The Applications of Morphology Controlled ZnO in Catalysis

Zinc oxide (ZnO), with the unique chemical and physical properties of high chemical stability, broad radiation absorption range, high electrochemical coupling coefficient, and high photo-stability, is an attractive multifunctional material which has promoted great interest in many fields. What is mo...

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Main Authors: Yuhai Sun, Limin Chen, Yunfeng Bao, Yujun Zhang, Jing Wang, Mingli Fu, Junliang Wu, Daiqi Ye
Format: Article
Language:English
Published: MDPI AG 2016-11-01
Series:Catalysts
Subjects:
Online Access:http://www.mdpi.com/2073-4344/6/12/188
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author Yuhai Sun
Limin Chen
Yunfeng Bao
Yujun Zhang
Jing Wang
Mingli Fu
Junliang Wu
Daiqi Ye
author_facet Yuhai Sun
Limin Chen
Yunfeng Bao
Yujun Zhang
Jing Wang
Mingli Fu
Junliang Wu
Daiqi Ye
author_sort Yuhai Sun
collection DOAJ
description Zinc oxide (ZnO), with the unique chemical and physical properties of high chemical stability, broad radiation absorption range, high electrochemical coupling coefficient, and high photo-stability, is an attractive multifunctional material which has promoted great interest in many fields. What is more, its properties can be tuned by controllable synthesized morphologies. Therefore, after the success of the abundant morphology controllable synthesis, both the morphology-dependent ZnO properties and their related applications have been extensively investigated. This review concentrates on the properties of morphology-dependent ZnO and their applications in catalysis, mainly involved reactions on green energy and environmental issues, such as CO2 hydrogenation to fuels, methanol steam reforming to generate H2, bio-diesel production, pollutant photo-degradation, etc. The impressive catalytic properties of ZnO are associated with morphology tuned specific microstructures, defects or abilities of electron transportation, etc. The main morphology-dependent promotion mechanisms are discussed and summarized.
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spelling doaj.art-b19a6ba491f341cd9c0f1e235e8031fe2022-12-22T02:49:10ZengMDPI AGCatalysts2073-43442016-11-0161218810.3390/catal6120188catal6120188The Applications of Morphology Controlled ZnO in CatalysisYuhai Sun0Limin Chen1Yunfeng Bao2Yujun Zhang3Jing Wang4Mingli Fu5Junliang Wu6Daiqi Ye7Guangdong Provincial Key Laboratory of Atmospheric Environment and Pollution Control, School of Environment and Energy, South China University of Technology, Guangzhou Higher Education Mega Centre, Guangzhou 510006, ChinaGuangdong Provincial Key Laboratory of Atmospheric Environment and Pollution Control, School of Environment and Energy, South China University of Technology, Guangzhou Higher Education Mega Centre, Guangzhou 510006, ChinaGuangdong Provincial Key Laboratory of Atmospheric Environment and Pollution Control, School of Environment and Energy, South China University of Technology, Guangzhou Higher Education Mega Centre, Guangzhou 510006, ChinaGuangdong Provincial Key Laboratory of Atmospheric Environment and Pollution Control, School of Environment and Energy, South China University of Technology, Guangzhou Higher Education Mega Centre, Guangzhou 510006, ChinaGuangdong Provincial Key Laboratory of Atmospheric Environment and Pollution Control, School of Environment and Energy, South China University of Technology, Guangzhou Higher Education Mega Centre, Guangzhou 510006, ChinaGuangdong Provincial Key Laboratory of Atmospheric Environment and Pollution Control, School of Environment and Energy, South China University of Technology, Guangzhou Higher Education Mega Centre, Guangzhou 510006, ChinaGuangdong Provincial Key Laboratory of Atmospheric Environment and Pollution Control, School of Environment and Energy, South China University of Technology, Guangzhou Higher Education Mega Centre, Guangzhou 510006, ChinaGuangdong Provincial Key Laboratory of Atmospheric Environment and Pollution Control, School of Environment and Energy, South China University of Technology, Guangzhou Higher Education Mega Centre, Guangzhou 510006, ChinaZinc oxide (ZnO), with the unique chemical and physical properties of high chemical stability, broad radiation absorption range, high electrochemical coupling coefficient, and high photo-stability, is an attractive multifunctional material which has promoted great interest in many fields. What is more, its properties can be tuned by controllable synthesized morphologies. Therefore, after the success of the abundant morphology controllable synthesis, both the morphology-dependent ZnO properties and their related applications have been extensively investigated. This review concentrates on the properties of morphology-dependent ZnO and their applications in catalysis, mainly involved reactions on green energy and environmental issues, such as CO2 hydrogenation to fuels, methanol steam reforming to generate H2, bio-diesel production, pollutant photo-degradation, etc. The impressive catalytic properties of ZnO are associated with morphology tuned specific microstructures, defects or abilities of electron transportation, etc. The main morphology-dependent promotion mechanisms are discussed and summarized.http://www.mdpi.com/2073-4344/6/12/188ZnOmorphologiespolar facetsoxygen vacanciesdefectsstrong metal-support interactions (SMSI)acid-base propertieselectron-hole recombinationband gapcatalytic activities
spellingShingle Yuhai Sun
Limin Chen
Yunfeng Bao
Yujun Zhang
Jing Wang
Mingli Fu
Junliang Wu
Daiqi Ye
The Applications of Morphology Controlled ZnO in Catalysis
Catalysts
ZnO
morphologies
polar facets
oxygen vacancies
defects
strong metal-support interactions (SMSI)
acid-base properties
electron-hole recombination
band gap
catalytic activities
title The Applications of Morphology Controlled ZnO in Catalysis
title_full The Applications of Morphology Controlled ZnO in Catalysis
title_fullStr The Applications of Morphology Controlled ZnO in Catalysis
title_full_unstemmed The Applications of Morphology Controlled ZnO in Catalysis
title_short The Applications of Morphology Controlled ZnO in Catalysis
title_sort applications of morphology controlled zno in catalysis
topic ZnO
morphologies
polar facets
oxygen vacancies
defects
strong metal-support interactions (SMSI)
acid-base properties
electron-hole recombination
band gap
catalytic activities
url http://www.mdpi.com/2073-4344/6/12/188
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