Influence of pyrolytic carbon black and pyrolytic oil made from used tires on the curing and (dynamic) mechanical properties of natural rubber (NR)/styrene-butadiene rubber (SBR) blends

Pyrolytic carbon black (CBp) and pyrolytic oil (Op) made from used tires were used in natural rubber (NR)/styrene-butadiene rubber (SBR) blends. The effects of CBp and Op on the processing properties, the mechanical properties and the dynamic mechanical properties of the NR/SBR blends were investiga...

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Main Authors: F. Karabork, S. T. Tipirdamaz
Format: Article
Language:English
Published: Budapest University of Technology 2016-01-01
Series:eXPRESS Polymer Letters
Subjects:
Online Access:http://www.expresspolymlett.com/letolt.php?file=EPL-0006452&mi=cd
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author F. Karabork
S. T. Tipirdamaz
author_facet F. Karabork
S. T. Tipirdamaz
author_sort F. Karabork
collection DOAJ
description Pyrolytic carbon black (CBp) and pyrolytic oil (Op) made from used tires were used in natural rubber (NR)/styrene-butadiene rubber (SBR) blends. The effects of CBp and Op on the processing properties, the mechanical properties and the dynamic mechanical properties of the NR/SBR blends were investigated and compared with a control sample that was prepared with N550 and commercial process oil. It was found that the effect of CBp on the processing properties of the NR/SBR blends was similar to that of N550. With the increase of the CBp content, the curing properties of the NR/SBR blends changed little. The reinforcing effect of CBp was inferior to that of N550. With the increase of the CBp content, the tensile strength, tear strength and modulus at 100% elongation of the NR/SBR vulcanizates decreased significantly. Dynamic mechanical properties of the NR/SBR blends were also affected and all samples comprising CBp have a higher tan δ than control sample. It is suggested that the low surface area and high ash content of CBp strongly effects all of these property changes of the NR/SBR blends. The morphology and distribution of the carbon black particles are studied using a scanning electron microscope. It was also found that with the increase of the Op content, the properties of the NR/SBR blends were strongly affected due to the high sulfur content of Op, which produced a high crosslinking density.
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spelling doaj.art-b0f09160acf9497da7272ef560f0970e2022-12-21T19:09:00ZengBudapest University of TechnologyeXPRESS Polymer Letters1788-618X2016-01-01101728210.3144/expresspolymlett.2016.8Influence of pyrolytic carbon black and pyrolytic oil made from used tires on the curing and (dynamic) mechanical properties of natural rubber (NR)/styrene-butadiene rubber (SBR) blendsF. KaraborkS. T. TipirdamazPyrolytic carbon black (CBp) and pyrolytic oil (Op) made from used tires were used in natural rubber (NR)/styrene-butadiene rubber (SBR) blends. The effects of CBp and Op on the processing properties, the mechanical properties and the dynamic mechanical properties of the NR/SBR blends were investigated and compared with a control sample that was prepared with N550 and commercial process oil. It was found that the effect of CBp on the processing properties of the NR/SBR blends was similar to that of N550. With the increase of the CBp content, the curing properties of the NR/SBR blends changed little. The reinforcing effect of CBp was inferior to that of N550. With the increase of the CBp content, the tensile strength, tear strength and modulus at 100% elongation of the NR/SBR vulcanizates decreased significantly. Dynamic mechanical properties of the NR/SBR blends were also affected and all samples comprising CBp have a higher tan δ than control sample. It is suggested that the low surface area and high ash content of CBp strongly effects all of these property changes of the NR/SBR blends. The morphology and distribution of the carbon black particles are studied using a scanning electron microscope. It was also found that with the increase of the Op content, the properties of the NR/SBR blends were strongly affected due to the high sulfur content of Op, which produced a high crosslinking density.http://www.expresspolymlett.com/letolt.php?file=EPL-0006452&mi=cdMechanical propertiespyrolytic carbon blackpyrolytic oilcure characteristicsdynamical mechanical propertie
spellingShingle F. Karabork
S. T. Tipirdamaz
Influence of pyrolytic carbon black and pyrolytic oil made from used tires on the curing and (dynamic) mechanical properties of natural rubber (NR)/styrene-butadiene rubber (SBR) blends
eXPRESS Polymer Letters
Mechanical properties
pyrolytic carbon black
pyrolytic oil
cure characteristics
dynamical mechanical propertie
title Influence of pyrolytic carbon black and pyrolytic oil made from used tires on the curing and (dynamic) mechanical properties of natural rubber (NR)/styrene-butadiene rubber (SBR) blends
title_full Influence of pyrolytic carbon black and pyrolytic oil made from used tires on the curing and (dynamic) mechanical properties of natural rubber (NR)/styrene-butadiene rubber (SBR) blends
title_fullStr Influence of pyrolytic carbon black and pyrolytic oil made from used tires on the curing and (dynamic) mechanical properties of natural rubber (NR)/styrene-butadiene rubber (SBR) blends
title_full_unstemmed Influence of pyrolytic carbon black and pyrolytic oil made from used tires on the curing and (dynamic) mechanical properties of natural rubber (NR)/styrene-butadiene rubber (SBR) blends
title_short Influence of pyrolytic carbon black and pyrolytic oil made from used tires on the curing and (dynamic) mechanical properties of natural rubber (NR)/styrene-butadiene rubber (SBR) blends
title_sort influence of pyrolytic carbon black and pyrolytic oil made from used tires on the curing and dynamic mechanical properties of natural rubber nr styrene butadiene rubber sbr blends
topic Mechanical properties
pyrolytic carbon black
pyrolytic oil
cure characteristics
dynamical mechanical propertie
url http://www.expresspolymlett.com/letolt.php?file=EPL-0006452&mi=cd
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