Hydrothermal synthesis of In2O3 nanoparticles hybrid twins hexagonal disk ZnO heterostructures for enhanced photocatalytic activities and stability

Abstract In2O3 nanoparticles hybrid twins hexagonal disk (THD) ZnO with different ratios were fabricated by a hydrothermal method. The as-obtained ZnO/In2O3 composites are constituted by hexagonal disks ZnO with diameters of about 1 μm and In2O3 nanoparticles with sizes of about 20–50 nm. With the i...

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Main Authors: Hairui Liu, Haifa Zhai, Chunjie Hu, Jien Yang, Zhiyong Liu
Format: Article
Language:English
Published: SpringerOpen 2017-07-01
Series:Nanoscale Research Letters
Subjects:
Online Access:http://link.springer.com/article/10.1186/s11671-017-2233-3
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author Hairui Liu
Haifa Zhai
Chunjie Hu
Jien Yang
Zhiyong Liu
author_facet Hairui Liu
Haifa Zhai
Chunjie Hu
Jien Yang
Zhiyong Liu
author_sort Hairui Liu
collection DOAJ
description Abstract In2O3 nanoparticles hybrid twins hexagonal disk (THD) ZnO with different ratios were fabricated by a hydrothermal method. The as-obtained ZnO/In2O3 composites are constituted by hexagonal disks ZnO with diameters of about 1 μm and In2O3 nanoparticles with sizes of about 20–50 nm. With the increase of In2O3 content in ZnO/In2O3 composites, the absorption band edges of samples shifted from UV to visible light region. Compared with pure ZnO, the ZnO/In2O3 composites show enhanced photocatalytic activities for degradation of methyl orange (MO) and 4-nitrophenol (4-NP) under solar light irradiation. Due to suitable alignment of their energy band-gap structure of the In2O3 and ZnO, the formation of type п heterostructure can enhance efficient separation of photo-generate electro-hole pairs and provides convenient carrier transfer paths.
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spelling doaj.art-b15d5667a42a4a0a83dd3f6b411323ca2023-09-03T09:34:07ZengSpringerOpenNanoscale Research Letters1931-75731556-276X2017-07-0112111010.1186/s11671-017-2233-3Hydrothermal synthesis of In2O3 nanoparticles hybrid twins hexagonal disk ZnO heterostructures for enhanced photocatalytic activities and stabilityHairui Liu0Haifa Zhai1Chunjie Hu2Jien Yang3Zhiyong Liu4College of Physics and Materials science, Henan Normal UniversityCollege of Physics and Materials science, Henan Normal UniversityCollege of Physics and Materials science, Henan Normal UniversityCollege of Physics and Materials science, Henan Normal UniversityCollege of Physics and Materials science, Henan Normal UniversityAbstract In2O3 nanoparticles hybrid twins hexagonal disk (THD) ZnO with different ratios were fabricated by a hydrothermal method. The as-obtained ZnO/In2O3 composites are constituted by hexagonal disks ZnO with diameters of about 1 μm and In2O3 nanoparticles with sizes of about 20–50 nm. With the increase of In2O3 content in ZnO/In2O3 composites, the absorption band edges of samples shifted from UV to visible light region. Compared with pure ZnO, the ZnO/In2O3 composites show enhanced photocatalytic activities for degradation of methyl orange (MO) and 4-nitrophenol (4-NP) under solar light irradiation. Due to suitable alignment of their energy band-gap structure of the In2O3 and ZnO, the formation of type п heterostructure can enhance efficient separation of photo-generate electro-hole pairs and provides convenient carrier transfer paths.http://link.springer.com/article/10.1186/s11671-017-2233-3ZnOIn2O3HeterostructuresPhotocatalytic efficiency
spellingShingle Hairui Liu
Haifa Zhai
Chunjie Hu
Jien Yang
Zhiyong Liu
Hydrothermal synthesis of In2O3 nanoparticles hybrid twins hexagonal disk ZnO heterostructures for enhanced photocatalytic activities and stability
Nanoscale Research Letters
ZnO
In2O3
Heterostructures
Photocatalytic efficiency
title Hydrothermal synthesis of In2O3 nanoparticles hybrid twins hexagonal disk ZnO heterostructures for enhanced photocatalytic activities and stability
title_full Hydrothermal synthesis of In2O3 nanoparticles hybrid twins hexagonal disk ZnO heterostructures for enhanced photocatalytic activities and stability
title_fullStr Hydrothermal synthesis of In2O3 nanoparticles hybrid twins hexagonal disk ZnO heterostructures for enhanced photocatalytic activities and stability
title_full_unstemmed Hydrothermal synthesis of In2O3 nanoparticles hybrid twins hexagonal disk ZnO heterostructures for enhanced photocatalytic activities and stability
title_short Hydrothermal synthesis of In2O3 nanoparticles hybrid twins hexagonal disk ZnO heterostructures for enhanced photocatalytic activities and stability
title_sort hydrothermal synthesis of in2o3 nanoparticles hybrid twins hexagonal disk zno heterostructures for enhanced photocatalytic activities and stability
topic ZnO
In2O3
Heterostructures
Photocatalytic efficiency
url http://link.springer.com/article/10.1186/s11671-017-2233-3
work_keys_str_mv AT hairuiliu hydrothermalsynthesisofin2o3nanoparticleshybridtwinshexagonaldiskznoheterostructuresforenhancedphotocatalyticactivitiesandstability
AT haifazhai hydrothermalsynthesisofin2o3nanoparticleshybridtwinshexagonaldiskznoheterostructuresforenhancedphotocatalyticactivitiesandstability
AT chunjiehu hydrothermalsynthesisofin2o3nanoparticleshybridtwinshexagonaldiskznoheterostructuresforenhancedphotocatalyticactivitiesandstability
AT jienyang hydrothermalsynthesisofin2o3nanoparticleshybridtwinshexagonaldiskznoheterostructuresforenhancedphotocatalyticactivitiesandstability
AT zhiyongliu hydrothermalsynthesisofin2o3nanoparticleshybridtwinshexagonaldiskznoheterostructuresforenhancedphotocatalyticactivitiesandstability