Recent advances of Copper- BTC metal-organic frameworks for efficient degradation of organic dye-polluted wastewater: Synthesis, mechanistic insights and future outlook

Water borne emerging pollutants represents a significant challenge confronting the modern society. As a result of excessive use of dyes and pigments by the textile and other industries, substantial amount of these toxic and recalcitrant substances are widely dispersed into the aquatic sources that m...

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Main Authors: Saptarshi Roy, Jnyanashree Darabdhara, Md. Ahmaruzzaman
Format: Article
Language:English
Published: Elsevier 2024-11-01
Series:Journal of Hazardous Materials Letters
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2666911023000205
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author Saptarshi Roy
Jnyanashree Darabdhara
Md. Ahmaruzzaman
author_facet Saptarshi Roy
Jnyanashree Darabdhara
Md. Ahmaruzzaman
author_sort Saptarshi Roy
collection DOAJ
description Water borne emerging pollutants represents a significant challenge confronting the modern society. As a result of excessive use of dyes and pigments by the textile and other industries, substantial amount of these toxic and recalcitrant substances are widely dispersed into the aquatic sources that may raise serious health issues to all life forms besides causing potential disruption to the ecosystem. Treatments of these hazardous and non-biodegradable organic contaminants in wastewater effluents have become a focal point for researchers dedicated to environmental remediation. Notably, Metal organic frameworks (MOFs) and their composites have been reported to be promising materials for tackling such challenges. This review is dedicated to provide a concise overview by consolidating the diverse beneficial attributes of Cu-BTC MOF rendering it as a versatile material with applications spanning diverse domains, focusing on the reactivity, the role of the metal ion and its recent potential for addressing the elimination of toxic textile dye wastes from the wastewater effluent. Furthermore, it also documents the underlying mechanistic pathway governing the degradation mechanism and the superior electron transport property of Cu ̶ BTC, besides painting in detail the existing limitations that hinder their applicability at an industrial platform. Moreover, a set of future research outlooks serving as a roadmap for exploring the potentiality of Cu ̶ BTC MOFs have also been presented.
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spelling doaj.art-b18fbe7493434221ae514a344c37abf92023-12-07T05:31:11ZengElsevierJournal of Hazardous Materials Letters2666-91102024-11-015100094Recent advances of Copper- BTC metal-organic frameworks for efficient degradation of organic dye-polluted wastewater: Synthesis, mechanistic insights and future outlookSaptarshi Roy0Jnyanashree Darabdhara1Md. Ahmaruzzaman2Department of Chemistry, National Institute of Technology Silchar, 788010 Assam, IndiaDepartment of Chemistry, National Institute of Technology Silchar, 788010 Assam, IndiaCorresponding author.; Department of Chemistry, National Institute of Technology Silchar, 788010 Assam, IndiaWater borne emerging pollutants represents a significant challenge confronting the modern society. As a result of excessive use of dyes and pigments by the textile and other industries, substantial amount of these toxic and recalcitrant substances are widely dispersed into the aquatic sources that may raise serious health issues to all life forms besides causing potential disruption to the ecosystem. Treatments of these hazardous and non-biodegradable organic contaminants in wastewater effluents have become a focal point for researchers dedicated to environmental remediation. Notably, Metal organic frameworks (MOFs) and their composites have been reported to be promising materials for tackling such challenges. This review is dedicated to provide a concise overview by consolidating the diverse beneficial attributes of Cu-BTC MOF rendering it as a versatile material with applications spanning diverse domains, focusing on the reactivity, the role of the metal ion and its recent potential for addressing the elimination of toxic textile dye wastes from the wastewater effluent. Furthermore, it also documents the underlying mechanistic pathway governing the degradation mechanism and the superior electron transport property of Cu ̶ BTC, besides painting in detail the existing limitations that hinder their applicability at an industrial platform. Moreover, a set of future research outlooks serving as a roadmap for exploring the potentiality of Cu ̶ BTC MOFs have also been presented.http://www.sciencedirect.com/science/article/pii/S2666911023000205Metal Organic FrameworkHKUST-1Organic dyesWastewaterPhotodegradationMechanistic Insights
spellingShingle Saptarshi Roy
Jnyanashree Darabdhara
Md. Ahmaruzzaman
Recent advances of Copper- BTC metal-organic frameworks for efficient degradation of organic dye-polluted wastewater: Synthesis, mechanistic insights and future outlook
Journal of Hazardous Materials Letters
Metal Organic Framework
HKUST-1
Organic dyes
Wastewater
Photodegradation
Mechanistic Insights
title Recent advances of Copper- BTC metal-organic frameworks for efficient degradation of organic dye-polluted wastewater: Synthesis, mechanistic insights and future outlook
title_full Recent advances of Copper- BTC metal-organic frameworks for efficient degradation of organic dye-polluted wastewater: Synthesis, mechanistic insights and future outlook
title_fullStr Recent advances of Copper- BTC metal-organic frameworks for efficient degradation of organic dye-polluted wastewater: Synthesis, mechanistic insights and future outlook
title_full_unstemmed Recent advances of Copper- BTC metal-organic frameworks for efficient degradation of organic dye-polluted wastewater: Synthesis, mechanistic insights and future outlook
title_short Recent advances of Copper- BTC metal-organic frameworks for efficient degradation of organic dye-polluted wastewater: Synthesis, mechanistic insights and future outlook
title_sort recent advances of copper btc metal organic frameworks for efficient degradation of organic dye polluted wastewater synthesis mechanistic insights and future outlook
topic Metal Organic Framework
HKUST-1
Organic dyes
Wastewater
Photodegradation
Mechanistic Insights
url http://www.sciencedirect.com/science/article/pii/S2666911023000205
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AT jnyanashreedarabdhara recentadvancesofcopperbtcmetalorganicframeworksforefficientdegradationoforganicdyepollutedwastewatersynthesismechanisticinsightsandfutureoutlook
AT mdahmaruzzaman recentadvancesofcopperbtcmetalorganicframeworksforefficientdegradationoforganicdyepollutedwastewatersynthesismechanisticinsightsandfutureoutlook