Bulk-like ferroelectricity and magnetoelectric response of low-temperature solution-processed BiFeO3–PbTiO3 films on Ni for metallic MEMS
Simple and cost-effective procedures for the direct integration of ferroelectric perovskite oxides into Ni structures are necessary to realize related multifunctional metallic microelectromechanical systems, such as dual-source energy harvesters. This is especially difficult in the case of lead-cont...
| Main Authors: | , , , , , , , , , |
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| Format: | Article |
| Language: | English |
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AIP Publishing LLC
2023-12-01
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| Series: | APL Energy |
| Online Access: | http://dx.doi.org/10.1063/5.0172616 |
| _version_ | 1797367032660885504 |
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| author | Miguel Algueró Layiq Zia Ricardo Jiménez Harvey Amorín Iñigo Bretos Adriana Barreto G. Hassnain Jaffari Enrique Rodríguez-Castellón Pablo Ramos M. Lourdes Calzada |
| author_facet | Miguel Algueró Layiq Zia Ricardo Jiménez Harvey Amorín Iñigo Bretos Adriana Barreto G. Hassnain Jaffari Enrique Rodríguez-Castellón Pablo Ramos M. Lourdes Calzada |
| author_sort | Miguel Algueró |
| collection | DOAJ |
| description | Simple and cost-effective procedures for the direct integration of ferroelectric perovskite oxides into Ni structures are necessary to realize related multifunctional metallic microelectromechanical systems, such as dual-source energy harvesters. This is especially difficult in the case of lead-containing morphotropic phase boundary materials for high piezoelectric response because the two components are thermodynamically incompatible and the formation of NiOx or perovskite oxide reduction takes place depending on the processing conditions. We show here that low-temperature solution processing is an effective means to kinetically limit nickel oxidation, capable of providing BiFeO3–PbTiO3 films on Ni plates at only 500 °C. Bulk-like ferroelectric properties and a distinctive magnetoelectric response were attained. This perovskite system, not explored before on Ni, has a much larger switchable polarization than the widely studied Pb(Zr,Ti)O3, and it is shown here to present an excellent downscaling behavior of ferroelectric properties until the verge of the nanoscale. |
| first_indexed | 2024-03-08T17:13:12Z |
| format | Article |
| id | doaj.art-b1d2c853a9df4b9687a29f66f5414fc3 |
| institution | Directory Open Access Journal |
| issn | 2770-9000 |
| language | English |
| last_indexed | 2024-03-08T17:13:12Z |
| publishDate | 2023-12-01 |
| publisher | AIP Publishing LLC |
| record_format | Article |
| series | APL Energy |
| spelling | doaj.art-b1d2c853a9df4b9687a29f66f5414fc32024-01-03T19:49:25ZengAIP Publishing LLCAPL Energy2770-90002023-12-0113036108036108-910.1063/5.0172616Bulk-like ferroelectricity and magnetoelectric response of low-temperature solution-processed BiFeO3–PbTiO3 films on Ni for metallic MEMSMiguel Algueró0Layiq Zia1Ricardo Jiménez2Harvey Amorín3Iñigo Bretos4Adriana Barreto5G. Hassnain Jaffari6Enrique Rodríguez-Castellón7Pablo Ramos8M. Lourdes Calzada9Instituto de Ciencia de Materiales de Madrid, Consejo Superior de Investigaciones Científicas (ICMM-CSIC), Madrid, SpainInstituto de Ciencia de Materiales de Madrid, Consejo Superior de Investigaciones Científicas (ICMM-CSIC), Madrid, SpainInstituto de Ciencia de Materiales de Madrid, Consejo Superior de Investigaciones Científicas (ICMM-CSIC), Madrid, SpainInstituto de Ciencia de Materiales de Madrid, Consejo Superior de Investigaciones Científicas (ICMM-CSIC), Madrid, SpainInstituto de Ciencia de Materiales de Madrid, Consejo Superior de Investigaciones Científicas (ICMM-CSIC), Madrid, SpainInstituto de Ciencia de Materiales de Madrid, Consejo Superior de Investigaciones Científicas (ICMM-CSIC), Madrid, SpainDepartment of Physics, Quaid-i-Azam University, Islamabad, PakistanDepartamento de Química Inorgánica, Facultad de Ciencias, Universidad de Málaga, Málaga, SpainDepartamento de Electrónica, Universidad de Alcalá, Alcalá de Henares, SpainInstituto de Ciencia de Materiales de Madrid, Consejo Superior de Investigaciones Científicas (ICMM-CSIC), Madrid, SpainSimple and cost-effective procedures for the direct integration of ferroelectric perovskite oxides into Ni structures are necessary to realize related multifunctional metallic microelectromechanical systems, such as dual-source energy harvesters. This is especially difficult in the case of lead-containing morphotropic phase boundary materials for high piezoelectric response because the two components are thermodynamically incompatible and the formation of NiOx or perovskite oxide reduction takes place depending on the processing conditions. We show here that low-temperature solution processing is an effective means to kinetically limit nickel oxidation, capable of providing BiFeO3–PbTiO3 films on Ni plates at only 500 °C. Bulk-like ferroelectric properties and a distinctive magnetoelectric response were attained. This perovskite system, not explored before on Ni, has a much larger switchable polarization than the widely studied Pb(Zr,Ti)O3, and it is shown here to present an excellent downscaling behavior of ferroelectric properties until the verge of the nanoscale.http://dx.doi.org/10.1063/5.0172616 |
| spellingShingle | Miguel Algueró Layiq Zia Ricardo Jiménez Harvey Amorín Iñigo Bretos Adriana Barreto G. Hassnain Jaffari Enrique Rodríguez-Castellón Pablo Ramos M. Lourdes Calzada Bulk-like ferroelectricity and magnetoelectric response of low-temperature solution-processed BiFeO3–PbTiO3 films on Ni for metallic MEMS APL Energy |
| title | Bulk-like ferroelectricity and magnetoelectric response of low-temperature solution-processed BiFeO3–PbTiO3 films on Ni for metallic MEMS |
| title_full | Bulk-like ferroelectricity and magnetoelectric response of low-temperature solution-processed BiFeO3–PbTiO3 films on Ni for metallic MEMS |
| title_fullStr | Bulk-like ferroelectricity and magnetoelectric response of low-temperature solution-processed BiFeO3–PbTiO3 films on Ni for metallic MEMS |
| title_full_unstemmed | Bulk-like ferroelectricity and magnetoelectric response of low-temperature solution-processed BiFeO3–PbTiO3 films on Ni for metallic MEMS |
| title_short | Bulk-like ferroelectricity and magnetoelectric response of low-temperature solution-processed BiFeO3–PbTiO3 films on Ni for metallic MEMS |
| title_sort | bulk like ferroelectricity and magnetoelectric response of low temperature solution processed bifeo3 pbtio3 films on ni for metallic mems |
| url | http://dx.doi.org/10.1063/5.0172616 |
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