Synthesis of Borane Complexes: From Small Borane Molecules to Polyhedral Boranes
Borane is a class of boron compounds, including active small borane molecules and relative stable polyhedral borane compounds, and has widely applied in energy storage, material science, and pharmaceutical medicine, especially as promising boron carriers for boron neutron capture therapy(BNCT), and...
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Format: | Article |
Language: | zho |
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Editorial Office of Journal of Nuclear and Radiochemistry
2023-12-01
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Series: | He huaxue yu fangshe huaxue |
Subjects: | |
Online Access: | http://www.jnrc.org.cn/CN/10.7538/hhx.2023.45.06.0499 |
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author | JING Yi WANG Ying-ying WANG Kai XI Bi-ying CHEN Xue-nian |
author_facet | JING Yi WANG Ying-ying WANG Kai XI Bi-ying CHEN Xue-nian |
author_sort | JING Yi |
collection | DOAJ |
description | Borane is a class of boron compounds, including active small borane molecules and relative stable polyhedral borane compounds, and has widely applied in energy storage, material science, and pharmaceutical medicine, especially as promising boron carriers for boron neutron capture therapy(BNCT), and many other fields. The synthesis of new borane molecules and optimization of the synthetic methods of boranes have been a significant part of boron chemistry over the last one hundred years. Herein, we have systematically summarized the syntheses of small borane molecules, polyhedral boranes, and carboranes; we also provided the molecular structures and 11B NMR spectra of borane compounds. Anticipatedly, this review will provide the basic knowledge for readers interested in borane chemistry and facilitate the readers for improving the synthetic methods of boranes and exploring the application of borane compounds. |
first_indexed | 2024-03-08T16:28:34Z |
format | Article |
id | doaj.art-b0dbc06ac55d4bf194ecf4cd3a92849d |
institution | Directory Open Access Journal |
issn | 0253-9950 |
language | zho |
last_indexed | 2024-04-24T12:50:18Z |
publishDate | 2023-12-01 |
publisher | Editorial Office of Journal of Nuclear and Radiochemistry |
record_format | Article |
series | He huaxue yu fangshe huaxue |
spelling | doaj.art-b0dbc06ac55d4bf194ecf4cd3a92849d2024-04-06T05:48:45ZzhoEditorial Office of Journal of Nuclear and RadiochemistryHe huaxue yu fangshe huaxue0253-99502023-12-0145649952310.7538/hhx.2023.45.06.0499Synthesis of Borane Complexes: From Small Borane Molecules to Polyhedral BoranesJING Yi0WANG Ying-ying1WANG Kai2XI Bi-ying3CHEN Xue-nian4Green Catalysis Center, College of Chemistry, Zhengzhou UniversityGreen Catalysis Center, College of Chemistry, Zhengzhou UniversityGreen Catalysis Center, College of Chemistry, Zhengzhou UniversityGreen Catalysis Center, College of Chemistry, Zhengzhou UniversityGreen Catalysis Center, College of Chemistry, Zhengzhou UniversityBorane is a class of boron compounds, including active small borane molecules and relative stable polyhedral borane compounds, and has widely applied in energy storage, material science, and pharmaceutical medicine, especially as promising boron carriers for boron neutron capture therapy(BNCT), and many other fields. The synthesis of new borane molecules and optimization of the synthetic methods of boranes have been a significant part of boron chemistry over the last one hundred years. Herein, we have systematically summarized the syntheses of small borane molecules, polyhedral boranes, and carboranes; we also provided the molecular structures and 11B NMR spectra of borane compounds. Anticipatedly, this review will provide the basic knowledge for readers interested in borane chemistry and facilitate the readers for improving the synthetic methods of boranes and exploring the application of borane compounds.http://www.jnrc.org.cn/CN/10.7538/hhx.2023.45.06.0499boranepolyhedral boraneborohydridesynthesis of boranestructure of borane |
spellingShingle | JING Yi WANG Ying-ying WANG Kai XI Bi-ying CHEN Xue-nian Synthesis of Borane Complexes: From Small Borane Molecules to Polyhedral Boranes He huaxue yu fangshe huaxue borane polyhedral borane borohydride synthesis of borane structure of borane |
title | Synthesis of Borane Complexes: From Small Borane Molecules to Polyhedral Boranes |
title_full | Synthesis of Borane Complexes: From Small Borane Molecules to Polyhedral Boranes |
title_fullStr | Synthesis of Borane Complexes: From Small Borane Molecules to Polyhedral Boranes |
title_full_unstemmed | Synthesis of Borane Complexes: From Small Borane Molecules to Polyhedral Boranes |
title_short | Synthesis of Borane Complexes: From Small Borane Molecules to Polyhedral Boranes |
title_sort | synthesis of borane complexes from small borane molecules to polyhedral boranes |
topic | borane polyhedral borane borohydride synthesis of borane structure of borane |
url | http://www.jnrc.org.cn/CN/10.7538/hhx.2023.45.06.0499 |
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