Bis(μ2-4,7-dimethyl-4,7-diazadecane-1,10-dithiolato)trinickel(II) bis(perchlorate)
In the title compound, [Ni3(C10H22N2S2)2](ClO4)2, the complex cation consists of a nickel(II) ion and two [Ni(C10H22N2S2)] units with an N2S2 tetradentate ligand, 3,3′-[1,2-ethanediylbis(methylimino)]bis(1-propanethiolate). The central NiII ion is located on a crystallographic inversio...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-03-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812006034 |
| _version_ | 1828437330485051392 |
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| author | Yuzo Yoshikawa Masaaki Kojima Naoto Kuwamura Isamu Kinoshita Masakazu Hirotsu |
| author_facet | Yuzo Yoshikawa Masaaki Kojima Naoto Kuwamura Isamu Kinoshita Masakazu Hirotsu |
| author_sort | Yuzo Yoshikawa |
| collection | DOAJ |
| description | In the title compound, [Ni3(C10H22N2S2)2](ClO4)2, the complex cation consists of a nickel(II) ion and two [Ni(C10H22N2S2)] units with an N2S2 tetradentate ligand, 3,3′-[1,2-ethanediylbis(methylimino)]bis(1-propanethiolate). The central NiII ion is located on a crystallographic inversion centre and is bound to the four S atoms of the two [Ni(C10H22N2S2)] units to form a linear sulfur-bridged trimetallic moiety. The dihedral angle between the central NiS4 plane and the terminal NiN2S2 plane is 145.71 (5)°. In the [Ni(C10H22N2S2)] unit, the two methyl groups on the chelating N atoms are cis to each other, and the two six-membered N,S-chelate rings adopt a chair conformation. The Ni—S bond lengths and the S—Ni—S bite angles in the central NiS4 group are similar to those in the [Ni(C10H22N2S2)] unit. |
| first_indexed | 2024-12-10T19:43:32Z |
| format | Article |
| id | doaj.art-b19e0104992d4635949697a3b0e4575f |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T19:43:32Z |
| publishDate | 2012-03-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-b19e0104992d4635949697a3b0e4575f2022-12-22T01:35:56ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-03-01683m307m30710.1107/S1600536812006034Bis(μ2-4,7-dimethyl-4,7-diazadecane-1,10-dithiolato)trinickel(II) bis(perchlorate)Yuzo YoshikawaMasaaki KojimaNaoto KuwamuraIsamu KinoshitaMasakazu HirotsuIn the title compound, [Ni3(C10H22N2S2)2](ClO4)2, the complex cation consists of a nickel(II) ion and two [Ni(C10H22N2S2)] units with an N2S2 tetradentate ligand, 3,3′-[1,2-ethanediylbis(methylimino)]bis(1-propanethiolate). The central NiII ion is located on a crystallographic inversion centre and is bound to the four S atoms of the two [Ni(C10H22N2S2)] units to form a linear sulfur-bridged trimetallic moiety. The dihedral angle between the central NiS4 plane and the terminal NiN2S2 plane is 145.71 (5)°. In the [Ni(C10H22N2S2)] unit, the two methyl groups on the chelating N atoms are cis to each other, and the two six-membered N,S-chelate rings adopt a chair conformation. The Ni—S bond lengths and the S—Ni—S bite angles in the central NiS4 group are similar to those in the [Ni(C10H22N2S2)] unit.http://scripts.iucr.org/cgi-bin/paper?S1600536812006034 |
| spellingShingle | Yuzo Yoshikawa Masaaki Kojima Naoto Kuwamura Isamu Kinoshita Masakazu Hirotsu Bis(μ2-4,7-dimethyl-4,7-diazadecane-1,10-dithiolato)trinickel(II) bis(perchlorate) Acta Crystallographica Section E |
| title | Bis(μ2-4,7-dimethyl-4,7-diazadecane-1,10-dithiolato)trinickel(II) bis(perchlorate) |
| title_full | Bis(μ2-4,7-dimethyl-4,7-diazadecane-1,10-dithiolato)trinickel(II) bis(perchlorate) |
| title_fullStr | Bis(μ2-4,7-dimethyl-4,7-diazadecane-1,10-dithiolato)trinickel(II) bis(perchlorate) |
| title_full_unstemmed | Bis(μ2-4,7-dimethyl-4,7-diazadecane-1,10-dithiolato)trinickel(II) bis(perchlorate) |
| title_short | Bis(μ2-4,7-dimethyl-4,7-diazadecane-1,10-dithiolato)trinickel(II) bis(perchlorate) |
| title_sort | bis amp 956 2 4 7 dimethyl 4 7 diazadecane 1 10 dithiolato trinickel ii bis perchlorate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812006034 |
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