Thiocarbonyl-enabled ferrocene C–H nitrogenation by cobalt(III) catalysis: thermal and mechanochemical

Thiocarbonyl-enabled ferrocene C–H nitrogenation by cobalt(III) catalysis: thermal and mechanochemical

Versatile C–H amidations of synthetically useful ferrocenes were accomplished by weakly-coordinating thiocarbonyl-assisted cobalt catalysis. Thus, carboxylates enabled ferrocene C–H nitrogenations with dioxazolones, featuring ample substrate scope and robust functional group tolerance. Mechanistic s...

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Bibliographic Details
Main Authors: Santhivardhana Reddy Yetra, Zhigao Shen, Hui Wang, Lutz Ackermann
Format: Article
Language:English
Published: Beilstein-Institut 2018-06-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
amidation
C–H activation
cobalt
ferrocene
mechanochemistry
Online Access:https://doi.org/10.3762/bjoc.14.131

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