Characteristics of Kaolinitic Raw Materials from the Lokoundje River (Kribi, Cameroon) for Ceramic Applications

Eight kaolinitic materials from the Lokoundje River at Kribi were sampled and investigated for their physical, chemical, mineralogical and thermal characteristics in order to evaluate their potential suitability as raw materials in ceramics. The Lokoundje kaolinitic materials are clayey to silty cla...

Full description

Bibliographic Details
Main Authors: Paul-Désiré Ndjigui, Jean Aimé Mbey, Soureiyatou Fadil-Djenabou, Vincent Laurent Onana, Elie Constantin Bayiga, Christophe Enock Embom, Georges-Ivo Ekosse
Format: Article
Language:English
Published: MDPI AG 2021-07-01
Series:Applied Sciences
Subjects:
Online Access:https://www.mdpi.com/2076-3417/11/13/6118
_version_ 1797528087233036288
author Paul-Désiré Ndjigui
Jean Aimé Mbey
Soureiyatou Fadil-Djenabou
Vincent Laurent Onana
Elie Constantin Bayiga
Christophe Enock Embom
Georges-Ivo Ekosse
author_facet Paul-Désiré Ndjigui
Jean Aimé Mbey
Soureiyatou Fadil-Djenabou
Vincent Laurent Onana
Elie Constantin Bayiga
Christophe Enock Embom
Georges-Ivo Ekosse
author_sort Paul-Désiré Ndjigui
collection DOAJ
description Eight kaolinitic materials from the Lokoundje River at Kribi were sampled and investigated for their physical, chemical, mineralogical and thermal characteristics in order to evaluate their potential suitability as raw materials in ceramics. The Lokoundje kaolinitic materials are clayey to silty clayey and are predominantly composed of kaolinite and quartz. The alkali (Na<sub>2</sub>O + K<sub>2</sub>O) content ranges between 1 and 2.5 wt.%; these low values do not favor vitrification of the ceramics but may be improved through flux amendment. The presence of goethite in some samples limits their utilization in white ceramics. The minerals content, color, metallic sound, cohesion, linear shrinkage, flexural strength, bulk density, water absorption and microstructure were determined. The XRD data reveal that kaolinite and goethite were transformed, respectively, into mullite and hematite. The colors of the fired products are characteristic of their mineral assemblage. The metallic sound is indicative of low vitrification which is confirmed by the presence of cracks due to low flux contents. The cohesion is good to very good, due to the abundance of kaolinite. The physicomechanical properties increase with temperature as well as densification. The geochemical data show that the Lokoundje alluvial clays are suitable for the manufacture of white stoneware tiles.
first_indexed 2024-03-10T09:53:07Z
format Article
id doaj.art-b1c3e600642c40a2a410f39138af9c86
institution Directory Open Access Journal
issn 2076-3417
language English
last_indexed 2024-03-10T09:53:07Z
publishDate 2021-07-01
publisher MDPI AG
record_format Article
series Applied Sciences
spelling doaj.art-b1c3e600642c40a2a410f39138af9c862023-11-22T02:34:06ZengMDPI AGApplied Sciences2076-34172021-07-011113611810.3390/app11136118Characteristics of Kaolinitic Raw Materials from the Lokoundje River (Kribi, Cameroon) for Ceramic ApplicationsPaul-Désiré Ndjigui0Jean Aimé Mbey1Soureiyatou Fadil-Djenabou2Vincent Laurent Onana3Elie Constantin Bayiga4Christophe Enock Embom5Georges-Ivo Ekosse6Department of Earth Sciences, University of Yaoundé I, P.O. Box 812, Yaoundé, CameroonDepartment of Inorganic Chemistry, University of Yaoundé I, P.O. Box 812, Yaoundé, CameroonDepartment of Life and Earth Sciences, Higher Teachers’ Training College, University of Maroua, P.O. Box 55, Maroua, CameroonDepartment of Earth Sciences, University of Yaoundé I, P.O. Box 812, Yaoundé, CameroonDepartment of Earth Sciences, University of Douala, P.O. Box 24157, Douala, CameroonDepartment of Earth Sciences, University of Yaoundé I, P.O. Box 812, Yaoundé, CameroonDirectorate of Research and Innovation, University of Venda, Thohoyandou 0950, South AfricaEight kaolinitic materials from the Lokoundje River at Kribi were sampled and investigated for their physical, chemical, mineralogical and thermal characteristics in order to evaluate their potential suitability as raw materials in ceramics. The Lokoundje kaolinitic materials are clayey to silty clayey and are predominantly composed of kaolinite and quartz. The alkali (Na<sub>2</sub>O + K<sub>2</sub>O) content ranges between 1 and 2.5 wt.%; these low values do not favor vitrification of the ceramics but may be improved through flux amendment. The presence of goethite in some samples limits their utilization in white ceramics. The minerals content, color, metallic sound, cohesion, linear shrinkage, flexural strength, bulk density, water absorption and microstructure were determined. The XRD data reveal that kaolinite and goethite were transformed, respectively, into mullite and hematite. The colors of the fired products are characteristic of their mineral assemblage. The metallic sound is indicative of low vitrification which is confirmed by the presence of cracks due to low flux contents. The cohesion is good to very good, due to the abundance of kaolinite. The physicomechanical properties increase with temperature as well as densification. The geochemical data show that the Lokoundje alluvial clays are suitable for the manufacture of white stoneware tiles.https://www.mdpi.com/2076-3417/11/13/6118Kribialluvial clayskaolinitevalorizationlow mullitizationwhite stoneware tiles
spellingShingle Paul-Désiré Ndjigui
Jean Aimé Mbey
Soureiyatou Fadil-Djenabou
Vincent Laurent Onana
Elie Constantin Bayiga
Christophe Enock Embom
Georges-Ivo Ekosse
Characteristics of Kaolinitic Raw Materials from the Lokoundje River (Kribi, Cameroon) for Ceramic Applications
Applied Sciences
Kribi
alluvial clays
kaolinite
valorization
low mullitization
white stoneware tiles
title Characteristics of Kaolinitic Raw Materials from the Lokoundje River (Kribi, Cameroon) for Ceramic Applications
title_full Characteristics of Kaolinitic Raw Materials from the Lokoundje River (Kribi, Cameroon) for Ceramic Applications
title_fullStr Characteristics of Kaolinitic Raw Materials from the Lokoundje River (Kribi, Cameroon) for Ceramic Applications
title_full_unstemmed Characteristics of Kaolinitic Raw Materials from the Lokoundje River (Kribi, Cameroon) for Ceramic Applications
title_short Characteristics of Kaolinitic Raw Materials from the Lokoundje River (Kribi, Cameroon) for Ceramic Applications
title_sort characteristics of kaolinitic raw materials from the lokoundje river kribi cameroon for ceramic applications
topic Kribi
alluvial clays
kaolinite
valorization
low mullitization
white stoneware tiles
url https://www.mdpi.com/2076-3417/11/13/6118
work_keys_str_mv AT pauldesirendjigui characteristicsofkaoliniticrawmaterialsfromthelokoundjeriverkribicameroonforceramicapplications
AT jeanaimembey characteristicsofkaoliniticrawmaterialsfromthelokoundjeriverkribicameroonforceramicapplications
AT soureiyatoufadildjenabou characteristicsofkaoliniticrawmaterialsfromthelokoundjeriverkribicameroonforceramicapplications
AT vincentlaurentonana characteristicsofkaoliniticrawmaterialsfromthelokoundjeriverkribicameroonforceramicapplications
AT elieconstantinbayiga characteristicsofkaoliniticrawmaterialsfromthelokoundjeriverkribicameroonforceramicapplications
AT christopheenockembom characteristicsofkaoliniticrawmaterialsfromthelokoundjeriverkribicameroonforceramicapplications
AT georgesivoekosse characteristicsofkaoliniticrawmaterialsfromthelokoundjeriverkribicameroonforceramicapplications