Effects of diagonal strains and H-bond geometry in antiferroelectric squaric acid crystals
The proton ordering model of the phase transition and physical properties of antiferroelectric crystals of squaric acid is modified by taking into account the influence of diagonal lattice strains and of the local geometry of hydrogen bonds, namely of the distance δ between the H-sites on a bond. Th...
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| Format: | Article |
| Language: | English |
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Institute for Condensed Matter Physics
2020-09-01
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| Series: | Condensed Matter Physics |
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| Online Access: | https://doi.org/10.5488/CMP.23.33704 |
| _version_ | 1811337722361544704 |
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| author | A.P. Moina |
| author_facet | A.P. Moina |
| author_sort | A.P. Moina |
| collection | DOAJ |
| description | The proton ordering model of the phase transition and physical properties of antiferroelectric crystals of squaric acid is modified by taking into account the influence of diagonal lattice strains and of the local geometry of hydrogen bonds, namely of the distance δ between the H-sites on a bond. Thermal expansion, the spontaneous strain ε_1–ε_3, and specific heat of squaric acid are well described by the proposed model. However, a consistent description of hydrostatic pressure influence on the transition temperature is possible only with further modifications of the model. |
| first_indexed | 2024-04-13T18:00:09Z |
| format | Article |
| id | doaj.art-b1d4705124f14841a5f6d698b2a9743b |
| institution | Directory Open Access Journal |
| issn | 1607-324X 2224-9079 |
| language | English |
| last_indexed | 2024-04-13T18:00:09Z |
| publishDate | 2020-09-01 |
| publisher | Institute for Condensed Matter Physics |
| record_format | Article |
| series | Condensed Matter Physics |
| spelling | doaj.art-b1d4705124f14841a5f6d698b2a9743b2022-12-22T02:36:18ZengInstitute for Condensed Matter PhysicsCondensed Matter Physics1607-324X2224-90792020-09-012333370410.5488/CMP.23.33704Effects of diagonal strains and H-bond geometry in antiferroelectric squaric acid crystalsA.P. MoinaThe proton ordering model of the phase transition and physical properties of antiferroelectric crystals of squaric acid is modified by taking into account the influence of diagonal lattice strains and of the local geometry of hydrogen bonds, namely of the distance δ between the H-sites on a bond. Thermal expansion, the spontaneous strain ε_1–ε_3, and specific heat of squaric acid are well described by the proposed model. However, a consistent description of hydrostatic pressure influence on the transition temperature is possible only with further modifications of the model.https://doi.org/10.5488/CMP.23.33704antiferroelectricityhydrogen bondphase transitionthermal expansionhydrostatic pressure |
| spellingShingle | A.P. Moina Effects of diagonal strains and H-bond geometry in antiferroelectric squaric acid crystals Condensed Matter Physics antiferroelectricity hydrogen bond phase transition thermal expansion hydrostatic pressure |
| title | Effects of diagonal strains and H-bond geometry in antiferroelectric squaric acid crystals |
| title_full | Effects of diagonal strains and H-bond geometry in antiferroelectric squaric acid crystals |
| title_fullStr | Effects of diagonal strains and H-bond geometry in antiferroelectric squaric acid crystals |
| title_full_unstemmed | Effects of diagonal strains and H-bond geometry in antiferroelectric squaric acid crystals |
| title_short | Effects of diagonal strains and H-bond geometry in antiferroelectric squaric acid crystals |
| title_sort | effects of diagonal strains and h bond geometry in antiferroelectric squaric acid crystals |
| topic | antiferroelectricity hydrogen bond phase transition thermal expansion hydrostatic pressure |
| url | https://doi.org/10.5488/CMP.23.33704 |
| work_keys_str_mv | AT apmoina effectsofdiagonalstrainsandhbondgeometryinantiferroelectricsquaricacidcrystals |