Evolution of Spin-Crossover Transition in Hybrid Crystals Involving Cationic Iron Complexes [Fe(III)(3-OMesal2-trien)]+ and Anionic Gold Bis(dithiolene) Complexes Au(dmit)2 and Au(dddt)2

Evolution of Spin-Crossover Transition in Hybrid Crystals Involving Cationic Iron Complexes [Fe(III)(3-OMesal2-trien)]+ and Anionic Gold Bis(dithiolene) Complexes Au(dmit)2 and Au(dddt)2

Hybrid ion-pair crystals involving hexadentate [Fe(III)(3-OMesal2-trien)]+ spin-crossover (SCO) cationic complexes and anionic gold complexes [Au(dmit)2]− (1) (dmit = 4,5-dithiolato-1,3-dithiole-2-thione) and [Au(dddt)2]− (2) (dddt = 5,6-dihydro-1,4-dithiin-2,3-dithiolate) were s...

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Bibliographic Details
Main Authors: Nataliya G. Spitsyna, Yuri N. Shvachko, Denis V. Starichenko, Erkki Lahderanta, Anton A. Komlev, Leokadiya V. Zorina, Sergey V. Simonov, Maksim A. Blagov, Eduard B. Yagubskii
Format: Article
Language:English
Published: MDPI AG 2018-10-01
Series:Crystals
Subjects:
metal dithiolene complexes
[Au(dmit)2]−, [Au(dddt)2]−
ion-pair crystals
[Fe(III)(3-OMesal2-trien)]+
coordination complexes
crystal structure
magnetic properties
magnetic susceptibility
magnetization
spin-crossover transition
Online Access:http://www.mdpi.com/2073-4352/8/10/382

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