules and optimization of the synthetic methods of boranes have been a significant part of boron chemistry over the last one hundred years. Herein, we have systematically summarized the syntheses of small borane molecules, polyhedral boranes, and carboranes; we also provided the molecular structures and 11B NMR spectra of borane compounds. Anticipatedly, this review will provide the basic knowledge for readers interested in borane chemistry and facilitate the readers for improving the synthetic methods of boranes and exploring the application of borane compounds.http://www.jnrc.org.cn/CN/10.7538/hhx.2023.45.06.0499boranepolyhedral boraneborohydridesynthesis of boranestructure of borane
spellingShingle JING Yi
WANG Ying-ying
WANG Kai
XI Bi-ying
CHEN Xue-nian
Synthesis of Borane Complexes: From Small Borane Molecules to Polyhedral Boranes
He huaxue yu fangshe huaxue
borane
polyhedral borane
borohydride
synthesis of borane
structure of borane
title Synthesis of Borane Complexes: From Small Borane Molecules to Polyhedral Boranes
title_full Synthesis of Borane Complexes: From Small Borane Molecules to Polyhedral Boranes
title_fullStr Synthesis of Borane Complexes: From Small Borane Molecules to Polyhedral Boranes
title_full_unstemmed Synthesis of Borane Complexes: From Small Borane Molecules to Polyhedral Boranes
title_short Synthesis of Borane Complexes: From Small Borane Molecules to Polyhedral Boranes
title_sort synthesis of borane complexes from small borane molecules to polyhedral boranes
topic borane
polyhedral borane
borohydride
synthesis of borane
structure of borane
url http://www.jnrc.org.cn/CN/10.7538/hhx.2023.45.06.0499
work_keys_str_mv AT jingyi synthesisofboranecomplexesfromsmallboranemoleculestopolyhedralboranes
AT wangyingying synthesisofboranecomplexesfromsmallboranemoleculestopolyhedralboranes
AT wangkai synthesisofboranecomplexesfromsmallboranemoleculestopolyhedralboranes
AT xibiying synthesisofboranecomplexesfromsmallboranemoleculestopolyhedralboranes
AT chenxuenian synthesisofboranecomplexesfromsmallboranemoleculestopolyhedralboranes