Photovoltaic Performance of Dye-Sensitized Solar Cell (DSSC) Fabricated by Silver Nanoclusters-Decorated TiO2 Electrode via Photochemical Reduction Technique

In this investigation, Ag@TiO2 nanocomposite was prepared by deposition of silver nanoclusters onto commercial TiO2 nanoparticles (known as P25 TiO2) via photodeposition technique as clean and simple photochemical route. The synthesized Ag@TiO2 nanocomposite was utilized in the fabrication of dye-se...

Full description

Bibliographic Details
Main Authors: A. Ehteram, M. Hamadanian, S. Z. Mirdamadian, V. Jabbari
Format: Article
Language:English
Published: Nanoscience and Nanotechnology Research Center, University of Kashan 2014-01-01
Series:Journal of Nanostructures
Subjects:
Online Access:http://jns.kashanu.ac.ir/article_6081_88071adf1d5abc631e4d6ba3f64234c9.pdf
_version_ 1818136496121577472
author A. Ehteram
M. Hamadanian
S. Z. Mirdamadian
V. Jabbari
author_facet A. Ehteram
M. Hamadanian
S. Z. Mirdamadian
V. Jabbari
author_sort A. Ehteram
collection DOAJ
description In this investigation, Ag@TiO2 nanocomposite was prepared by deposition of silver nanoclusters onto commercial TiO2 nanoparticles (known as P25 TiO2) via photodeposition technique as clean and simple photochemical route. The synthesized Ag@TiO2 nanocomposite was utilized in the fabrication of dye-sensitized solar cell (DSSC) chiefly because, compared to pure TiO2, the electron affinity of Ag@TiO2 nanocomposites is higher which enhances the photo-generated excitons lifetime, and as result, reduces the rate of photo-generated charge carriers recombination. Additionally, we found that via deposition of silver nanoclusters, TiO2 absorption in visible light region was considerably improved due to the surface Plasmon phenomenon. XRD results proved existence of anatase and rutile phases within TiO2 structure. Finally, photovoltaic performance and solar energy conversion efficiency of TiO2 and Ag@TiO2 electrode-based DSSC were compared and discussed.
first_indexed 2024-12-11T09:41:20Z
format Article
id doaj.art-b0e907c186fc4b449d47f45a711f817d
institution Directory Open Access Journal
issn 2251-7871
2251-788X
language English
last_indexed 2024-12-11T09:41:20Z
publishDate 2014-01-01
publisher Nanoscience and Nanotechnology Research Center, University of Kashan
record_format Article
series Journal of Nanostructures
spelling doaj.art-b0e907c186fc4b449d47f45a711f817d2022-12-22T01:12:40ZengNanoscience and Nanotechnology Research Center, University of KashanJournal of Nanostructures2251-78712251-788X2014-01-0141758210.7508/jns.2014.01.0096081Photovoltaic Performance of Dye-Sensitized Solar Cell (DSSC) Fabricated by Silver Nanoclusters-Decorated TiO2 Electrode via Photochemical Reduction TechniqueA. Ehteram0M. Hamadanian1S. Z. Mirdamadian2V. Jabbari3Department of Electrical Engineering, Kashan Branch, Islamic Azad University, Kashan, IRANInstitute of Nanosciences and Nanotechnology, University of Kashan, Kashan, IRAN , Department of Physical Chemistry, Faculty of Chemistry, University of Kashan, Kashan, IRANInstitute of Nanosciences and Nanotechnology, University of Kashan, Kashan, IRANInstitute of Nanosciences and Nanotechnology, University of Kashan, Kashan, IRANIn this investigation, Ag@TiO2 nanocomposite was prepared by deposition of silver nanoclusters onto commercial TiO2 nanoparticles (known as P25 TiO2) via photodeposition technique as clean and simple photochemical route. The synthesized Ag@TiO2 nanocomposite was utilized in the fabrication of dye-sensitized solar cell (DSSC) chiefly because, compared to pure TiO2, the electron affinity of Ag@TiO2 nanocomposites is higher which enhances the photo-generated excitons lifetime, and as result, reduces the rate of photo-generated charge carriers recombination. Additionally, we found that via deposition of silver nanoclusters, TiO2 absorption in visible light region was considerably improved due to the surface Plasmon phenomenon. XRD results proved existence of anatase and rutile phases within TiO2 structure. Finally, photovoltaic performance and solar energy conversion efficiency of TiO2 and Ag@TiO2 electrode-based DSSC were compared and discussed.http://jns.kashanu.ac.ir/article_6081_88071adf1d5abc631e4d6ba3f64234c9.pdfTiO2SilverPhotodepositionDSSCPhotovoltaic
spellingShingle A. Ehteram
M. Hamadanian
S. Z. Mirdamadian
V. Jabbari
Photovoltaic Performance of Dye-Sensitized Solar Cell (DSSC) Fabricated by Silver Nanoclusters-Decorated TiO2 Electrode via Photochemical Reduction Technique
Journal of Nanostructures
TiO2
Silver
Photodeposition
DSSC
Photovoltaic
title Photovoltaic Performance of Dye-Sensitized Solar Cell (DSSC) Fabricated by Silver Nanoclusters-Decorated TiO2 Electrode via Photochemical Reduction Technique
title_full Photovoltaic Performance of Dye-Sensitized Solar Cell (DSSC) Fabricated by Silver Nanoclusters-Decorated TiO2 Electrode via Photochemical Reduction Technique
title_fullStr Photovoltaic Performance of Dye-Sensitized Solar Cell (DSSC) Fabricated by Silver Nanoclusters-Decorated TiO2 Electrode via Photochemical Reduction Technique
title_full_unstemmed Photovoltaic Performance of Dye-Sensitized Solar Cell (DSSC) Fabricated by Silver Nanoclusters-Decorated TiO2 Electrode via Photochemical Reduction Technique
title_short Photovoltaic Performance of Dye-Sensitized Solar Cell (DSSC) Fabricated by Silver Nanoclusters-Decorated TiO2 Electrode via Photochemical Reduction Technique
title_sort photovoltaic performance of dye sensitized solar cell dssc fabricated by silver nanoclusters decorated tio2 electrode via photochemical reduction technique
topic TiO2
Silver
Photodeposition
DSSC
Photovoltaic
url http://jns.kashanu.ac.ir/article_6081_88071adf1d5abc631e4d6ba3f64234c9.pdf
work_keys_str_mv AT aehteram photovoltaicperformanceofdyesensitizedsolarcelldsscfabricatedbysilvernanoclustersdecoratedtio2electrodeviaphotochemicalreductiontechnique
AT mhamadanian photovoltaicperformanceofdyesensitizedsolarcelldsscfabricatedbysilvernanoclustersdecoratedtio2electrodeviaphotochemicalreductiontechnique
AT szmirdamadian photovoltaicperformanceofdyesensitizedsolarcelldsscfabricatedbysilvernanoclustersdecoratedtio2electrodeviaphotochemicalreductiontechnique
AT vjabbari photovoltaicperformanceofdyesensitizedsolarcelldsscfabricatedbysilvernanoclustersdecoratedtio2electrodeviaphotochemicalreductiontechnique