Di-μ-azido-κ4N:N-bis({2-[(3-amino-2,2-dimethylpropyl)iminomethyl]-6-methoxyphenolato-1κ3N,N′,O1}copper(II))
The complete molecule of the title complex, [Cu2(C13H19N2O2)2(N3)2], is generated by the application of a centre of inversion. The central Cu2N2 core is a rhombus as the μ2-azide ligands bridge in an asymmetric fashion. Each CuII atom is also coordinated by a monoanionic tridentate Schi...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-07-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812028954 |
| _version_ | 1818958629604163584 |
|---|---|
| author | Akbar Ghaemi Saeed Rayati Kazem Fayyazi Seik Weng Ng Edward R. T. Tiekink |
| author_facet | Akbar Ghaemi Saeed Rayati Kazem Fayyazi Seik Weng Ng Edward R. T. Tiekink |
| author_sort | Akbar Ghaemi |
| collection | DOAJ |
| description | The complete molecule of the title complex, [Cu2(C13H19N2O2)2(N3)2], is generated by the application of a centre of inversion. The central Cu2N2 core is a rhombus as the μ2-azide ligands bridge in an asymmetric fashion. Each CuII atom is also coordinated by a monoanionic tridentate Schiff base ligand via the anticipated oxide O, imine N and amine N atoms. The resulting N4O coordination geometry is based on a square pyramid. No specific intermolecular interactions are noted in the crystal packing, but the amine H atoms form intramolecular N—H...O(oxide)/N(azide) hydrogen bonds. |
| first_indexed | 2024-12-20T11:28:47Z |
| format | Article |
| id | doaj.art-b17b3f83c550444b84e5a4230c223218 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:28:47Z |
| publishDate | 2012-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-b17b3f83c550444b84e5a4230c2232182022-12-21T19:42:18ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-07-01687m993m99410.1107/S1600536812028954Di-μ-azido-κ4N:N-bis({2-[(3-amino-2,2-dimethylpropyl)iminomethyl]-6-methoxyphenolato-1κ3N,N′,O1}copper(II))Akbar GhaemiSaeed RayatiKazem FayyaziSeik Weng NgEdward R. T. TiekinkThe complete molecule of the title complex, [Cu2(C13H19N2O2)2(N3)2], is generated by the application of a centre of inversion. The central Cu2N2 core is a rhombus as the μ2-azide ligands bridge in an asymmetric fashion. Each CuII atom is also coordinated by a monoanionic tridentate Schiff base ligand via the anticipated oxide O, imine N and amine N atoms. The resulting N4O coordination geometry is based on a square pyramid. No specific intermolecular interactions are noted in the crystal packing, but the amine H atoms form intramolecular N—H...O(oxide)/N(azide) hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536812028954 |
| spellingShingle | Akbar Ghaemi Saeed Rayati Kazem Fayyazi Seik Weng Ng Edward R. T. Tiekink Di-μ-azido-κ4N:N-bis({2-[(3-amino-2,2-dimethylpropyl)iminomethyl]-6-methoxyphenolato-1κ3N,N′,O1}copper(II)) Acta Crystallographica Section E |
| title | Di-μ-azido-κ4N:N-bis({2-[(3-amino-2,2-dimethylpropyl)iminomethyl]-6-methoxyphenolato-1κ3N,N′,O1}copper(II)) |
| title_full | Di-μ-azido-κ4N:N-bis({2-[(3-amino-2,2-dimethylpropyl)iminomethyl]-6-methoxyphenolato-1κ3N,N′,O1}copper(II)) |
| title_fullStr | Di-μ-azido-κ4N:N-bis({2-[(3-amino-2,2-dimethylpropyl)iminomethyl]-6-methoxyphenolato-1κ3N,N′,O1}copper(II)) |
| title_full_unstemmed | Di-μ-azido-κ4N:N-bis({2-[(3-amino-2,2-dimethylpropyl)iminomethyl]-6-methoxyphenolato-1κ3N,N′,O1}copper(II)) |
| title_short | Di-μ-azido-κ4N:N-bis({2-[(3-amino-2,2-dimethylpropyl)iminomethyl]-6-methoxyphenolato-1κ3N,N′,O1}copper(II)) |
| title_sort | di amp 956 azido amp 954 4n n bis 2 3 amino 2 2 dimethylpropyl iminomethyl 6 methoxyphenolato 1 amp 954 3n n amp 8242 o1 copper ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812028954 |
| work_keys_str_mv | AT akbarghaemi diamp956azidoamp9544nnbis23amino22dimethylpropyliminomethyl6methoxyphenolato1amp9543nnamp8242o1copperii AT saeedrayati diamp956azidoamp9544nnbis23amino22dimethylpropyliminomethyl6methoxyphenolato1amp9543nnamp8242o1copperii AT kazemfayyazi diamp956azidoamp9544nnbis23amino22dimethylpropyliminomethyl6methoxyphenolato1amp9543nnamp8242o1copperii AT seikwengng diamp956azidoamp9544nnbis23amino22dimethylpropyliminomethyl6methoxyphenolato1amp9543nnamp8242o1copperii AT edwardrttiekink diamp956azidoamp9544nnbis23amino22dimethylpropyliminomethyl6methoxyphenolato1amp9543nnamp8242o1copperii |