Chiral Nanocluster Complexes Formed by Host−Guest Interaction between Enantiomeric 2,6-Helic[6]arenes and Silver Cluster Ag<sub>20</sub>: Emission Enhancement and Chirality Transfer
A pair of chiral nanocluster complexes were formed by the host−guest interaction between the enantiomeric 2,6-helic[6]arenes and nanocluster Ag<sub>20</sub>. The formation and stability of the nanocluster complexes were experimentally and theoretically confirmed. Meanwhile, the chiral na...
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| Format: | Article |
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MDPI AG
2022-06-01
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| Series: | Molecules |
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| Online Access: | https://www.mdpi.com/1420-3049/27/12/3932 |
| _version_ | 1797483952623058944 |
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| author | Yan Guo Ying Han Chuanfeng Chen |
| author_facet | Yan Guo Ying Han Chuanfeng Chen |
| author_sort | Yan Guo |
| collection | DOAJ |
| description | A pair of chiral nanocluster complexes were formed by the host−guest interaction between the enantiomeric 2,6-helic[6]arenes and nanocluster Ag<sub>20</sub>. The formation and stability of the nanocluster complexes were experimentally and theoretically confirmed. Meanwhile, the chiral nanocluster complexes exhibited enhanced luminescence and induced CD signals at room temperature in the solid state, revealing the stable complexation and chirality transfer from the chiral macrocycles to the nanocluster Ag<sub>20</sub>. |
| first_indexed | 2024-03-09T22:54:29Z |
| format | Article |
| id | doaj.art-b117b34b6f1a45a3b372e03c0bcf6cf6 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-03-09T22:54:29Z |
| publishDate | 2022-06-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-b117b34b6f1a45a3b372e03c0bcf6cf62023-11-23T18:13:57ZengMDPI AGMolecules1420-30492022-06-012712393210.3390/molecules27123932Chiral Nanocluster Complexes Formed by Host−Guest Interaction between Enantiomeric 2,6-Helic[6]arenes and Silver Cluster Ag<sub>20</sub>: Emission Enhancement and Chirality TransferYan Guo0Ying Han1Chuanfeng Chen2Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, ChinaBeijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, ChinaBeijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, ChinaA pair of chiral nanocluster complexes were formed by the host−guest interaction between the enantiomeric 2,6-helic[6]arenes and nanocluster Ag<sub>20</sub>. The formation and stability of the nanocluster complexes were experimentally and theoretically confirmed. Meanwhile, the chiral nanocluster complexes exhibited enhanced luminescence and induced CD signals at room temperature in the solid state, revealing the stable complexation and chirality transfer from the chiral macrocycles to the nanocluster Ag<sub>20</sub>.https://www.mdpi.com/1420-3049/27/12/39322,6-helic[6]arenesilver clusterhost–guest interactionluminescencechirality transfer |
| spellingShingle | Yan Guo Ying Han Chuanfeng Chen Chiral Nanocluster Complexes Formed by Host−Guest Interaction between Enantiomeric 2,6-Helic[6]arenes and Silver Cluster Ag<sub>20</sub>: Emission Enhancement and Chirality Transfer Molecules 2,6-helic[6]arene silver cluster host–guest interaction luminescence chirality transfer |
| title | Chiral Nanocluster Complexes Formed by Host−Guest Interaction between Enantiomeric 2,6-Helic[6]arenes and Silver Cluster Ag<sub>20</sub>: Emission Enhancement and Chirality Transfer |
| title_full | Chiral Nanocluster Complexes Formed by Host−Guest Interaction between Enantiomeric 2,6-Helic[6]arenes and Silver Cluster Ag<sub>20</sub>: Emission Enhancement and Chirality Transfer |
| title_fullStr | Chiral Nanocluster Complexes Formed by Host−Guest Interaction between Enantiomeric 2,6-Helic[6]arenes and Silver Cluster Ag<sub>20</sub>: Emission Enhancement and Chirality Transfer |
| title_full_unstemmed | Chiral Nanocluster Complexes Formed by Host−Guest Interaction between Enantiomeric 2,6-Helic[6]arenes and Silver Cluster Ag<sub>20</sub>: Emission Enhancement and Chirality Transfer |
| title_short | Chiral Nanocluster Complexes Formed by Host−Guest Interaction between Enantiomeric 2,6-Helic[6]arenes and Silver Cluster Ag<sub>20</sub>: Emission Enhancement and Chirality Transfer |
| title_sort | chiral nanocluster complexes formed by host guest interaction between enantiomeric 2 6 helic 6 arenes and silver cluster ag sub 20 sub emission enhancement and chirality transfer |
| topic | 2,6-helic[6]arene silver cluster host–guest interaction luminescence chirality transfer |
| url | https://www.mdpi.com/1420-3049/27/12/3932 |
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