Electrical and Optical Properties of Poly(vinyl chloride)/ZnS Nanocomposites Exposed to Gamma Radiation

Poly(vinyl chloride) (PVC) is considered one of the most versatile polymers due to its interaction with different additives. On the other hand, binary sulfides have wide applications as zinc sulfide (ZnS), one of the first discovered semiconductors. This study aims to synthesize a nanocomposite mate...

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Main Authors: Nara E. Guimarães, Érika R. B. Ximenes, Lindomar Avelino da Silva, Renata Francisca da Silva Santos, Elmo Silvano Araújo, Kátia Aparecida da Silva Aquino
Format: Article
Language:English
Published: Associação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol) 2023-05-01
Series:Materials Research
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392023000100259&tlng=en
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author Nara E. Guimarães
Érika R. B. Ximenes
Lindomar Avelino da Silva
Renata Francisca da Silva Santos
Elmo Silvano Araújo
Kátia Aparecida da Silva Aquino
author_facet Nara E. Guimarães
Érika R. B. Ximenes
Lindomar Avelino da Silva
Renata Francisca da Silva Santos
Elmo Silvano Araújo
Kátia Aparecida da Silva Aquino
author_sort Nara E. Guimarães
collection DOAJ
description Poly(vinyl chloride) (PVC) is considered one of the most versatile polymers due to its interaction with different additives. On the other hand, binary sulfides have wide applications as zinc sulfide (ZnS), one of the first discovered semiconductors. This study aims to synthesize a nanocomposite material containing nano ZnS in the PVC matrix with a surfactant as a compatibilizer agent to evaluate its optical and electrical properties when exposed to gamma radiation. Our results showed that adding ZnS at 0.5 wt% concentration in the PVC matrix promoted the system from insulating to the semiconductor material. Therefore, gamma radiation has played an important role in nanocomposites' optical and electrical properties with changes in electrical and electrical conductivity, constant dielectric parts, refraction index, optical band gap, and Urbach energy. Thus, our study points to the development of nanocomposite material, semiconductors, and features useful for applications in flexible electronics or optical-electronic devices.
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spelling doaj.art-b0ee408f0c754e069f98cff7d2a7df9e2023-05-23T07:32:02ZengAssociação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol)Materials Research1516-14392023-05-012610.1590/1980-5373-mr-2022-0308Electrical and Optical Properties of Poly(vinyl chloride)/ZnS Nanocomposites Exposed to Gamma RadiationNara E. GuimarãesÉrika R. B. XimenesLindomar Avelino da SilvaRenata Francisca da Silva SantosElmo Silvano AraújoKátia Aparecida da Silva Aquinohttps://orcid.org/0000-0001-8895-6637Poly(vinyl chloride) (PVC) is considered one of the most versatile polymers due to its interaction with different additives. On the other hand, binary sulfides have wide applications as zinc sulfide (ZnS), one of the first discovered semiconductors. This study aims to synthesize a nanocomposite material containing nano ZnS in the PVC matrix with a surfactant as a compatibilizer agent to evaluate its optical and electrical properties when exposed to gamma radiation. Our results showed that adding ZnS at 0.5 wt% concentration in the PVC matrix promoted the system from insulating to the semiconductor material. Therefore, gamma radiation has played an important role in nanocomposites' optical and electrical properties with changes in electrical and electrical conductivity, constant dielectric parts, refraction index, optical band gap, and Urbach energy. Thus, our study points to the development of nanocomposite material, semiconductors, and features useful for applications in flexible electronics or optical-electronic devices.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392023000100259&tlng=enOptical-electronic devicesgamma radiationgap band
spellingShingle Nara E. Guimarães
Érika R. B. Ximenes
Lindomar Avelino da Silva
Renata Francisca da Silva Santos
Elmo Silvano Araújo
Kátia Aparecida da Silva Aquino
Electrical and Optical Properties of Poly(vinyl chloride)/ZnS Nanocomposites Exposed to Gamma Radiation
Materials Research
Optical-electronic devices
gamma radiation
gap band
title Electrical and Optical Properties of Poly(vinyl chloride)/ZnS Nanocomposites Exposed to Gamma Radiation
title_full Electrical and Optical Properties of Poly(vinyl chloride)/ZnS Nanocomposites Exposed to Gamma Radiation
title_fullStr Electrical and Optical Properties of Poly(vinyl chloride)/ZnS Nanocomposites Exposed to Gamma Radiation
title_full_unstemmed Electrical and Optical Properties of Poly(vinyl chloride)/ZnS Nanocomposites Exposed to Gamma Radiation
title_short Electrical and Optical Properties of Poly(vinyl chloride)/ZnS Nanocomposites Exposed to Gamma Radiation
title_sort electrical and optical properties of poly vinyl chloride zns nanocomposites exposed to gamma radiation
topic Optical-electronic devices
gamma radiation
gap band
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392023000100259&tlng=en
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